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Dipoles, conjugation and molecular electronics

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University of Groningen

Dipoles, conjugation and molecular electronics Kovalchuk, Andrii

IMPORTANT NOTE: You are advised to consult the publisher's version (publisher's PDF) if you wish to cite from it. Please check the document version below.

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Publication date: 2018

Link to publication in University of Groningen/UMCG research database

Citation for published version (APA):

Kovalchuk, A. (2018). Dipoles, conjugation and molecular electronics. University of Groningen.

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Propositions

belonging to the thesis

Dipoles, Conjugation and Molecular Electronics

by

Andrii Kovalchuk

1. Bias induced (de)localization of the frontier states that mitigate transport can cause asymmetry in current/voltage characteristic of a molecular junction. 2. Transition voltages represent an easy way to acquire information about the energy level alignment inside the junction.

3. Sometimes science is more art than science.

4. A single methylene unit inserted into an OPE3-based molecular wire is enough to measurably reduce the strength of the coupling to the bottom electrode.

5. The solution based understanding of pKa is inapplicable in the case of a

surface-bound monolayer. Hence, a self-assembled monolayer comprising ω-thiol carboxylic acids can be protonated by water.

6. Science is a way of thinking much more than it is a body of knowledge. 7. The over-reliance on metrics stifles curiosity-driven, fundamental science. 8. Nobody exists on purpose. Nobody belongs anywhere. We’re all going to die. Come watch TV.

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