University of Groningen Tuning the crystalline phases of poly(vinylidene fluoride) for capacitive energy storage applications Meereboer, Niels Laurens

University of Groningen

Tuning the crystalline phases of poly(vinylidene fluoride) for capacitive energy storage

applications

Meereboer, Niels Laurens

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Publication date: 2019

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Meereboer, N. L. (2019). Tuning the crystalline phases of poly(vinylidene fluoride) for capacitive energy storage applications. Rijksuniversiteit Groningen.

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Niels L. Meereboer PhD thesis University of Groningen May 2019 ĞƌŶŝŬĞ/ŶƐƟƚƵƚĞWŚƚŚĞƐŝƐƐĞƌŝĞƐϮϬϭϵͲϭϬ /^^E͗ϭϱϳϬͲϭϱϯϬ /^E͗ϵϳϴͲϵϰͲϬϯϰͲϭϰϴϴͲϭ;ƉƌŝŶƚĞĚǀĞƌƐŝŽŶͿ /^E͗ϵϳϴͲϵϰͲϬϯϰͲϭϰϴϳͲϰ;ĞůĞĐƚƌŽŶŝĐǀĞƌƐŝŽŶͿ

The research presented in this work was performed in the research group Macromolecular ŚĞŵŝƐƚƌLJĂŶĚEĞǁWŽůLJŵĞƌDĂƚĞƌŝĂůƐŽĨƚŚĞĞƌŶŝŬĞ/ŶƐƟƚƵƚĞĨŽƌĚǀĂŶĐĞĚDĂƚĞƌŝĂůƐĂƚ the University of Groningen, The Netherlands. This work was funded by The Netherlands KƌŐĂŶŝƐĂƟŽŶĨŽƌ^ĐŝĞŶƟĮĐZĞƐĞĂƌĐŚEtK;s//'ƌĂŶƚϳϮϰ͘Ϭϭϯ͘ϬϬϬϭͿ͘

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© 2019, Niels L. Meereboer

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ĐĂƉĂĐŝƟǀĞĞŶĞƌŐLJƐƚŽƌĂŐĞĂƉƉůŝĐĂƟŽŶƐ

WƌŽĞĨƐĐŚƌŝŌ ƚĞƌǀĞƌŬƌŝũŐŝŶŐǀĂŶĚĞŐƌĂĂĚǀĂŶĚŽĐƚŽƌĂĂŶĚĞ ZŝũŬƐƵŶŝǀĞƌƐŝƚĞŝƚ'ƌŽŶŝŶŐĞŶ op gezag van de ƌĞĐƚŽƌŵĂŐŶŝĮĐƵƐƉƌŽĨ͘Ěƌ͘͘^ƚĞƌŬĞŶ ĞŶǀŽůŐĞŶƐďĞƐůƵŝƚǀĂŶŚĞƚŽůůĞŐĞǀŽŽƌWƌŽŵŽƟĞƐ͘

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Promotor Prof. dr. K. Loos Copromotor ŵ͘ƉƌŽĨ͘Ěƌ͘'͘ƚĞŶƌŝŶŬĞ ĞŽŽƌĚĞůŝŶŐƐĐŽŵŵŝƐƐŝĞ WƌŽĨ͘Ěƌ͘͘ŵĞĚƵƌŝ Prof. dr. F. Picchioni WƌŽĨ͘Ěƌ͘͘͘<ŽŶŝŶŐ

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Contents

ŚĂƉƚĞƌϭ Ws&ĨŽƌĞŶĞƌŐLJƐƚŽƌĂŐĞĂƉƉůŝĐĂƟŽŶƐ 7 ŚĂƉƚĞƌϮ EĂŶŽĐŽŶĮŶĞŵĞŶƚŝŶĚƵĐĞĚɴͲƉŚĂƐĞĨŽƌŵĂƟŽŶŝŶWs& ϯϭ ŚĂƉƚĞƌϯ ƵƌŝĞƚƌĂŶƐŝƟŽŶŝŶW;s&ͲcoͲdƌ&ͿďůŽĐŬĐŽƉŽůLJŵĞƌƐ ϰϵ ŚĂƉƚĞƌϰ ůĞĐƚƌŽĂĐƟǀĞĞŚĂǀŝŽƌŝŶW;s&ͲcoͲsͿĐŽƉŽůLJŵĞƌƐ 71 ŚĂƉƚĞƌϱ &ůƵŽƌŝŶĂƚĞĚƉŽůLJŵĞƌŶĞƚǁŽƌŬƐƵƐŝŶŐƵƌĞƚŚĂŶĞͲďĂƐĞĚ crosslinking 87 ŚĂƉƚĞƌϲ ZĞůĂdžŽƌĨĞƌƌŽĞůĞĐƚƌŝĐďĞŚĂǀŝŽƌŝŶW;s&Ͳter-dƌ&ͲterͲsͿ terpolymers 105 ƉƉĞŶĚŝdž Summary 127 ^ĂŵĞŶǀĂƫŶŐ ϭϯϭ >ŝƐƚŽĨWƵďůŝĐĂƟŽŶƐ ϭϯϰ ĐŬŶŽǁůĞĚŐĞŵĞŶƚƐ ϭϯϲ

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