University of Groningen Tuning the crystalline phases of poly(vinylidene fluoride) for capacitive energy storage applications Meereboer, Niels Laurens

University of Groningen

Tuning the crystalline phases of poly(vinylidene fluoride) for capacitive energy storage

applications

Meereboer, Niels Laurens

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Publication date: 2019

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Meereboer, N. L. (2019). Tuning the crystalline phases of poly(vinylidene fluoride) for capacitive energy storage applications. Rijksuniversiteit Groningen.

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529927-L-sub01-bw-Meereboer 529927-L-sub01-bw-Meereboer 529927-L-sub01-bw-Meereboer 529927-L-sub01-bw-Meereboer Processed on: 21-3-2019 Processed on: 21-3-2019 Processed on: 21-3-2019

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Appendix

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529927-L-sub01-bw-Meereboer 529927-L-sub01-bw-Meereboer 529927-L-sub01-bw-Meereboer 529927-L-sub01-bw-Meereboer Processed on: 21-3-2019 Processed on: 21-3-2019 Processed on: 21-3-2019

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128 Summary

Summary

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529927-L-sub01-bw-Meereboer 529927-L-sub01-bw-Meereboer 529927-L-sub01-bw-Meereboer 529927-L-sub01-bw-Meereboer Processed on: 21-3-2019 Processed on: 21-3-2019 Processed on: 21-3-2019

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129 Summary

A

ŚŝŐŚůLJƉŽůĂƌɴͲƉŚĂƐĞ͘/ŶƚŚŝƐǁĂLJ͕ƚŚĞɴͲĐƌLJƐƚĂůƐĂƌĞǁĞůůŝƐŽůĂƚĞĚƐŚŽǁŝŶŐŝƚƐƉŽƚĞŶƟĂůƚŽ ďĞƵƐĞĚĨŽƌĞůĞĐƚƌŝĐĂůĞŶĞƌŐLJƐƚŽƌĂŐĞĂƉƉůŝĐĂƟŽŶƐ͘ /Ŷ ŚĂƉƚĞƌ ϯ͕ ďůŽĐŬ ĐŽƉŽůLJŵĞƌƐ ĐŽŶƚĂŝŶŝŶŐ ƉŽůLJ;ǀŝŶLJůŝĚĞŶĞ ĨůƵŽƌŝĚĞ-co-ƚƌŝŇƵŽƌŽĞƚŚLJůĞŶĞͿ;W;s&-co-dƌ&ͿͿĂƌĞŝŶǀĞƐƟŐĂƚĞĚƚŽƐŚĞĚůŝŐŚƚŽŶƚŚĞĞīĞĐƚŽĨĚŽŵĂŝŶ ǁĂůůƉŽůĂƌŝƚLJŽŶƚŚĞƵƌŝĞƚƌĂŶƐŝƟŽŶƚĞŵƉĞƌĂƚƵƌĞ͘dŚĞƵƌŝĞƚƌĂŶƐŝƟŽŶƚĞŵƉĞƌĂƚƵƌĞŝƐĂ ĨĞƌƌŽĞůĞĐƚƌŝĐͲƚŽͲƉĂƌĂĞůĞĐƚƌŝĐĐƌLJƐƚĂůůŝŶĞƉŚĂƐĞƚƌĂŶƐŝƟŽŶ;ĂŶĚvice versaͿŝŶŇƵĞŶĐĞĚďLJ ƚŚĞƉŽůLJŵĞƌĐŽŵƉŽƐŝƟŽŶ͕ŵŝĐƌŽƐƚƌƵĐƚƵƌĞ͕ĂŶĚĐƌLJƐƚĂůůŝnjĂƟŽŶŚŝƐƚŽƌLJ͘ƌŽƵŶĚƚŚĞƵƌŝĞ ƚƌĂŶƐŝƟŽŶŵĂdžŝŵƵŵǀĂůƵĞƐŽĨƚŚĞĚŝĞůĞĐƚƌŝĐĐŽŶƐƚĂŶƚ;ΕϱϬͿĂƌĞŽďƚĂŝŶĞĚŵĂŬŝŶŐƚŚĞƐĞ ƉŽůLJŵĞƌƐŚŝŐŚůLJƐƵŝƚĂďůĞĨŽƌĚŝĞůĞĐƚƌŝĐƐ͕ďƵƚĂĚĚŝƟŽŶĂůůLJĨŽƌƐŽůŝĚͲƐƚĂƚĞĐŽŽůŝŶŐĚĞǀŝĐĞƐ ĚƵĞƚŽƚŚĞĞůĞĐƚƌŽĐĂůŽƌŝĐĞīĞĐƚ͘LJƚŚĞƵƐĞŽĨĂƐŝŵŝůĂƌĂƉƉƌŽĂĐŚĂƐĚŝƐĐƵƐƐĞĚŝŶŚĂƉƚĞƌ 2, triblock copolymers, containing either polystyrene or poly(tertͲďƵƚŽdžLJƐƚLJƌĞŶĞͿĂƐŽƵƚĞƌ ďůŽĐŬ͕ĂƌĞĚĞƐŝŐŶĞĚƚŽƐĞůĨͲĂƐƐĞŵďůĞŝŶƐƉŚĞƌŝĐĂůŶĂŶŽĚŽŵĂŝŶƐ͘ŶŝŶĐƌĞĂƐĞŝŶĚŽŵĂŝŶ wall polarity is realized by in situ hydrolysis of the block copolymers having poly(tertͲ ďƵƚŽdžLJƐƚLJƌĞŶĞͿĂƐŽƵƚĞƌďůŽĐŬ͘/ŶƚŚŝƐǁĂLJ͕ŶĂŶŽĐƌLJƐƚĂůƐŝŶƚŚĞƐƉŚĞƌŝĐĂůŶĂŶŽĚŽŵĂŝŶƐ ĂƌĞ ƉƌĞƐĞƌǀĞĚ͕ ǁŚŝůĞ ƚŚĞ ƉŽůĂƌŝƚLJ ŽĨ ƚŚĞ ƐƵƌƌŽƵŶĚŝŶŐ ŵĂƚƌŝdž ŝƐ ŝŶĐƌĞĂƐĞĚ ĚƵĞ ƚŽ ƚŚĞ ĨŽƌŵĂƟŽŶŽĨƉŽůĂƌŚLJĚƌŽdžLJůŐƌŽƵƉƐ͘ŽŵƉĂƌĞĚƚŽƚŚĞƉƌŝƐƟŶĞĐŽƉŽůLJŵĞƌƐ͕ŝƚŝƐĨŽƵŶĚ ƚŚĂƚĂŶŝŶĐƌĞĂƐĞŝŶƉŽůĂƌŝƚLJŽĨƚŚĞƐƵƌƌŽƵŶĚŝŶŐŵĂƚƌŝdžůĞĂĚƐƚŽĂƌĞĚƵĐƟŽŶŽĨƚŚĞƵƌŝĞ ƚƌĂŶƐŝƟŽŶƚĞŵƉĞƌĂƚƵƌĞ͕ǁŚŝůĞW;s&-co-dƌ&ͿĐƌLJƐƚĂůƐĞŵďĞĚĚĞĚŝŶĂŶŽŶƉŽůĂƌŵĂƚƌŝdž ƐŚŽǁĂŶŝŶĐƌĞĂƐĞŝŶƚŚĞƵƌŝĞƚƌĂŶƐŝƟŽŶƚĞŵƉĞƌĂƚƵƌĞ͘dŚĞƐĞĮŶĚŝŶŐƐƉƌŽǀŝĚĞĚĞƐŝŐŶ ƉĂƌĂŵĞƚĞƌƐĨŽƌĚĞǀŝĐĞŵŝŶŝĂƚƵƌŝnjĂƟŽŶƵƐŝŶŐW;s&-co-dƌ&ͿĐŽƉŽůLJŵĞƌƐĨŽƌĂĚǀĂŶĐĞĚ ĞůĞĐƚƌŽŶŝĐĂƉƉůŝĐĂƟŽŶƐ͘ Ws&ĂŶĚŝƚƐŇƵŽƌŝŶĂƚĞĚĐŽƉŽůLJŵĞƌƐůĂĐŬĨƵŶĐƟŽŶĂůŝƟĞƐŝŶƚŚĞƉŽůLJŵĞƌďĂĐŬďŽŶĞ͘ dŚĞƌĞĨŽƌĞ͕ĨƵƌƚŚĞƌŵŽĚŝĮĐĂƟŽŶƚŽĞŶŚĂŶĐĞWs&͛ƐƉƌŽƉĞƌƟĞƐĂƉƉĞĂƌƚŽďĞĚŝĸĐƵůƚ͕ ƐƵĐŚĂƐĐƌŽƐƐůŝŶŬŝŶŐ͕ŶĂŶŽƉĂƌƟĐůĞĚŝƐƉĞƌƐŝŽŶĂŶĚĂĚŚĞƐŝŽŶƚŽƐƵďƐƚƌĂƚĞƐ͘ĞƐŝĚĞƐƚŚŝƐ͕ ƚŚĞĐŽŵŵŽŶŇƵŽƌŝŶĂƚĞĚĐŽŵŽŶŽŵĞƌƐĂƌĞĞdžƉĞŶƐŝǀĞůŝŵŝƟŶŐƚŚĞŝƌůĂƌŐĞƐĐĂůĞƵƐĂŐĞ͘ /ŶŚĂƉƚĞƌϰ͕ǀŝŶLJůĂĐĞƚĂƚĞŝƐƵƐĞĚƚŽĐŽƉŽůLJŵĞƌŝnjĞǁŝƚŚs&LJŝĞůĚŝŶŐW;s&-co-sĐͿ ĐŽƉŽůLJŵĞƌƐ͘LJĂĚĚŝŶŐƐŵĂůůĂŵŽƵŶƚƐŽĨsĐƚŽƚŚĞƌĞĂĐƟŽŶŵŝdžƚƵƌĞĂŶĚŬĞĞƉŝŶŐƚŚĞ ƉŽůLJŵĞƌŝnjĂƟŽŶƟŵĞƐƐŚŽƌƚ͕ϭϬĂŶĚϭϱŵŽůйsĐĂƌĞŝŶĐŽƌƉŽƌĂƚĞĚŝŶƚŚĞĐŽƉŽůLJŵĞƌĂŶĚ ƉƌŽǀĞƚŽďĞŚŽŵŽŐĞŶĞŽƵƐůLJĚŝƐƚƌŝďƵƚĞĚ͘,LJĚƌŽůLJƐŝƐŽĨW;s&-co-sĐͿƚŽŝƚƐǀŝŶLJůĂůĐŽŚŽů ;sͿĐŽƵŶƚĞƌƉĂƌƚĂŶĚƐƵďƐĞƋƵĞŶƚŵĞůƚĐƌLJƐƚĂůůŝnjĂƟŽŶůĞĂĚƐƚŽĂƉƉĞĂůŝŶŐĐƌLJƐƚĂůůŝnjĂƟŽŶ ďĞŚĂǀŝŽƌ͘dŚĞŝŶƚƌŽĚƵĐƟŽŶŽĨĚĞĨĞĐƚƐĂŶĚƚŚĞƐŵĂůůŵŽŶŽŵĞƌŝĐƐŝnjĞŽĨƚŚĞsƵŶŝƚƐ ĐŚĂŶŐĞƐWs&͛ƐĐƌLJƐƚĂůůŝnjĂƟŽŶďĞŚĂǀŝŽƌĂŶĚĂůůŽǁƐsƚŽďĞŝŶĐůƵĚĞĚŝŶƚŚĞWs&ĐƌLJƐƚĂůƐ͘ ŵŝdžƚƵƌĞŽĨɲͲĂŶĚɴͲƉŚĂƐĞŝƐŽďƚĂŝŶĞĚĨŽƌW;s&-co-sͿĐŽƉŽůLJŵĞƌƐĐŽŶƚĂŝŶŝŶŐϭϬ ŵŽůйs͕ǁŚŝůĞƚŚĞĐŽƉŽůLJŵĞƌƐŚĂǀŝŶŐϭϱŵŽůйsĐƌLJƐƚĂůůŝnjĞƐŽůĞůLJŝŶƚŚĞɴͲƉŚĂƐĞ͘ ŽŶƐĞƋƵĞŶƚůLJ͕ůŝŶĞĂƌĚŝĞůĞĐƚƌŝĐďĞŚĂǀŝŽƌŝƐŽďƐĞƌǀĞĚǁŚĞŶĂŵŝdžƚƵƌĞŽĨɲͲĂŶĚɴͲƉŚĂƐĞƐ ŝƐŽďƚĂŝŶĞĚ͕ǁŚŝůĞ͕ŝŶĚĞĞĚ͕ĐŽƉŽůLJŵĞƌƐŚĂǀŝŶŐƐŽůĞůLJƚŚĞĨĞƌƌŽĞůĞĐƚƌŝĐɴͲƉŚĂƐĞĚŝƐƉůĂLJ ferroelectric behavior. The ferroelectric phase obtained in these copolymers leads to ŶŽŶͲůŝŶĞĂƌƉŽůĂƌŝnjĂƟŽŶďĞŚĂǀŝŽƌďĞŶĞĮĐŝĂůĨŽƌƐƚŽƌŝŶŐůĂƌŐĞĂŵŽƵŶƚƐŽĨĞŶĞƌŐLJŝŶƐŝĚĞ

529927-L-sub01-bw-Meereboer 529927-L-sub01-bw-Meereboer 529927-L-sub01-bw-Meereboer 529927-L-sub01-bw-Meereboer Processed on: 21-3-2019 Processed on: 21-3-2019 Processed on: 21-3-2019

Processed on: 21-3-2019 PDF page: 130PDF page: 130PDF page: 130PDF page: 130

130 Summary ƚŚĞŵĂƚĞƌŝĂůĂŶĚƚŚĞŚLJĚƌŽdžLJůĨƵŶĐƟŽŶĂůŝƟĞƐŝŶƚƌŽĚƵĐĞĚŝŶƚŚĞďĂĐŬďŽŶĞŐŝǀĞŽƉƟŽŶƐ ƚŽƚƵŶĞƚŚĞĞůĞĐƚƌŽĂĐƟǀĞďĞŚĂǀŝŽƌĨƵƌƚŚĞƌ͘ dŽŝŶĐƌĞĂƐĞƚŽĞŶĞƌŐLJĞĸĐŝĞŶĐLJĂŶĚƚŽƌĞĂůŝnjĞůĂƌŐĞƌĚŝƐĐŚĂƌŐĞĚĞŶĞƌŐLJĚĞŶƐŝƟĞƐ͕ ƚŚĞĨĞƌƌŽĞůĞĐƚƌŝĐW;s&-co-sͿĐŽƉŽůLJŵĞƌƐĚŝƐĐƵƐƐĞĚŝŶŚĂƉƚĞƌϰĂƌĞĐƌŽƐƐůŝŶŬĞĚƵƐŝŶŐ ƵƌĞƚŚĂŶĞĐŚĞŵŝƐƚƌLJ͘hŶƟůŶŽǁ͕ƚŚĞƌĞŝƐĂůĂƌŐĞŐĂƉŝŶĞĂƐLJĐŚĞŵŝĐĂůŵĞƚŚŽĚƐƚŽŝŶĚƵĐĞ ĐƌŽƐƐůŝŶŬŝŶŐŝŶŇƵŽƌŝŶĂƚĞĚƉŽůLJŵĞƌƐ͕ǁŚŝůĞŚĂǀŝŶŐŐƌĞĂƚĐŽŶƚƌŽůŽǀĞƌƚŚĞĐƌŽƐƐůŝŶŬŝŶŐƐŝƚĞƐ͘ /ŶŚĂƉƚĞƌϱ͕ŝƚŝƐƐŚŽǁŶƚŚĂƚĐŚĞŵŝĐĂůĐƌŽƐƐůŝŶŬŝŶŐŝŵƉƌŽǀĞĚƚŚĞĚŝĞůĞĐƚƌŝĐƉƌŽƉĞƌƟĞƐ ƐŝŐŶŝĮĐĂŶƚůLJ͘ dŚĞ ďƌĞĂŬĚŽǁŶ ƐƚƌĞŶŐƚŚƐ ŽĨ ƚŚĞ ĐƌŽƐƐůŝŶŬĞĚ ŇƵŽƌŝŶĂƚĞĚ ŶĞƚǁŽƌŬƐ ĂƌĞ largely increased leading to increasing amounts of energy stored and released inside ƚŚĞŵĂƚĞƌŝĂůƐ͘/ŶĂĚĚŝƟŽŶ͕ŝƐŽůĂƟŽŶŽĨĨĞƌƌŽĞůĞĐƚƌŝĐĐƌLJƐƚĂůƐĚƵĞƚŽĐƌŽƐƐůŝŶŬŝŶŐƌĞƐƵůƚƐŝŶĂ ĐŚĂŶŐĞĨƌŽŵĨĞƌƌŽĞůĞĐƚƌŝĐƚŽĂŶƟĨĞƌƌŽĞůĞĐƚƌŝĐůŝŬĞďĞŚĂǀŝŽƌ͕ůĞĂĚŝŶŐƚŽŚŝŐŚĞƌĞĸĐŝĞŶĐŝĞƐ ĂƚůŽǁĞƌĮĞůĚƐ͘ /ŶŚĂƉƚĞƌϲ͕ƚŚĞĮŶĂůĐŚĂƉƚĞƌŽĨƚŚŝƐĚŝƐƐĞƌƚĂƟŽŶ͕ŇƵŽƌŝŶĂƚĞĚƚĞƌƉŽůLJŵĞƌƐĐŽŶƚĂŝŶŝŶŐ ƐŵĂůůĂŵŽƵŶƚƐŽĨsĂƌĞƐŚŽǁŶ͘dŚĞƚŚĞƌŵĂůďĞŚĂǀŝŽƌŽĨƚŚĞƐĞW;s&-ter-dƌ&-ter-sͿ ƚĞƌƉŽůLJŵĞƌƐŝƐŝŶǀĞƐƟŐĂƚĞĚĂŶĚůĂƌŐĞƌĞĚƵĐƟŽŶƐŝŶƚŚĞƵƌŝĞƚƌĂŶƐŝƟŽŶƚĞŵƉĞƌĂƚƵƌĞ ĂƌĞŽďƐĞƌǀĞĚĐŽŵƉĂƌĞĚƚŽW;s&-co-dƌ&ͿŚĂǀŝŶŐĂƐŝŵŝůĂƌĐŽŵƉŽƐŝƟŽŶ͘dŚĞĐƌLJƐƚĂůƐ ŽďƚĂŝŶĞĚ ĂƌĞ ƐŵĂůů ĂŶĚ͕ ĂĚĚŝƟŽŶĂůůLJ͕ ŵŽƌĞ ƉĂƌĂĞůĞĐƚƌŝĐ ƉŚĂƐĞ ŝƐ ĨŽƌŵĞĚ ĚƵĞ ƚŽ ƚŚĞ ŝŶĚƵĐƟŽŶŽĨŵŽƌĞŝƐŽƚĂĐƟĐŵŽŶŽŵĞƌƐĞƋƵĞŶĐĞƐĐĂƵƐĞĚďLJǀŝŶLJůĂůĐŽŚŽůƵŶŝƚƐ͘dŚŝƐ ůĞĂĚƐƚŽƌĞůĂdžŽƌĨĞƌƌŽĞůĞĐƚƌŝĐďĞŚĂǀŝŽƌ͕ŚŝŐŚůLJďĞŶĞĮĐŝĂůĨŽƌĐĂƉĂĐŝƟǀĞĞŶĞƌŐLJƐƚŽƌĂŐĞ ĂƉƉůŝĐĂƟŽŶƐĚƵĞƚŽŝƚƐŚŝŐŚĞĸĐŝĞŶĐLJĂŶĚĚŝƐĐŚĂƌŐĞĚĞŶĞƌŐLJĚĞŶƐŝƟĞƐ͘^ƵďƐĞƋƵĞŶƚůLJ ĐŚĞŵŝĐĂůĐƌŽƐƐůŝŶŬŝŶŐŽĨƚŚĞƚĞƌƉŽůLJŵĞƌƐƌĞƐƵůƚƐŝŶĞǀĞŶďĞƩĞƌďĞŚĂǀŝŽƌĚƵĞƚŽƚŚĞŶĞĂƌ ϬƌĞŵĂŶĞŶƚƉŽůĂƌŝnjĂƟŽŶ͘dŚŝƐŝƐĞdžƉůĂŝŶĞĚďLJĨƵƌƚŚĞƌŝƐŽůĂƟŽŶŽĨƚŚĞĐƌLJƐƚĂůƐĂŶĚƚŚĞ increasing amount of paraelectric phase. In this way, chemical and physical pinning of ĨĞƌƌŽĞůĞĐƚƌŝĐĐƌLJƐƚĂůƐƌĞƐƵůƚŝŶƐůŝŵŵĞƌŚLJƐƚĞƌĞƐŝƐůŽŽƉƐŚŝŐŚůLJĨĂǀŽƌĂďůĞĨŽƌĐĂƉĂĐŝƟǀĞ ĞŶĞƌŐLJƐƚŽƌĂŐĞĂƉƉůŝĐĂƟŽŶƐ͘

529927-L-sub01-bw-Meereboer 529927-L-sub01-bw-Meereboer 529927-L-sub01-bw-Meereboer 529927-L-sub01-bw-Meereboer Processed on: 21-3-2019 Processed on: 21-3-2019 Processed on: 21-3-2019

Processed on: 21-3-2019 PDF page: 131PDF page: 131PDF page: 131PDF page: 131

131 Samenvatting

A

Nederlandse Samenvatting

,ĞƚŐĞďƌƵŝŬŵĂŬĞŶǀĂŶƉŽůLJŵĞƌĞŶĂůƐĚŝĞůĞĐƚƌŝƐĐŚŵĞĚŝƵŵŽŵĞŶĞƌŐŝĞŽƉƚĞƐůĂĂŶŝŶ ĐŽŶĚĞŶƐĂƚŽƌƐŐĞĞŌƵŶŝĞŬĞŬĂŶƐĞŶƚĞŶŽƉnjŝĐŚƚĞǀĂŶĂŶĚĞƌĞĞŶĞƌŐŝĞŽƉƐůĂŐŵĞƚŚŽĚĞƐ͕ njŽĂůƐďĂƩĞƌŝũĞŶĞŶďƌĂŶĚƐƚŽĨĐĞůůĞŶ͘ŽŶĚĞŶƐĂƚŽƌƐŐĞďĂƐĞĞƌĚŽƉƉŽůLJŵĞƌĞŶnjŝũŶŝŶƐƚĂĂƚ ŽŵnjĞĞƌƐŶĞůƚĞŽŶƚůĂĚĞŶ͕njŽĚĂƚǀĞĞůĞŶĞƌŐŝĞŝŶŬŽƌƚƟũĚƐďĞƐƚĞŬŬĂŶǁŽƌĚĞŶǀƌŝũŐĞŐĞǀĞŶ͘ ŽǀĞŶĚŝĞŶnjŝũŶĚĞnjĞĐŽŶĚĞŶƐĂƚŽƌƐŚĞĞůďĞƚƌŽƵǁďĂĂƌĚŽŽƌĞĞŶŐƌĂĐŝĞƵƐĨĂĂůŵĞĐŚĂŶŝƐŵĞ͘ ĞǀŝŶĚĞŶƚŽĞƉĂƐƐŝŶŐĞŶŝŶĚŝƌĞĐƚĞĞŶĞƌŐŝĞĂƉƉůŝĐĂƟĞƐ͕ďŝũǀŽŽƌďĞĞůĚĂůƐƐƚƌŽŽŵŽŵnjĞƩĞƌƐ ĞŶŐĞƉƵůƐĞĞƌĚĞƐƚƌŽŽŵĂƉƉĂƌĂƚĞŶ͘,ĞůĂĂƐŚĞĞŌďŝĂdžŝĂĂůŐĞŽƌŝģŶƚĞĞƌĚƉŽůLJƉƌŽƉLJůĞĞŶ͕ĚĂƚ ŽƉĚŝƚŵŽŵĞŶƚĚĞŐŽƵĚĞŶƐƚĂŶĚĂĂƌĚŝƐ͕ĞĞŶƌĞůĂƟĞĨůĂŐĞĞŶĞƌŐŝĞĚŝĐŚƚŚĞŝĚĞŶĚĂĂƌďŝũ ŚŽŐĞĞŶĞƌŐŝĞǀĞƌůŝĞnjĞŶďŝũǀĞƌŚŽŽŐĚĞƚĞŵƉĞƌĂƚƵƌĞŶ͘KŵĚĂƚĚĞĞŶĞƌŐŝĞĚŝĐŚƚŚĞŝĚŝŶĚĞnjĞ ŵĂƚĞƌŝĂůĞŶƉƌŽƉŽƌƟŽŶĞĞůĂĂŶĚĞĚŝĞůĞŬƚƌŝƐĐŚĞĐŽŶƐƚĂŶƚĞŝƐĞŶŬǁĂĚƌĂƟƐĐŚƐĐŚĂĂůƚŵĞƚ het toegepast elektrisch veld wordt veel onderzoek gedaan naar manieren om deze ƚǁĞĞƉĂƌĂŵĞƚĞƌƐŵĂdžŝŵĂĂůƚĞďĞŶƵƩĞŶ͘ŝƚůĞŝĚƚƚŽƚǀĞĞůĂĂŶĚĂĐŚƚǀŽŽƌƉŽůLJ;ǀŝŶLJůŝĚĞĞŶ ŇƵŽƌŝĚĞͿ ;Ws&Ϳ ĚŽŽƌ ŚĂĂƌ ƌĞůĂƟĞǀĞ ŚŽŐĞ ĚŝĞůĞŬƚƌŝƐĐŚĞ ĐŽŶƐƚĂŶƚĞ ;ΕϭϬͿ ĞŶ ŚŽŐĞ ĚŝĞůĞŬƚƌŝƐĐŚĞƐƚĞƌŬƚĞ;ΕϲϬϬDsŵͲϭ_{Ϳ͘,ĞůĂĂƐǀŝŶĚƚǀĞĞůĨĞƌƌŽĞůĞŬƚƌŝƐĐŚǀĞƌůŝĞƐƉůĂĂƚƐďŝũ} ŚŽŐĞƌĞĞůĞŬƚƌŝƐĐŚĞǀĞůĚĞŶĚŽŽƌĞĞŶŽŶŽŵŬĞĞƌďĂƌĞŬƌŝƐƚĂůůŝũŶĞĨĂƐĞǀĞƌĂŶĚĞƌŝŶŐǀĂŶ ĞĞŶŶŝĞƚƉŽůĂŝƌĞɲͲĨĂƐĞŶĂĂƌĞĞŶĨĞƌƌŽĞůĞŬƚƌŝƐĐŚĞɴͲĨĂƐĞ͘ĂĂƌŽŵŝƐŝŶŚŽŽĨĚƐƚƵŬϭ͕ŚĞƚ ŵĞĐŚĂŶŝƐŵĞǀĂŶĨĞƌƌŽĞůĞŬƚƌŝĐŝƚĞŝƚŽƉŐĞŚĞůĚĞƌĚĞŶnjŝũŶďĞŶĂĚĞƌŝŶŐĞŶŽŵĨĞƌƌŽĞůĞŬƚƌŝƐĐŚ verlies tegen te gaan bediscussieerd.

/ŶŚŽŽĨĚƐƚƵŬϭůĞƌĞŶǁĞĚĂƚĚĞŚŽŐĞƉŽůĂƌŝƐĂƟĞŝŶɴͲĨĂƐĞŬƌŝƐƚĂůůĞŶŐĞďƌƵŝŬƚŬĂŶ ǁŽƌĚĞŶ ǀŽŽƌ ĚŝƌĞŬƚĞ ĞŶĞƌŐŝĞŽƉƐůĂŐ͘ ĞŶ ǀŽŽƌǁĂĂƌĚĞ ŚŝĞƌǀŽŽƌ ŝƐ ĚĂƚ ĚĞ ŬƌŝƐƚĂůůŝũŶĞ ĚŽŵĞŝŶĞŶŐŽĞĚŐĞŢƐŽůĞĞƌĚnjŝũŶ͕njŽĚĂƚĨĞƌƌŽĞůĞŬƚƌŝƐĐŚĞĚŽŵĞŝŶŬŽƉƉĞůŝŶŐŝŶƚĞƌĂĐƟĞƐ ǀĞƌŵĞĚĞŶǁŽƌĚĞŶ͘ĂĂƌďŝũƚŽĞŐĞǀŽĞŐĚ͕ĞĞŶŶŽŶƉŽůĂŝƌĞŵĂƚƌŝdžŽŵĚĞWs&ŬƌŝƐƚĂůůĞŶ ŵŝŶŝŵĂůŝƐĞĞƌƚĚĞĐŽŵƉĞŶƐĂƟĞƉŽůĂƌŝƐĂƟĞůĞŝĚĞŶĚƚŽƚĞĞŶǀĞƌďĞƚĞƌŝŶŐǀĂŶĚĞŬƌŝƐƚĂůůŝũŶĞ ĚŝƉŽŽůŽŵŬĞĞƌďĂĂƌŚĞŝĚ͘DŽŐĞůŝũŬĞŵĞƚŚŽĚĞƐ͕ŝŶĐůƵƐŝĞĨĐŽͲĞŶƚĞƌƉŽůLJŵĞƌŝƐĂƟĞƐ͕ŬĂŵ ƉŽůLJŵĞƌĞŶ͕ŚĞƚǀĞƌŶĞƚǁĞƌŬĞŶǀĂŶŐĞŇƵŽƌĞĞƌĚĞƉŽůLJŵĞƌĞŶ͕ŐĞůĂŵŝŶĞĞƌĚĞƉŽůLJŵĞƌĞŶĞŶ blok copolymeren, om een hoge dielektrische constante en hoge dielektrische sterkte ƚĞŬƌŝũŐĞŶnjŝũŶŬŽƌƚďĞĚŝƐĐƵƐƐŝĞĞƌĚ͘ /Ŷ ŚŽŽĨĚƐƚƵŬ Ϯ ŝƐ ŚĞƚ ŶĂŶŽͲŝŶƐůƵŝƟŶŐƐ ĞīĞĐƚ ŽƉ ĚĞ ƐŵĞůƚ ŬƌŝƐƚĂůůŝƐĂƟĞ ǀĂŶ Ws& ƐLJƐƚĞŵĂƟƐĐŚŽŶĚĞƌnjŽĐŚƚĚŽŽƌŐĞďƌƵŝŬƚĞŵĂŬĞŶǀĂŶďůŽŬĐŽƉŽůLJŵĞĞƌnjĞůĨĂƐƐĞŵďůĂŐĞ͘ KŶĚĞƌ ŶŽƌŵĂůĞ ĐŽŶĚŝƟĞƐ ŬƌŝƐƚĂůůŝƐĞĞƌƚ Ws& ŝŶ ĚĞ ɲͲĨĂƐĞ ǀĂŶƵŝƚ ĚĞ ƐŵĞůƚ͘ Kŵ ŚĞƚ ŬƌŝƐƚĂůůŝƐĂƟĞŐĞĚƌĂŐǀĂŶWs&ƚĞŽŶĚĞƌnjŽĞŬĞŶŝŶŶĂŶŽĚŝŵĞŶƐŝĞƐ͕njŝũŶƚƌŝďůŽŬĐŽƉŽůLJŵĞƌĞŶ͕ ǁĂĂƌŝŶWs&ŚĞƚŵŝĚĚĞůƐƚĞďůŽŬŝƐ͕ŽƉnjŽĞĞŶŵĂŶŝĞƌŽŶƚǁŽƌƉĞŶnjŽĚĂƚŬƌŝƐƚĂůůŝƐĂƟĞ ŐĞĚƌĞǀĞŶnjĞůĨĂƐƐĞŵďůĂŐĞ͕ŝŶŐĞƐůŽƚĞŶŬƌŝƐƚĂůůŝƐĂƟĞŝŶůĂŵĞůůĂŝƌĞĚŽŵĞŝŶĞŶĞŶŝŶŐĞƐůŽƚĞŶ ŬƌŝƐƚĂůůŝƐĂƟĞ ŝŶ ĞĞŶ ďŽůǀŽƌŵŝŐĞ ƐƚƌƵĐƚƵƵƌ ŬŽŶ ƉůĂĂƚƐ ǀŝŶĚĞŶ͘ <ƌŝƐƚĂůůŝƐĂƟĞ ŐĞĚƌĞǀĞŶ njĞůĨĂƐƐĞŵďůĂŐĞůĞŝĚƚƚŽƚĚĞĨŽƌŵĂƟĞǀĂŶĞĞŶŵĞŶŐƐĞůǀĂŶɲͲĞŶɶͲĨĂƐĞWs&͘/ŶŚĞƚ ŐĞǀĂůĚĂƚůĂĂŐŵŽůĞĐƵƵůŐĞǁŝĐŚƚďůŽŬŬĞŶnjŝũŶŐĞďƌƵŝŬƚ͕ůĞŝĚĞŶǁĂƚĞƌƐƚŽĩƌƵŐŝŶƚĞƌĂĐƟĞƐ ǀĂŶWs&ŵĞƚŚĞƚĂŶĚĞƌĞďůŽŬƚŽƚĚĞĨŽƌŵĂƟĞǀĂŶĚĞɶͲĨĂƐĞ͘ůƐĞƌŐĞĞŶŝŶƚĞƌĂĐƟĞƐ

529927-L-sub01-bw-Meereboer 529927-L-sub01-bw-Meereboer 529927-L-sub01-bw-Meereboer 529927-L-sub01-bw-Meereboer Processed on: 21-3-2019 Processed on: 21-3-2019 Processed on: 21-3-2019

Processed on: 21-3-2019 PDF page: 132PDF page: 132PDF page: 132PDF page: 132

132 Samenvatting ƉůĂĂƚƐǀŝŶĚĞŶŝŶĚĞƐŵĞůƚ͕ƌĞƐƵůƚĞĞƌƚŽǀĞƌƐĐŚƌŝũǀŝŶŐǀĂŶĚĞƐŵĞůƚƐƚƌƵĐƚƵƵƌŝŶɲͲĨĂƐĞ ŬƌŝƐƚĂůůĞŶ͘ŝƚŬŽŵƚĚŽŽƌĞĞŶŚĞƚĞƌŽŐĞĞŶŶƵĐůĞĂƟĞŵĞĐŚĂŶŝƐŵĞnjŽƌŐĞŶĚǀŽŽƌŚŽŐĞ ŬƌŝƐƚĂůůŝƐĂƟĞƚĞŵƉĞƌĂƚƵƌĞŶĚĂƚůĞŝĚƚƚŽƚĚĞŬŝŶĞƟƐĐŚŐĞƉƌĞĨĞƌĞĞƌĚĞɲͲĨĂƐĞ͘ŝƚnjĞůĨĚĞŝƐ ŐĞŽďƐĞƌǀĞĞƌĚĂůƐĚĞŬƌŝƐƚĂůůŝƐĂƟĞǀĂŶWs&ŝƐŝŶŐĞƐůŽƚĞŶŝŶůĂŵĞůůĂŝƌĞŶĂŶŽĚŽŵĞŝŶĞŶ͘ /ŶƚĞŐĞŶƐƚĞůůŝŶŐƚŽƚĞŶŚŽŽŐƐƚŝŶƚĞƌĞƐƐĂŶƚŵĞƚďĞƚƌĞŬŬŝŶŐƚŽƚĚŝĞůĞŬƚƌŝƐĐŚĞĂƉƉůŝĐĂƟĞƐ͕ ůĞŝĚƚĞĞŶŚŽŵŽŐĞĞŶŬƌŝƐƚĂůůŝƐĂƟĞŵĞĐŚĂŶŝƐŵĞŝŶďŽůǀŽƌŵŝŐĞŶĂŶŽĚŽŵĞŝŶĞŶƚŽƚĞĞŶ ǀĞƌůĂŐŝŶŐǀĂŶĚĞŬƌŝƐƚĂůůŝƐĂƟĞƚĞŵƉĞƌĂƚƵƵƌ͘KƉĚĞnjĞŵĂŶŝĞƌǁŽƌĚƚĚĞŬƌŝƐƚĂůůŝƐĂƟĞŝŶĚĞ ŚŽŽŐƉŽůĂŝƌĞɴͲĨĂƐĞĚŽŵŝŶĂŶƚ͘ŝƚǁĞƌŬůĂĂƚŚĞƚƉŽƚĞŶƟĞĞůnjŝĞŶǀĂŶďůŽŬĐŽƉŽůLJŵĞĞƌ ŵĞƚŚŽĚĞƐǀŽŽƌĞůĞŬƚƌŝƐĐŚĞĞŶĞƌŐŝĞŽƉƐůĂŐ͕ǁĂĂƌŝŶĚĞĨĞƌƌŽĞůĞŬƚƌŝƐĐŚĞɴͲƉŚĂƐĞŐĞǁĞŶƐƚŝƐ͘ /Ŷ ŚŽŽĨĚƐƚƵŬ ϯ njŝũŶ ďůŽŬ ĐŽƉŽůLJŵĞƌĞŶ͕ ĚŝĞ ƉŽůLJ;ǀŝŶLJůŝĚĞĞŶ ĨůƵŽƌŝĚĞ-co-ƚƌŝŇƵŽƌŽĞƚŚLJůĞĞŶͿ;W;s&-co-dƌ&ͿͿďĞǀĂƩĞŶ͕ŽŶĚĞƌnjŽĐŚƚŽŵŝŶnjŝĐŚƚƚĞŐĞǀĞŶŽƉŚĞƚĞīĞĐƚ van de domein muur polariteit op de Curie overgangstemperatuur. De Curie overgang ŝƐĞĞŶŬƌŝƐƚĂůůŝũŶĞĨĞƌƌŽĞůĞŬƚƌŝƐĐŚŶĂĂƌƉĂƌĂĞůĞŬƚƌŝƐĐŚĞĨĂƐĞŽǀĞƌŐĂŶŐ;ĞŶvice versaͿ͘ŝƚ ŝƐŝŶƚĞƌĞƐƐĂŶƚŽŵĚĂƚƌŽŶĚĚĞƵƌŝĞŽǀĞƌŐĂŶŐŵĂdžŝŵĂůĞǁĂĂƌĚĞŶǀŽŽƌĚĞĚŝĞůĞŬƚƌŝƐĐŚĞ constante worden geobserveerd. Dit maakt dit soort polymeren uiterst geschikt voor ĚŝĞůĞŬƚƌŝƐĐŚĞ ĂƉƉůŝĐĂƟĞƐ͕ ŵĂĂƌ ŽŽŬ ǀŽŽƌ ŽƉ ǀĂƐƚĞ ƐƚŽĨ ŐĞďĂƐĞĞƌĚĞ ŬŽĞů ĂƉƉĂƌĂƚƵƵƌ ĚŽŽƌŚĞƚĞůĞŬƚƌŽĐĂůŽƌŝƐĐŚĞīĞĐƚ͘'ĞďƌƵŝŬŵĂŬĞŶĚǀĂŶĞĞŶǀĞƌŐĞůŝũŬďĂƌĞŵĞƚŚŽĚĞĂůƐ beschreven in hoofdstuk 2, triblok copolymeren, die of een polystyreen of poly(tertͲ ďƵƚŽdžLJƐƚLJƌĞĞŶͿ ĂůƐ ďƵŝƚĞŶƐƚĞ ďůŽŬ ŚĞďďĞŶ͕ njŝũŶ ŽŶƚǁŽƌƉĞŶ Žŵ ƚĞ njĞůĨ ĂƐƐĞŵďůĞƌĞŶ ŝŶ ƌŽŶĚĞ ŶĂŶŽĚŽŵĞŝŶĞŶ͘ ĞŶ ǀĞƌŚŽŐŝŶŐ ǀĂŶ ĚĞ ƉŽůĂƌŝƚĞŝƚ ǀĂŶ ĚĞ ĚŽŵĞŝŶ ŵƵƵƌ ŝƐ gerealiseerd door een in-situ hydrolyse van de tertͲďƵƚŽdžLJŐƌŽĞƉŵĞƚƚƌŝŇƵŽƌŽĂĐĞƟĐĂĐŝĚ͘ KƉĚĞnjĞŵĂŶŝĞƌ͕njŝũŶĚĞŶĂŶŽŬƌŝƐƚĂůůĞŶŝŶĚĞďŽůůĞŶďĞŚŽƵĚĞŶƚĞƌǁŝũůĚĞƉŽůĂƌŝƚĞŝƚǀĂŶ ĚĞŽŵƌŝŶŐĞŶĚĞŵĂƚƌŝdžŝƐǀĞƌŚŽŽŐĚ͘sĞƌŐĞůĞŬĞŶŵĞƚĚĞŽŶŐĞŵŽĚŝĮĐĞĞƌĚĞĐŽƉŽůLJŵĞƌĞŶ͕ njŽƌŐƚĚĞǀĞƌŚŽŽŐĚĞƉŽůĂƌŝƚĞŝƚǀĂŶĚĞŽŵƌŝŶŐĞŶĚĞŵĂƚƌŝdžǀŽŽƌĞĞŶǀĞƌůĂŐŝŶŐǀĂŶĚĞƵƌŝĞ ŽǀĞƌŐĂŶŐƐƚĞŵƉĞƌĂƚƵƵƌ͕ƚĞƌǁŝũůĞĞŶŶŽŶƉŽůĂŝƌĞŵĂƚƌŝdžƌĞƐƵůƚĞĞƌƚŝŶĞĞŶǀĞƌŚŽŐŝŶŐǀĂŶ de Curie overgangstemperatuur. Deze resultaten geven ontwerpparameters voor de ŵŝŶŝĂƚƵƌŝƐĂƟĞǀĂŶĂƉƉĂƌĂƚĞŶǀŽŽƌŐĞĂǀĂŶĐĞĞƌĚĞĞůĞŬƚƌŽŶŝƐĐŚĞƚŽĞƉĂƐƐŝŶŐĞŶ͘ Ws&ĞŶnjŝũŶŐĞŇƵŽƌĞĞƌĚĞĐŽƉŽůLJŵĞƌĞŶŚĞďďĞŶĞĞŶŐĞďƌĞŬĂĂŶĨƵŶĐƟŽŶĂůŝƚĞŝƚĞŶŝŶ ĚĞƉŽůLJŵĞĞƌŬĞƚĞŶƐ͘ĂĂƌŽŵnjŝũŶǀĞƌĚĞƌĞŵŽĚŝĮĐĂƟĞƐŽŵĚĞĞŝŐĞŶƐĐŚĂƉƉĞŶǀĂŶWs& ƚĞ ǀĞƌďĞƚĞƌĞŶ ŵŽĞŝůŝũŬ͕ njŽĂůƐ ǀĞƌŶĞƚǁĞƌŬĞŶ͕ ŶĂŶŽĚĞĞůƚũĞƐ ĚŝƐƉĞƌƐŝĞ ĞŶ ŚĞĐŚƟŶŐ ĂĂŶ ŽƉƉĞƌǀůĂŬƚĞƐ͘ĂĂƌďƵŝƚĞŶnjŝũŶŇƵŽƌŽŵŽŶŽŵĞƌĞŶĚƵƵƌ͕njŽĚĂƚƚŽĞƉĂƐƐŝŶŐŽƉŐƌŽƚĞƐĐŚĂĂů ďĞůĞŵŵĞƌĚǁŽƌĚƚ͘/ŶŚŽŽĨĚƐƚƵŬϰŝƐĞĞŶŶŝĞƵǁĞŵĞƚŚŽĚĞŽŵĨƵŶĐƟŽŶĂůŝƚĞŝƚŝŶĚĞWs& ŬĞƚĞŶƚĞŬƌŝũŐĞŶŐĞŢŶƚƌŽĚƵĐĞĞƌĚ͘sŝŶLJůĂĐĞƚĂĂƚ;sĐͿ͕ĚĂƚĞĞŶŐŽĞĚŬŽŽƉŵŽŶŽŵĞĞƌŝƐ͕ ŝƐŐĞĐŽƉŽůLJŵĞƌŝƐĞĞƌĚŵĞƚs&ƌĞƐƵůƚĞƌĞŶĚŝŶW;s&-co-sĐͿĐŽƉŽůLJŵĞƌĞŶ͘ŽŽƌŚĞƚ ƚŽĞǀŽĞŐĞŶǀĂŶŬůĞŝŶĞŚŽĞǀĞĞůŚĞĚĞŶsĐĂĂŶŚĞƚƉŽůLJŵĞƌŝƐĂƟĞŵĞŶŐƐĞůĞŶŚĞƚŬŽƌƚ ŚŽƵĚĞŶǀĂŶĚĞƉŽůLJŵĞƌŝƐĂƟĞƟũĚ͕njŝũŶϭϬĞŶϭϱŵŽůйsĐŝŶŐĞďŽƵǁĚŝŶĚĞĐŽƉŽůLJŵĞƌĞŶ ĞŶůĂƚĞŶnjŝĞŶŚŽŵŽŐĞĞŶǀĞƌĚĞĞůĚƚĞnjŝũŶ͘,LJĚƌŽůLJƐĞǀĂŶW;s&-co-sĐͿĐŽƉŽůLJŵĞƌĞŶ ŶĂĂƌĚĞǀŝŶLJůĂůĐŽŚŽůƚĞŐĞŶŚĂŶŐĞƌǀĂŶĚŝƚƉŽůLJŵĞĞƌ͕W;s&-co-sͿĐŽƉŽůLJŵĞĞƌůĞŝĚƚƚŽƚ ĂĂŶƐƉƌĞŬĞŶĚŬƌŝƐƚĂůůŝƐĂƟĞŐĞĚƌĂŐ͘ĞŝŶƚƌŽĚƵĐƟĞǀĂŶĚĞĨĞĐƚĞŶŝŶĚĞŬĞƚĞŶĞŶĚĞŬůĞŝŶĞ

529927-L-sub01-bw-Meereboer 529927-L-sub01-bw-Meereboer 529927-L-sub01-bw-Meereboer 529927-L-sub01-bw-Meereboer Processed on: 21-3-2019 Processed on: 21-3-2019 Processed on: 21-3-2019

Processed on: 21-3-2019 PDF page: 133PDF page: 133PDF page: 133PDF page: 133

133 Samenvatting

A

ŐƌŽŽƩĞǀĂŶsĞĞŶŚĞĚĞŶůĞŝĚƚƚŽƚĞĞŶǀĞƌĂŶĚĞƌŝŶŐŝŶŚĞƚŬƌŝƐƚĂůůŝƐĂƟĞŐĞĚƌĂŐĞŶŝŶƐůƵŝƟŶŐ ǀĂŶsŝŶĚĞŬƌŝƐƚĂůůĞŶ͘ĞŶŵĞŶŐƐĞůǀĂŶɲͲĞŶɴͲĨĂƐĞWs&ŝƐǀĞƌŬƌĞŐĞŶŵĞƚϭϬŵŽůй sŝŶĚĞƉŽůLJŵĞĞƌŬĞƚĞŶ͕ǁĂĂƌĐŽƉŽůLJŵĞƌĞŶŵĞƚϭϱŵŽůйsĂůůĞĞŶŬƌŝƐƚĂůůŝƐĞƌĞŶŝŶĚĞ ĨĞƌƌŽĞůĞŬƚƌŝƐĐŚĞɴͲĨĂƐĞ͘ŝƚůĞŝĚƚƚŽƚůŝŶĞĂŝƌĚŝĞůĞŬƚƌŝƐĐŚŐĞĚƌĂŐǁĂŶŶĞĞƌĞĞŶŵĞŶŐƐĞů ǀĂŶĚĞɲͲĞŶɴͲĨĂƐĞnjŝũŶǀĞƌŬƌĞŐĞŶĞŶnjŽĂůƐǀĞƌǁĂĐŚƚĨĞƌƌŽĞůĞŬƚƌŝƐĐŚŐĞĚƌĂŐŝŶɴͲĨĂƐĞ W;s&-co-sͿ͘ŝƚŶŽŶůŝŶĞĂŝƌĞƉŽůĂƌŝƐĂƟĞŐĞĚƌĂŐŝŶĚĞnjĞĐŽƉŽůLJŵĞƌĞŶŝƐǀŽŽƌĚĞůŝŐŽŵ veel energie in het materiaal op te slaan en wordt verder onderzocht voor elektronische toepassingen zoals beschreven in hoofdstuk 5.

/Ŷ ŚŽŽĨĚƐƚƵŬ ϱ ŝƐ ŚĞƚ ĞīĞĐƚ ǀĂŶ ŚĞƚ ĐŚĞŵŝƐĐŚ ǀĞƌŶĞƚǁĞƌŬĞŶ ŽƉ ĚĞ ĞůĞŬƚƌŝƐĐŚĞ ĞŝŐĞŶƐĐŚĂƉƉĞŶǀĂŶW;s&-co-sͿŽŶĚĞƌnjŽĐŚƚ͘ĞĐŽƉŽůLJŵĞƌĞŶnjŝũŶǀĞƌŶĞƚǁĞƌŬƚvia een ŵĂŬŬĞůŝũŬĞŽƉƵƌĞƚŚĂĂŶŐĞďĂƐĞĞƌĚĞǀĞƌŶĞƚǁĞƌŬŝŶŐƐŵĞƚŚŽĚĞ͘KƉĚĞnjĞŵĂŶŝĞƌnjŝũŶĚĞ kristallen klein en geïsoleerd, hetgeen leidt tot verbeterde elektrische eigenschappen. De dielektrische sterkte is verhoogd zorgend voor een verhoogde energie opslag in de ŵĂƚĞƌŝĂůĞŶ͘ŽǀĞŶĚŝĞŶŝƐĞĞŶǀĞƌĂŶĚĞƌŝŶŐǀĂŶĨĞƌƌŽĞůĞŬƚƌŝƐĐŚŶĂĂƌĂŶƟͲĨĞƌƌŽĞůĞŬƚƌŝƐĐŚ ĞŶůŝŶĞĂŝƌĚŝĞůĞŬƚƌŝƐĐŚŐĞĚƌĂŐǁĂĂƌŐĞŶŽŵĞŶďŝũĞĞŶǀĞƌŚŽŐĞŶĚĞŵĂƚĞǀĂŶǀĞƌŶĞƚǁĞƌŬŝŶŐ͘ ŝƚůĞŝĚƚƚŽƚĞĞŶŚŽŐĞŽŶƚůĂĚŝŶŐƐĞŶĞƌŐŝĞĚŝĐŚƚŚĞŝĚĞŶĞĞŶǀĞƌďĞƚĞƌĞŶĚĞĞĸĐŝģŶƟĞ͘ĞnjĞ ŵĂƚĞƌŝĂůĞŶůĞǀĞƌĞŶǀĞĞůďĞƚĞƌĞƉƌĞƐƚĂƟĞƐĚĂŶĚĞŐŽƵĚĞŶƐƚĂŶĚĂĂƌĚ͕ďŝĂdžŝĂĂůŐĞŽƌŝģŶƚĞĞƌĚ ƉŽůLJƉƌŽƉLJůĞĞŶĞŶĚĞŵĞƚŚŽĚĞůĂĂƚnjŝĞŶĚĂƚŚĞƚĐŚĞŵŝƐĐŚǀĞƌŶĞƚǁĞƌŬĞŶǀĂŶWs&ŐƌŽƚĞ ŵŽŐĞůŝũŬŚĞĚĞŶďŝĞĚƚƚŽƚŚĞƚǀĞƌďĞƚĞƌĞŶǀĂŶĚŝĞůĞŬƚƌŝƐĐŚĞŵĂƚĞƌŝĂůĞŶ͘ /Ŷ ŚŽŽĨĚƐƚƵŬ ϲ͕ ŚĞƚ ůĂĂƚƐƚĞ ŚŽŽĨĚƐƚƵŬ ǀĂŶ Ěŝƚ ƉƌŽĞĨƐĐŚƌŝŌ͕ ǁŽƌĚĞŶ ŐĞŇƵŽƌĞĞƌĚĞ ƚĞƌƉŽůLJŵĞƌĞŶ͕ĚŝĞŬůĞŝŶĞŚŽĞǀĞĞůŚĞĚĞŶǀŝŶLJůĂůĐŽŚŽůďĞǀĂƩĞŶ͕ŐĞĚĞŵŽŶƐƚƌĞĞƌĚ͘,Ğƚ ƚŚĞƌŵŝƐĐŚŐĞĚƌĂŐǀĂŶĚĞnjĞW;s&-ter-dƌ&-ter-sͿƚĞƌƉŽůLJŵĞƌĞŶŝƐŽŶĚĞƌnjŽĐŚƚĞŶĞĞŶ sterke verlaging van de Curie overgangstemperatuur is waargenomen ten opzichte van ǀĞƌŐĞůŝũŬďĂƌĞW;s&-co-dƌ&ͿĐŽƉŽůLJŵĞƌĞŶ͘ĞŬƌŝƐƚĂůůĞŶnjŝũŶŬůĞŝŶĞŶďŽǀĞŶĚŝĞŶŝƐĞƌ ƌĞůĂƟĞĨŵĞĞƌƉĂƌĂĞůĞŬƚƌŝƐĐŚĞĨĂƐĞŐĞǀŽƌŵĚĚŽŽƌĚĂƚĞƌŵĞĞƌŝƐŽƚĂĐƟƐĐŚĞŵŽŶŽŵĞĞƌ ƐĞƋƵĞŶƟĞĂĂŶǁĞnjŝŐnjŝũŶ͘ŝƚůĞŝĚƚƚŽƚƌĞůĂdžŽƌĨĞƌƌŽĞůĞŬƚƌŝƐĐŚŐĞĚƌĂŐ͕ĞƌŐŐĞǁĞŶƐƚǀŽŽƌ ĐĂƉĂĐŝƟĞǀĞĞŶĞƌŐŝĞŽƉƐůĂŐĚŽŽƌĚĞŚŽŐĞĞĸĐŝģŶƟĞĞŶŽŶƚůĂĚŝŶŐƐĞŶĞƌŐŝĞĚŝĐŚƚŚĞŝĚ͘,Ğƚ chemisch netwerken van deze terpolymeren zorgt voor nog betere eigenschappen ĚŽŽƌĚĂƚĚĞďůŝũǀĞŶĚĞƉŽůĂƌŝƐĂƟĞŶĂŚĞƚǀĞƌǁŝũĚĞƌĞŶǀĂŶŚĞƚĞůĞŬƚƌŝƐĐŚǀĞůĚŶĂŐĞŶŽĞŐϬŝƐ͘ KƉĚĞnjĞŵĂŶŝĞƌnjŽƌŐƚĚĞĐŽŵďŝŶĂƟĞǀĂŶĨLJƐŝƐĐŚĞŶĐŚĞŵŝƐĐŚƉŝŶŶĞŶǀĂŶWs&ŬƌŝƐƚĂůůĞŶ voor een sterke verbetering van de elektrische eigenschappen voor dielektrische toepassingen.

529927-L-sub01-bw-Meereboer 529927-L-sub01-bw-Meereboer 529927-L-sub01-bw-Meereboer 529927-L-sub01-bw-Meereboer Processed on: 21-3-2019 Processed on: 21-3-2019 Processed on: 21-3-2019

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134 List of Publications

List of Publications

DĞĞƌĞďŽĞƌ͕E͘>͖͘dĞƌnjŝđ͕/͖͘^ĂŝĚŝ͕^͖͘,ĞƌŵŝĚĂDĞƌŝŶŽ͕͖͘>ŽŽƐ͕<͘EĂŶŽĐŽŶĮŶĞŵĞŶƚͲ /ŶĚƵĐĞĚɴͲWŚĂƐĞ&ŽƌŵĂƟŽŶ/ŶƐŝĚĞWŽůLJ;sŝŶLJůŝĚĞŶĞ&ůƵŽƌŝĚĞͿͲĂƐĞĚůŽĐŬŽƉŽůLJŵĞƌƐ͘ ^DĂĐƌŽ>ĞƩĞƌƐ ϮϬϭϴ͕ϴϲϯʹϴϲϳ͘K/͗ϭϬ͘ϭϬϮϭͬĂĐƐŵĂĐƌŽůĞƩ͘ϴďϬϬϰϭϴ͘ DĞĞƌĞďŽĞƌ͕E͘>͖͘ΎdĞƌnjŝĐ͕/͘Ύ͖DĞůůĞŵĂ͕,͘,͖͘͘WŽƌƚĂůĞ͕'͖͘>ŽŽƐ͕<͘WƌŽŶŽƵŶĐĞĚ^ƵƌĨĂĐĞ īĞĐƚƐ ŽŶ ƚŚĞ ƵƌŝĞ dƌĂŶƐŝƟŽŶ dĞŵƉĞƌĂƚƵƌĞ ŝŶ EĂŶŽĐŽŶĮŶĞĚ W;s&Ͳdƌ&Ϳ ƌLJƐƚĂůƐ͘ Macromolecules ϮϬϭϵ͕ϱϮ͕ϭϱϲϳͲϭϱϳϲ͘K/͗ϭϬ͘ϭϬϮϭͬĂĐƐ͘ŵĂĐƌŽŵŽů͘ϴďϬϮϯϴϮ DĞĞƌĞďŽĞƌ͕ E͘ >͖͘ dĞƌnjŝđ͕ /͖͘ ǀĂŶ ĚĞƌ ^ƚĞĞŐ͕ W͖͘ ĐƵĂƵƚůĂ͕ D͖͘ sŽĞƚ͕ s͘ ^͘ ͖͘ >ŽŽƐ͕ <͘ ůĞĐƚƌŽĂĐƚŝǀĞ ĞŚĂǀŝŽƌ ŽŶ ĞŵĂŶĚ ŝŶ WŽůLJ;sŝŶLJůŝĚĞŶĞ &ůƵŽƌŝĚĞͲŽͲsŝŶLJů ůĐŽŚŽůͿ Copolymers. Materials Today Energy ϮϬϭϵ͕ϭϭ͕ϴϯʹϴϴ͘K/͗ϭϬ͘ϭϬϭϲͬũ͘ŵƚĞŶĞƌ͘ϮϬϭϴ͘ϭϬ͘Ϭϭϵ͘

DĞĞƌĞďŽĞƌ͕E͘>͖͘dĞƌnjŝđ͕/͖͘>ŽŽƐ͕<͘dƵŶŝŶŐƚŚĞĚŝĞůĞĐƚƌŝĐďĞŚĂǀŝŽƌŽĨƉŽůLJ;ǀŝŶLJůŝĚĞŶĞ

ŇƵŽƌŝĚĞͲcoͲǀŝŶLJůĂůĐŽŚŽůͿƵƐŝŶŐĂĨĂĐŝůĞƵƌĞƚŚĂŶĞͲďĂƐĞĚĐƌŽƐƐůŝŶŬŝŶŐŵĞƚŚŽĚ͘Polymer

Chemistry ϮϬϭϵ͕ϭϬ͕ϭϯϯϱͲϭϯϰϯ͘K/͗ϭϬ͘ϭϬϯϵͬϴWzϬϭϴϬϮ

DĞĞƌĞďŽĞƌ͕E͘>͖͘dĞƌnjŝđ͕/͖͘^ƚĞĞŐ͕W͘ǀĂŶĚĞƌ͖WŽƌƚĂůĞ͕'͖͘>ŽŽƐ͕<͘WŚLJƐŝĐĂůWŝŶŶŝŶŐĂŶĚ

ŚĞŵŝĐĂůƌŽƐƐůŝŶŬŝŶŐͲ/ŶĚƵĐĞĚZĞůĂdžŽƌ&ĞƌƌŽĞůĞĐƚƌŝĐĞŚĂǀŝŽƌŝŶW;s&ͲterͲdƌ&ͲterͲsͿ Terpolymers. Journal of Materials Chemistry A ϮϬϭϵ, 7;ϲͿ͕ϮϳϵϱʹϮϴϬϯ͘K/͗ϭϬ͘ϭϬϯϵͬ ϴdϭϭϱϯϰ&͘

dĞƌnjŝđ͕/͘Ύ͖DĞĞƌĞďŽĞƌ͕E͘>͘Ύ͖ĐƵĂƵƚůĂ͕D͖͘WŽƌƚĂůĞ͕'͖͘>ŽŽƐ͕<͘ůĞĐƚƌŽĂĐƟǀĞDĂƚĞƌŝĂůƐ ǁŝƚŚdƵŶĂďůĞZĞƐƉŽŶƐĞĂƐĞĚŽŶůŽĐŬŽƉŽůLJŵĞƌ^ĞůĨͲƐƐĞŵďůLJ͘EĂƚƵƌĞŽŵŵƵŶŝĐĂƟŽŶƐ

ϮϬϭϵ, 10;ϭͿ͕ϲϬϭ͘K/͗ϭϬ͘ϭϬϯϴͬƐϰϭϰϲϳͲϬϭϵͲϬϴϰϯϲͲϮ

dĞƌnjŝđ͕ /͖͘ DĞĞƌĞďŽĞƌ͕ E͘ >͖͘ DĞůůĞŵĂ͕ ,͘ ,͖͘ >ŽŽƐ͕ <͘ WŽůLJŵĞƌͲĂƐĞĚ DƵůƟĨĞƌƌŽŝĐ EĂŶŽĐŽŵƉŽƐŝƚĞƐ ǀŝĂ ŝƌĞĐƚĞĚ ůŽĐŬ ŽƉŽůLJŵĞƌ ^ĞůĨͲƐƐĞŵďůLJ͘ Journal of Materials

Chemistry C ϮϬϭϵ, 7;ϰͿ͕ϵϲϴʹϵϳϲ͘K/͗ϭϬ͘ϭϬϯϵͬϴdϬϱϬϭϳ͘ dĞƌnjŝĐ͕/͖͘DĞĞƌĞďŽĞƌ͕E͘>͖͘ĐƵĂƵƚůĂ͕D͖͘WŽƌƚĂůĞ͕'͖͘>ŽŽƐ͕<͘dĂŝůŽƌĞĚ^ĞůĨͲƐƐĞŵďůĞĚ &ĞƌƌŽĞůĞĐƚƌŝĐWŽůLJŵĞƌEĂŶŽƐƚƌƵĐƚƵƌĞƐǁŝƚŚdƵŶĂďůĞZĞƐƉŽŶƐĞ͘Macromolecules ϮϬϭϵ, 52 ;ϭͿ͕ϯϱϰʹϯϲϰ͘K/͗ϭϬ͘ϭϬϮϭͬĂĐƐ͘ŵĂĐƌŽŵŽů͘ϴďϬϮϭϯϭ͘ dĞƌnjŝĐ͕/͖͘DĞĞƌĞďŽĞƌ͕E͘>͖͘>ŽŽƐ͕<͘ƵůŝĐŬŚĞŵŝƐƚƌLJ͗sĞƌƐĂƟůĞƉƉƌŽĂĐŚƚŽǁĂƌĚƐ Ws&ͲĂƐĞĚůŽĐŬŽƉŽůLJŵĞƌƐ͘Polymer Chemistry ϮϬϭϴ, 9;ϮϳͿ͕ϯϳϭϰʹϯϳϮϬ͘K/͗ϭϬ͘ϭϬϯϵͬ ϴWzϬϬϳϰϮ:͘

529927-L-sub01-bw-Meereboer 529927-L-sub01-bw-Meereboer 529927-L-sub01-bw-Meereboer 529927-L-sub01-bw-Meereboer Processed on: 21-3-2019 Processed on: 21-3-2019 Processed on: 21-3-2019

Processed on: 21-3-2019 PDF page: 135PDF page: 135PDF page: 135PDF page: 135

135 List of Publications

A

sŽĞƚ͕s͘^͖͘͘ŬĞŶƐƚĞŝŶ͕'͘K͘Z͘͘ǀĂŶ͖DĞĞƌĞďŽĞƌ͕E͘>͖͘,ŽĨŵĂŶ͕͘,͖͘ƌŝŶŬĞ͕'͘ƚĞŶ͖ >ŽŽƐ͕<͘ŽƵďůĞͲƌLJƐƚĂůůŝŶĞW>>ͲďͲWs&ͲďͲW>>dƌŝďůŽĐŬŽƉŽůLJŵĞƌƐ͗WƌĞƉĂƌĂƟŽŶĂŶĚ ƌLJƐƚĂůůŝnjĂƟŽŶ͘Polymer Chemistry ϮϬϭϰ, 5;ϳͿ͕ϮϮϭϵʹϮϮϯϬ͘K/͗ϭϬ͘ϭϬϯϵͬϯWzϬϭϱϲϬ͘ DĞĞƌĞďŽĞƌE͘>͘Ύ͖dĞƌnjŝĐ͕/Ύ͖WŽƌƚĂůĞ͕'͖͘>ŽŽƐ͕<͘/ŵƉƌŽǀĞĚĞŶĞƌŐLJĚĞŶƐŝƚLJĂŶĚĐŚĂƌŐĞͲ ĚŝƐĐŚĂƌŐĞĞĸĐŝĞŶĐLJŝŶƐŽůƵƟŽŶƉƌŽĐĞƐƐĞĚŚŝŐŚůLJĚĞĮŶĞĚĨĞƌƌŽĞůĞĐƚƌŝĐďůŽĐŬĐŽƉŽůLJŵĞƌͲ ďĂƐĞĚĚŝĞůĞĐƚƌŝĐŶĂŶŽĐŽŵƉŽƐŝƚĞƐ;ƐƵďŵŝƩĞĚͿ ΎďŽƚŚĂƵƚŚŽƌƐĐŽŶƚƌŝďƵƚĞĚĞƋƵĂůůLJ

529927-L-sub01-bw-Meereboer 529927-L-sub01-bw-Meereboer 529927-L-sub01-bw-Meereboer 529927-L-sub01-bw-Meereboer Processed on: 21-3-2019 Processed on: 21-3-2019 Processed on: 21-3-2019

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Acknowledgements

Acknowledgements

&ŝƌƐƚ͕/ǁŽƵůĚůŝŬĞƚŽƚŚĂŶŬŵLJƉƌŽŵŽƚŽƌ͗ƉƌŽĨ͘Ěƌ͘<ĂƚũĂ>ŽŽƐ͘dŽǁŽƌŬŝŶŚĞƌƌĞƐĞĂƌĐŚ group, Macromolecular Chemistry and New Polymeric Materials, gave me a great ŽƉƉŽƌƚƵŶŝƚLJƚŽĚĞǀĞůŽƉŵLJƐĞůĨ͘ƐƉĞĐŝĂůůLJ͕ƚŚĞĚĞŐƌĞĞƐŽĨĨƌĞĞĚŽŵĞdžƉĞƌŝĞŶĐĞĚĂŶĚƚŚĞ ŇĞdžŝďŝůŝƚLJŝŶĚĞǀĞůŽƉŝŶŐƚŚĞƌĞƐĞĂƌĐŚƉƌŽũĞĐƚƐ͕ǁŚĞƌĞŝŶ/ŐŽƚĂĐƋƵĂŝŶƚĞĚǁŝƚŚŶƵŵĞƌŽƵƐ ƌĞƐĞĂƌĐŚƚĞĐŚŶŝƋƵĞƐ͕ŵĂĚĞŝƚĂǀĞƌLJũŽLJĨƵůƟŵĞ͘ĞƐŝĚĞƐƚŚŝƐ͕ǁŚĞŶĞǀĞƌ/ŶĞĞĚĞĚĂĚǀŝĐĞ ŽƌŚĞůƉ͕ƚŚĞĚŽŽƌǁĂƐĂůǁĂLJƐŽƉĞŶ͕ǁŚŝĐŚŝƐĂƉƉƌĞĐŝĂƚĞĚĂůŽƚ͘KǀĞƌƚŚĞLJĞĂƌƐ͕ĮƌƐƚĚŽŝŶŐ my bachelor in the polymer chemistry department followed by the polymer chemistry ŵĂƐƚĞƌ͕/ŐŽƚĂĐƋƵĂŝŶƚĞĚǁŝƚŚƚŚĞŶŝĐĞǁŽƌŬ͕ƚŽƉŝĐƐĂŶĚĂƚŵŽƐƉŚĞƌĞŝŶŚĞƌŐƌŽƵƉ͘/Ăŵ ǀĞƌLJŐƌĂƚĞĨƵůƚŚĂƚ/ĐŽƵůĚĮŶŝƐŚŵLJƟŵĞĂƚƚŚĞhŶŝǀĞƌƐŝƚLJŽĨ'ƌŽŶŝŶŐĞŶǁŝƚŚĂWŚŝŶŚĞƌ group. ŵ͘ƉƌŽĨ͘Ěƌ͘'ĞƌƌŝƚƚĞŶƌŝŶŬĞŝƐŬŝŶĚůLJĂĐŬŶŽǁůĞĚŐĞĚĨŽƌďĞŝŶŐŵLJĐŽͲƉƌŽŵŽƚŽƌ͘ /ĂůƐŽǁŽƵůĚůŝŬĞƚŽƚŚĂŶŬƚŚĞŵĞŵďĞƌƐŽĨƚŚĞƌĞĂĚŝŶŐĐŽŵŵŝƩĞĞ͕ƉƌŽĨ͘Ěƌ͘ƌƵŶŽ ŵĞĚƵƌŝ͕ ƉƌŽĨ͘ Ěƌ͘ Žƌ <ŽŶŝŶŐ͕ ĂŶĚ ƉƌŽĨ͘ Ěƌ͘ &ƌĂŶĐĞƐĐŽ WŝĐĐŚŝŽŶŝ͘ dŚĞŝƌ ĐŽŶƐƚƌƵĐƟǀĞ ĨĞĞĚďĂĐŬĂŶĚƵƐĞĨƵůŝŶƐŝŐŚƚŚĞůƉĞĚŝŵƉƌŽǀŝŶŐƚŚĞƋƵĂůŝƚLJŽĨƚŚŝƐƚŚĞƐŝƐ͘

This work wasn’t possible without proper funding. Therefore, I would like to thank EtKĨŽƌƚŚĞEtKǀŝĐŝŝŶŶŽǀĂƟŽŶĂůŐƌĂŶƚŐŝǀĞŶƚŽƚŚĞ>ŽŽƐŐƌŽƵƉĨŽƌĨƵŶĚŝŶŐƚŚĞƐĞ ƉƌŽũĞĐƚƐ͘

/ǀĂŶ͕ƚŚŝƐĚŝƐƐĞƌƚĂƟŽŶŝƐĂĐĐŽŵƉůŝƐŚĞĚĚƵĞƚŽƚŚĞŝŶƚĞŶƐŝǀĞĐŽůůĂďŽƌĂƟŽŶďĞƚǁĞĞŶƵƐ͘ ^ŝŶĐĞƚŚĞƐƚĂƌƚŽĨŽƵƌWŚƚƌĂũĞĐƚŽƌLJ͕LJŽƵƚǁŽǁĞĞŬƐĂŌĞƌŵĞ͕ǁĞŚĂǀĞǁŽƌŬĞĚƚŽŐĞƚŚĞƌ in more of less every step of the research. In every chapter you had your input and I’m ŐƌĂƚĞĨƵůĨŽƌLJŽƵƌĐŽŶƚƌŝďƵƟŽŶƐ͘

DĂƌƟũŶ͕ĐŚĞĨ͕ŵŽůĞĐƵůĂƌĚĞƐŝŐŶďƌŽƵŐŚƚƵƐƚŽŐĞƚŚĞƌĂŶĚĮŶĂůůLJŵĂĚĞŵĞĚĞĐŝĚĞƚŽ follow you and do polymer chemistry. I followed you to Berkeley as well, where we drank ŶŝĐĞůLJƚĂƐƟŶŐ/W͛ƐĨƌŽŵĂũĞůůLJďŽƩůĞ;ĂŶĚƐŽŵĞŵŽƌĞƚŚŝŶŐƐŚĂƉƉĞŶĞĚͿĂŶĚǁĞǁĞŶƚƚŽ &ƌĂŶĐĞĐůŝŵďŝŶŐƚŚĞDŽŶƚsĞŶƚŽƵdžŝŶĂŶĂƌĐĂĚŝĐ͕ŝĚLJůůŝĐƐƵƌƌŽƵŶĚŝŶŐ͕ũƵƐƚůŝŬĞ>ŝŵďƵƌŐ͘ 'ƌĞĂƚŵĞŵŽƌŝĞƐ͘dŚĂŶŬƐLJŽƵĨŽƌƉŽŝŶƟŶŐŵĞŝŶƚŚŝƐĚŝƌĞĐƟŽŶĂŶĚĨŽƌďĞŝŶŐĂĨƌŝĞŶĚĂŶĚ now also paranimph.

<ĂƌŝŶ͕ǁŝƚŚŽƵƚŚĂǀŝŶŐĂŐŽŽĚŽƌŐĂŶŝnjĂƟŽŶƚŚĂƚŐĞƚƚŚŝŶŐƐĚŽŶĞ͕ǁĞĂƌĞŶŽǁŚĞƌĞ during our PhD. Besides that you are cool and a nice person to talk to. I would like to thank you for the work you’ve done and for being who you are.

,Ăƌŵ,ĞŶĚƌŝŬ͕ǁŝƚŚƐƉĞĐŝĂůĂƩĞŶƟŽŶƚŽ,Ăƌŵ,ĞŶĚƌŝŬ͕ƐŝŶĐĞ,Ăƌŵ,ĞŶĚƌŝŬŝƐŚŝƐ ĮƌƐƚŶĂŵĞ͘dŚĂŶŬLJŽƵĨŽƌďĞŝŶŐŵLJďĂĐŚĞůŽƌƐƚƵĚĞŶƚĂŶĚŚĞůƉŝŶŐŝŶƚŚĞƵƌŝĞƚƌĂŶƐŝƟŽŶ ƉƌŽũĞĐƚ͘zŽƵƌƐLJŶƚŚĞƐŝƐĂŶĚĮƌƐƚĞdžƉůŽƌĂƟŽŶƐƉƌŽǀŝĚĞĚƚŚĞŐƵŝĚĞůŝŶĞƐŝŶǁŚŝĐŚĚŝƌĞĐƟŽŶƐ ƚŽŐŽƚŽĂŶĚĮŶĂůůLJƌĞƐƵůƚĞĚŝŶĂƉƵďůŝĐĂƟŽŶ͘/ŚŽƉĞLJŽƵůĞĂƌŶĞĚĂůŽƚ͕ǁŝůůƐƵĐĐĞĞĚŝŶĂ future career and start to eat vegetables.

WŝĞƚ͕LJŽƵĐĂŵĞĂƚƚŚĞƌŝŐŚƚŵŽŵĞŶƚƚŽĚŽLJŽƵƌŵĂƐƚĞƌ͛ƐƉƌŽũĞĐƚŽŶƚŚĞW;s&ͲcoͲsͿͲ ďĂƐĞĚƉƌŽũĞĐƚƐ͘ƵĞƚŽLJŽƵƌƉƌĞƐĞŶĐĞ͕ƚŚĞƐĞƉƌŽũĞĐƚƐŵŽǀĞĚĨŽƌǁĂƌĚĂŶĚ/ǁŽƵůĚůŝŬĞƚŽ

529927-L-sub01-bw-Meereboer 529927-L-sub01-bw-Meereboer 529927-L-sub01-bw-Meereboer 529927-L-sub01-bw-Meereboer Processed on: 21-3-2019 Processed on: 21-3-2019 Processed on: 21-3-2019

Processed on: 21-3-2019 PDF page: 137PDF page: 137PDF page: 137PDF page: 137

137 Acknowledgements

A

ƚŚĂŶŬLJŽƵĨŽƌLJŽƵƌƐLJƐƚĞŵĂƟĐĂŶĂůLJƐŝƐŽĨƚŚĞĐŽͲĂŶĚƚĞƌƉŽůLJŵĞƌƐ͘ĞƐŝĚĞƐƚŚŝƐ͕LJŽƵĂƌĞ ĂŬŝŶĚĂŶĚƉůĞĂƐĂŶƚƉĞƌƐŽŶƚŽǁŽƌŬǁŝƚŚĂŶĚ/ŚŽƉĞLJŽƵĞŶũŽLJĞĚŽƵƌƚƌŝƉƚŽ'ƌĞŶŽďůĞ͘ dŚĞƉĂƐƚLJĞĂƌƐ͕ƚŚĞƚĞĐŚŶŝĐŝĂŶŝŶƚŚĞ>ŽŽƐŐƌŽƵƉŚĂǀĞĐŽŶƚƌŝďƵƚĞĚƐŝŐŶŝĮĐĂŶƚůLJƚŽƚŚŝƐ ƌĞƐĞĂƌĐŚĂƐǁĞůů͘&ŝƌƐƚ͕ůďĞƌƚtŽŽƌƚŵĂŶ͕ĂƉůĞĂƐĂŶƚLJŽƵŶŐŵĂŶƚŽǁŽƌŬǁŝƚŚĂůůƚŚĞǁĂLJ ĨƌŽŵsĂŝŶĚĂŵ͕ďƵƚƉƌĞĨĞƌĂďůLJŝŶ/ƚĂůLJ͘,ĞƉĞƌĨŽƌŵĞĚ'WŵĞĂƐƵƌĞŵĞŶƚƐ͕ŬĞƉƚƚŚĞ&d/Z ƌƵŶŶŝŶŐĂŶĚĂůǁĂLJƐǁĂƐĂǀĂŝůĂďůĞǁŚĞŶ/ŽĨĐŽƵƌƐĞƋƵŝĐŬůLJŶĞĞĚĞĚĂŶŽƚŚĞƌŵĞĂƐƵƌĞŵĞŶƚ ƚŽƐƉĞĞĚƵƉǁŽƌŬ͘^ĞĐŽŶĚ͕:ƵƌǀĂŶŝũŬĞŶ͕ĂŶŽƚŚĞƌLJŽƵŶŐŵĂŶ͕ƌƵŶŶŝŶŐƚŚĞƚŚĞƌŵĂůĂŶĚ ŵĞĐŚĂŶŝĐĂůĂŶĂůLJƐŝƐůĂď͘dŚĂŶŬLJŽƵĨŽƌƚŚĞd'ŵĞĂƐƵƌĞŵĞŶƚƐĂŶĚŬĞĞƉŝŶŐƚŚĞ^ running. DLJĮƌƐƚĞdžƉĞƌŝĞŶĐĞǁŝƚŚƌ͘'ŝƵƐĞƉƉĞWŽƌƚĂůĞǁĂƐŝŶ'ƌĞŶŽďůĞĂƚ^Z&ĚƵƌŝŶŐŵLJ ŵĂƐƚĞƌ͛Ɛ͘:ƵƐƚǁŚĞŶ/ƐƚĂƌƚĞĚŵLJWŚ͕'ŝƵƐĞƉƉĞƐƚĂƌƚĞĚŚŝƐŽǁŶŐƌŽƵƉĂƚŽƵƌŇŽŽƌ͘ 'ŝƵƐĞƉƉĞ͕/ǁŽƵůĚůŝŬĞƚŽƚŚĂŶŬLJŽƵĨŽƌĂůůLJŽƵƌŝŶƐŝŐŚƚƐƌĞŐĂƌĚŝŶŐƚŚĞŵƵůƟƉůĞƉƌŽũĞĐƚƐ ǁĞŚĂǀĞĚŝƐĐƵƐƐĞĚĂŶĚĐŽͲǁŽƌŬĞĚ͘/ŶĂĚĚŝƟŽŶ͕LJŽƵƌŬŶŽǁůĞĚŐĞĂďŽƵƚ^y^ĂŶĚty^ ƉƌŽǀŝĚĞĚ ǀĂůƵĂďůĞ ŝŶƐŝŐŚƚƐ ŝŶ ƚŚĞ ƉŽůLJŵĞƌƐ ƵƐĞĚ ŝŶ ƚŚĞ ĐŽŶƚĞdžƚ ŽĨ ƚŚŝƐ ĚŝƐƐĞƌƚĂƟŽŶ͘ Moreover, you are also a very social person, appreciated a lot.

ƌ͘ĂŶŝĞů,ĞƌŵŝĚĂDĞƌŝŶŽ͕ǁŽƌŬŝŶŐĂƚƚŚĞ^Z&ŝŶ'ƌĞŶŽďůĞ͕ĂůƐŽĚĞƐĞƌǀĞƐĂƐƉĞĐŝĂů ƚŚĂŶŬƐ͘tŚĞŶĞǀĞƌƚŚĞďĞĂŵůŝŶĞĚŝĚŶ͛ƚĚŽǁŚĂƚǁĞǁĂŶƚ͕ĂŶŝĞůĂůǁĂLJƐŚĞůƉĞĚĂŶĚƐƚŽŽĚ ƐƚĂŶĚͲďLJ͘/ŶĂĚĚŝƟŽŶ͕ĂŶŝĞůĂůǁĂLJƐƚŽŽŬƐƉĞĐŝĂůƟŵĞƚŽĞdžƉůĂŝŶŵŽƌĞĚĞƚĂŝůƐĂďŽƵƚƚŚĞ ^y^ͬty^ƐLJƐƚĞŵŝŶĐĂƐĞƐŽŵĞƚŚŝŶŐǁĂƐĐŚĂŶŐĞĚ͕ǁŚŝĐŚǁĂƐĂůǁĂLJƐƚŚĞĐĂƐĞ͘dŚĂŶŬƐ for all your help.

&ƌŽŵƚŚĞŶĂŶŽƐƚƌƵĐƚƵƌĞƐĂŶĚĨƵŶĐƟŽŶĂůŽdžŝĚĞƐŐƌŽƵƉŝŶŽƵƌďƵŝůĚŝŶŐ͕/ǁŽƵůĚůŝŬĞ ƚŽƚŚĂŶŬƉƌŽĨ͘Ěƌ͘ĞĂƚƌŝnjEŽŚĞĚĂĂŶĚĚƌ͘DŽŶŝĐĂĐƵĂƵƚůĂ͘dŚĞLJĐŽŶƚƌŝďƵƚĞĚŝŶĨƌƵŝƞƵů discussion regarding the electronic measurements. Besides this, Monica also provided ŐƌĞĂƚŚĞůƉŝŶƉĞƌĨŽƌŵŝŶŐƚŚĞŵĞĂƐƵƌĞŵĞŶƚƐ͕ǁŚŝĐŚĂƌĞĂĐƌƵĐŝĂůĐŽŶƚƌŝďƵƟŽŶƚŽƚŚŝƐ thesis. DLJŽĸĐĞŵĂƚĞƐ͕ĮƌƐƚDĂƐLJŝƚŚĂĂŶĚůĂƚĞƌĂůƐŽ:ƵĚŝƚŚ͕LJŽƵĂƌĞǀĞƌLJŬŝŶĚĂŶĚ/ĂŵŚĂƉƉLJ ƚŽŚĂǀĞƐŚĂƌĞĚĂŶŽĸĐĞǁŝƚŚLJŽƵ͘ŝŶĂ͕ƚŚĞŐŝƌůŶĞdžƚĚŽŽƌ͕ƐŚŽƵůĚŶŽƚďĞĨŽƌŐŽƩĞŶ;ĂŶĚ ŽǀĞƌůŽŽŬĞĚͿ͘zŽƵĂƌĞĂůǁĂLJƐǁŝůůŝŶŐƚŽƉƌŽǀŝĚĞŚĞůƉǁŚĞŶŶĞĞĚĞĚĂŶĚƚŚĂƚŝƐĂƉƉƌĞĐŝĂƚĞĚ ĂůŽƚ͘DŽƌĞŽǀĞƌ͕ƚŚĞũŽŬĞƐǁĞŵĂĚĞŝŶƚŚĞŽĸĐĞǁĞƌĞŽĨŐƌĞĂƚĨƵŶ͘/͕ŽĨĐŽƵƌƐĞ͕ŚĂǀĞƚŽ ƚŚĂŶŬDĂƐLJŝƚŚĂĨŽƌƚŚĞ͚WĞŶŝƐŬŽŬĞƌƐ͛ďƌŽƵŐŚƚĨƌŽŵƚŚĞWĂƉƵĂŶƚƌŝďĞ͘,ŽƉĞĨƵůůLJ͕ŽŶĞĚĂLJ I have balls to wear them with pride in public.

I would like to thank the current and former members of the Macromolecular ŚĞŵŝƐƚƌLJĂŶĚEĞǁWŽůLJŵĞƌŝĐDĂƚĞƌŝĂůƐŐƌŽƵƉŝŶ'ƌŽŶŝŶŐĞŶĨŽƌƚŚĞŐƌŽƵƉŵĞĞƟŶŐƐ͕ ĚŝƐĐƵƐƐŝŽŶƐ͕ĐŽŶĨĞƌĞŶĐĞƐ͕ĂŶĚƉƌŽǀŝĚŝŶŐĂƉůĞĂƐĂŶƚǁŽƌŬŝŶŐĂƚŵŽƐƉŚĞƌĞ͘ŶƚŽŶ͚ĚĞďĞĞƌ Ƶŝƚ^ĐŚĞĞŵĚĂ͛,ŽĨŵĂŶƚŚĂŶŬLJŽƵĨŽƌďĞŝŶŐŵLJůĂďŵĂƚĞĂŶĚƌŝŐŚƞƵůůLJĐŽŵƉůĂŝŶǁŚĞŶ I didn’t clean my mess. Marco, I am happy to have learned Italian sign language and ƉĞƌĨĞĐƟŽŶĂƚĞĚŵLJ/ƚĂůŝĂŶƉƌŽŶƵŶĐŝĂƟŽŶ͚͘ĨƌƵƫĚŝŵĂƌĞ͛͘

LJĐůŝŶŐǁĂƐŽŶĞŽĨŵLJŵĂŝŶŽĐĐƵƉĂƟŽŶŽƵƚƐŝĚĞĂĐĂĚĞŵŝĂĚƵƌŝŶŐŵLJWŚ͘dŚĞƌĞĨŽƌĞ͕ /ǁŽƵůĚůŝŬĞƚŽƚŚĂŶŬŵLJƚĞĂŵŵĞŵďĞƌƐĨƌŽŵtsĚĞ<ĂŶŶŝďĂĂůĨŽƌŐƌĞĂƚƌŝĚĞƐ͕ƚƌĂŝŶŝŶŐ

529927-L-sub01-bw-Meereboer 529927-L-sub01-bw-Meereboer 529927-L-sub01-bw-Meereboer 529927-L-sub01-bw-Meereboer Processed on: 21-3-2019 Processed on: 21-3-2019 Processed on: 21-3-2019

Processed on: 21-3-2019 PDF page: 138PDF page: 138PDF page: 138PDF page: 138

138 Acknowledgements ƐĞƐƐŝŽŶƐ͕ĂŶĚƌĂĐĞƐ͘/ŶƉĂƌƟĐƵůĂƌ͕DĞŶŶŽ͕ǁĞŚĂǀĞĐLJĐůĞĚĂůŽŶŐƚŚĞƉĂƐƚLJĞĂƌƐĂŶĚLJŽƵ ĂůǁĂLJƐŚĂǀĞŵŽƟǀĂƟŽŶ͘dŚĂŶŬƐ͘/ŶĂĚĚŝƟŽŶ͕ƚŚĞĐLJĐůŝŶŐƚƌŝƉƐǁŝƚŚ>ĞŶŶĂĞƌƚ͕:ĂŶ͕dŚŝũƐ ĂŶĚ>ĞŽŶ͕/ĞŶũŽLJĞĚĂůŽƚ͘tŝƚŚLJŽƵ/ŚĂǀĞĐLJĐůĞĚŝŶ&ƌĂŶĐĞ͕^ǁŝƚnjĞƌůĂŶĚ͕ƵƐƚƌŝĂ͕ĞůŐŝƵŵ͕ 'ƌŽŶŝŶŐĞŶ͕tĞƐƚĞƌďŽƌŬ͕ŶƵŵĂŶƟů͕ĂůůďĞĂƵƟĨƵůƉůĂĐĞƐƚŽĐLJĐůĞǁŝƚŚLJŽƵŐƵLJƐ͘

The group from Glimmen and surroundings are already friends since high school and ǀĂůƵĞĚĂůŽƚ͘ƐƉĞĐŝĂůůLJ͕DĂĂƌƚĞŶĂŶĚŽďŶĞĞĚƚŽďĞŵĞŶƟŽŶĞĚƐƉĞĐŝĮĐĂůůLJ͘ĞĐĂƵƐĞ ďƌƵƚĂůůLJ͕>ĞŽŶƐŬŝƉƉĞĚƚŚĞŵ͘EŽƚĞǁŽƌƚŚŝůLJ͕ŽďƐŚŽǁƐŚŝŐŚƉŽƚĞŶƟĂůĂƐĂĐŚĞŵŝƐƚ͕ǁŚĞƌĞ >ĞŽŶĚƌĂŵĂƟĐĂůůLJĨĂŝůƐ͘ŽŶ͛ƚǁŽƌƌLJŶŽǁ͕>ĞŽŶŝƐĂůƐŽĂŶŝĐĞŐƵLJ͘,ĞŚĂƐĂůƌĞĂĚLJďĞĞŶĂŶ ĞdžĂŵƉůĞĨŽƌŵĞƐŝŶĐĞŚŝŐŚƐĐŚŽŽů͘ƵƚĂůƐŽ͕WĂƵů͕:ƵůŝƵƐ͕,Ăƌŵ͕DŝĐŚŝĞů͕EŝĞŬ͕ZĞŵŵĞůƚ͕ ĂŶĚDĂdžĂƌĞ͚ǀƌŝĞŶĚǀŽŽƌŚĞƚůĞǀĞŶ͛͘ ĂĂŶ͕dŚĂůĞƐ͕:ĂŶďŝŶŶĞĞŶĂƐĂƌĞĂůǁĂLJƐŝŶĨŽƌũŽŬĞƐĂŶĚŐƌĞĂƚĨƵŶ͘ĞĞƌƉŽŶŐ͕zŽƵƐĞĨ ůŝĂŶĚƵƐƐĞŶĂƌĞŐĂŵĞƐƚŚĂƚƐŚŽƵůĚďĞǁƌŝƩĞŶŝŶŚŝƐƚŽƌLJĂƐŝƚŝƐŶŽǁ͕ũƵƐƚĂƐĂƩƌŝďƵƚĞƐ like the Mustapha Oumguil.

dŚĞŐƵLJƐĨƌŽŵWƌŽdžŝŵŝƚĂƐĂƌĞĨƌŝĞŶĚƐĂůƌĞĂĚLJĨŽƌŵĂŶLJLJĞĂƌƐ͘tŝƚŚƉĞŽƉůĞůŝǀŝŶŐ ŶĞĂƌďLJ'ƌŽŶŝŶŐĞŶ͕ǁĞƐƟůůŚĂǀĞĚŝŶŶĞƌĞǀĞƌLJtĞĚŶĞƐĚĂLJ͕ĂŐƌĞĂƚŵŽŵĞŶƚƚŽďƌĞĂŬƚŚĞ week.

DĂŵĂŶĚ'ĞƌĂƌĚ͕ƚŚĞƌĞŝƐŶŽƉůĂĐĞůŝŬĞŚŽŵĞ͘ǀĞŶƚŚŽƵŐŚ/ŚĂǀĞůŝǀĞĚŝŶ'ƌŽŶŝŶŐĞŶ for many years. It always feels good to be back in Bronnegerveen. Thanks a lot.

DĂŝŬĞ͕/ůŽǀĞLJŽƵ͘/ĐĂŶĐŽŵƉůĞƚĞůLJďĞŵLJƐĞůĨĂůŽŶŐLJŽƵƌƐŝĚĞĂŶĚĞŶũŽLJĞǀĞƌLJŵŽŵĞŶƚ ǁŝƚŚLJŽƵ͘ǀĞŶƚŚŽƵŐŚǁĞŵĞƚĂƚƚŚĞĞŶĚŽĨŵLJWŚ͕LJŽƵƌƐƵƉƉŽƌƚƚŽƉƵƚƚŚĞĮŶĂůƉŝĞĐĞƐ together helped a lot.

529927-L-sub01-bw-Meereboer 529927-L-sub01-bw-Meereboer 529927-L-sub01-bw-Meereboer 529927-L-sub01-bw-Meereboer Processed on: 21-3-2019 Processed on: 21-3-2019 Processed on: 21-3-2019

Processed on: 21-3-2019 PDF page: 139PDF page: 139PDF page: 139PDF page: 139

139 Acknowledgements

529927-L-sub01-bw-Meereboer 529927-L-sub01-bw-Meereboer 529927-L-sub01-bw-Meereboer 529927-L-sub01-bw-Meereboer Processed on: 21-3-2019 Processed on: 21-3-2019 Processed on: 21-3-2019