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Correction to: Oxidative Cleavage of Cellobiose by Lytic Polysaccharide Monooxygenase (LPMO)-Inspired Copper Complexes (vol 4, pg 10729, 2019)

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University of Groningen

Correction to:

Neira, Andrea C.; Martinez-Alanis, Paulina R.; Aullon, Gabriel; Flores-Alamo, Marcos; Zeron,

Paulino; Company, Anna; Chen, Juan; Kasper, Johann B.; Browne, Wesley R.; Nordlander,

Ebbe

Published in: ACS Omega

DOI:

10.1021/acsomega.0c04910

IMPORTANT NOTE: You are advised to consult the publisher's version (publisher's PDF) if you wish to cite from it. Please check the document version below.

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Publisher's PDF, also known as Version of record

Publication date: 2020

Link to publication in University of Groningen/UMCG research database

Citation for published version (APA):

Neira, A. C., Martinez-Alanis, P. R., Aullon, G., Flores-Alamo, M., Zeron, P., Company, A., Chen, J., Kasper, J. B., Browne, W. R., Nordlander, E., & Castillo, I. (2020). Correction to: Oxidative Cleavage of Cellobiose by Lytic Polysaccharide Monooxygenase (LPMO)-Inspired Copper Complexes (vol 4, pg 10729, 2019). ACS Omega, 5(43), 28403-28403. https://doi.org/10.1021/acsomega.0c04910

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(2)

Correction to

“Oxidative Cleavage of Cellobiose by Lytic

Polysaccharide Monooxygenase (LPMO)-Inspired Copper

Complexes

Andrea. C. Neira, Paulina R. Martínez-Alanis, Gabriel Aullón, Marcos Flores-Alamo, Paulino Zerón,

Anna Company, Juan Chen, Johann B. Kasper, Wesley R. Browne, Ebbe Nordlander, and Ivan Castillo

*

ACS Omega 2019, 4, 6, 10729−10740 DOI:10.1021/acsomega.9b00785

Cite This:ACS Omega 2020, 5, 28403−28403 Read Online

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It should be specified that in the preparative scale oxidations of cellobiose, the total volume of the reaction mixture was 2 mL at a phosphate buffer concentration of 200 mM. The column employed for HPLC-MS analysis was Poroshell 120 EC-C18 (2.7 μm), and samples were filtered through a short plug of Celite prior to analysis to eliminate the copper complexes.

We identified the peak in Figure S19 in the Supporting Information as a leaching product from the HPLC column when H2O2/Et3N is employed as oxidant for cellobiose

degradation. Upon further analysis, the peak giving rise to m/z = 118 and 235 is consistent with protonated triethylamine N-oxide [Et3NOH]+and [(Et3NO)2H]+, respectively.

Received: October 7, 2020 Published: October 23, 2020

Addition/Correction

http://pubs.acs.org/journal/acsodf

© 2020 American Chemical Society 28403

https://dx.doi.org/10.1021/acsomega.0c04910 ACS Omega 2020, 5, 28403−28403 This is an open access article published under an ACS AuthorChoice License, which permits

copying and redistribution of the article or any adaptations for non-commercial purposes.

Downloaded via UNIV GRONINGEN on April 7, 2021 at 06:08:16 (UTC).

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