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University of Groningen New catalytic reactions of (unsaturated) nitriles via metal-ligand cooperative activation of the C≡N bond Guo, Beibei

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University of Groningen

New catalytic reactions of (unsaturated) nitriles via metal-ligand cooperative activation of the

C≡N bond

Guo, Beibei

DOI:

10.33612/diss.136481036

IMPORTANT NOTE: You are advised to consult the publisher's version (publisher's PDF) if you wish to cite from it. Please check the document version below.

Document Version

Publisher's PDF, also known as Version of record

Publication date: 2020

Link to publication in University of Groningen/UMCG research database

Citation for published version (APA):

Guo, B. (2020). New catalytic reactions of (unsaturated) nitriles via metal-ligand cooperative activation of the C≡N bond. University of Groningen. https://doi.org/10.33612/diss.136481036

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Acknowledgments

197

Acknowledgments

Doing a PhD project is fully filled with the happiness of achieving initial goals, new surprising findings and hardships of accidents or unexpected failures. This moment, I have gone through most of them and I am finally getting there. During this whole journey, I feel so lucky and happy to work with my colleagues and enjoyed every important moment with all my friends. Thus, I would like to thank you to be in my PhD life.

Hans, I still remember that moment of reading your email in replying to my PhD application. I felt so happy and shared it with my master research group. I appreciated the opportunity you gave me to come here and your guide in the past four years. Especially, at the beginning of my PhD, I quite struggled as a new foreigner and you were very nice, patient and continuously encouraging me. I enjoy every meeting with you and always get many useful suggestions. Thank you very much!

Edwin, you are a nice person. When I first entered Physics and Chemistry building, it was you who picked me up to the lab, gave me a warm welcome and introduced me to everyone. Later when I told others which group I worked for, their first response was that Edwin is a nice person. Indeed, you treat us like family. Even when you are busy, you are always ready to help us with our projects and our lives. During the first two years, our chemistry projects did not go well and I struggled with almost everything. As my daily supervisor, it must be also a difficult time for you. Without your kind and patient help, I wouldn’t be able to overcome them and finish the PhD in time. Many thanks!

I would like to thank the members of the reading committee: Prof. Antonio Mezzetti, Prof. Adri Minnaard and Prof. Gerard Roelfes for going through my thesis and your kind suggestions and comments to improve my thesis.

I also want to express my gratitude to Prof. Antonio Mezzetti for the nice collaboration in October 2019. During the whole month in Zurich, I appreciated Alessandro Passera for your guide in the lab and I enjoyed the time with you, Hari and Kun.

Francesca, it is great to be your friend, colleague and share the office with you for four years. You always prepare surprises for your friends at their important event. Not every Chinese will celebrate his/her birthday every year, and I am one of them. But you and others bought a cake and the presents for me on my birthday in 2016, my first year in Groningen. I was surprised and later I learned that in the Dutch way, I was supposed to buy cakes for others. And as you have a strong sense of responsibility, you did a good job as a senior PhD in the group. Thank you for your help during the past four years and I am sure you are facing a bright future in the Netherlands with Marco.

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Acknowledgments

198

Jelte and Folkert, thank you for being my paranymphs and helping me so much in the past four years. It is lucky for me to have you around for these years. When I joined the group, you just started your master. You guys helped me to familiar with the building and institute at my beginning. Additionally, as Dutch, you tell me the stories behind the Dutch culture and helped me to solve many problems in life. I still remembered that you taught me the Dutch traffic rule after my small accident. And you let me join your life, introducing friends to me. By the way, I did have very good naps in Jelte’s sofa on your birthdays!

I would like to acknowledge the (former) colleagues. Johan, we just worked together for one year, while we did have a nice publication and many drunk pictures. At the beginning, you gave me a list of places of interest in the Netherlands. Unfortunately, I didn’t visit all of them. Ranajit, as the lab supervisor, you helped me a lot during these years and gave me many suggestions. We also had many good times during the travels in Barcelona and Girona. Now you are in the USA, I hope you are well and wish you a lot of success. Denise, Imke and Silene, it is not easy for you to do a small project under my supervision, since my project in the first two years didn’t go well. But all of you did a good job at the end. Onno and Linda, many thanks for working together and nice chat during the leisure time. By the way, because of you, I know what the difference is between vegan and vegetarian. I would also thank Renske, Edwin (Eddie), Tamara, Luuk, Sumeet,Arjan, Jules, Emma, Jacob, Daniel and all the others for the good moments we have spent together.

Since Dr. Johannes set up his group in Groningen, our two groups become very close friends. I would also like to thank Dr. Johannes for the nice discussion during group meetings and invited me and my girlfriend Linan to his wedding. It was wonderful and we had a really good time there. I really enjoyed the time that our two groups spent together, and I deeply thank you Taegeun, Kristo, Evagniya, Isaac and all the other members for these great moments, like Rondje Biotoop, Christmas borrel, conferences, barbeques, etc.

I am also grateful to Oetze, Pieter, Johan, Renze, Monique, Theodora for your help on technical and analytical support.

I would like to thank Prof. Wesley R. Browne for the useful discussions during the Molan meetings. And all Molan members: Juan, Jorn, Hans, Sandeep as well as others, Thank you for the help and great moments we spent together during the nice Molan trip. Out of inorganic departments, I also met many great friends and had a lot of fun. Many thanks to you, George, Marco, Sven, Anirban, Yafei, Luo, Xingchen, Zhuohua, Xianyuan, Yongzhuang, Gang, Yuru, Gongbao, Viktor, Franco, Shaoyu, Zhi.

To whom I may have forgotten, I am unintentional to do this. Please accept my sincere apologies.

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Acknowledgments

199

能够顺利完成博士学位,我必须还要感谢同样身为留学生的朋友们。从拿到留学基 金委支持后的材料准备工作到刚荷兰时各式各样的当地生活报备申请,以及后面一 连串生活适应住所的搬迁,真的是大家相互间扶持一步步摸索着走过来的。所以我 在这里要感谢你们,让我感受我不并是一个人孤独的外出求学,而是有丰富的社交 生活有许多来自朋友的关心,尤其是佳哥、芳源、倩倩,我们第一年作为室友,周 末一起闲聊交心,假期一起计划旅游;还有隔壁经常一起聚会、聚餐、烧烤,后面 一起辛苦搬家又在一个楼里做邻居三年的余意、贾秀、高健、方顺、宋亚凤,感谢 你们平时的帮助。还有最开始经常在一起后面因为搬家而不常见面和许多后面又交 到的朋友感谢你们提供的帮助和我们共同经历的美好时光,刘建军、郭蔚腾、张萌 帆、冯帅、叶重楠、王艳芳、刘艳艳、陈浩祁、王浅、季成涛等等。在此真诚的祝 大家学业顺利,早日找到合适理想的工作,未来家庭生活美满幸福! 我还要感谢我的家人,感谢他们一直以来对我的支持,四年的离家生活对我来说不 容易,对家人来讲分离也不是那么简单。虽然当代社会的求学或工作很大一部分是 远离家乡与亲人的,但远在他国,距离和时差导致的分离感以及事实上的团聚机会 减少都造成了思念的增加,事实上还很可能错过了亲人的离世。非常感谢你们的理 解与支持,好消息是这种情况马上就要结束了! 最后,我要感谢我的女朋友俐南。因为有你,所以我心有所依;因为有你,我并不 觉得博士生活那么辛苦难熬。每天与你电话联系的时间,总会让我感到安心,减轻 实验上压力与不时地的挫折感。周末的相聚,虽不是真的面对面,但至少心连心。 这些年来,你独自在北京,一个人打拼,应对生活与工作的压力,而且你比我更辛 苦的是只有工作上的同事,生活中的朋友比我在这边更少,我真心感谢你的付出与 陪伴!我爱你,俐南!下一次见面我们应该就再也不用体验现在这样的分离! Beibei Guo Groningen Oct 1st 2020

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