University of Groningen Redox-behavior and reactivity of formazanate ligands Mondol, Ranajit

The world’s first stock exchange: how the Amsterdam market for Dutch East India Company shares became a modern securities market, 1602-1700..

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Aluminum complexes with redox-active formazanate ligand: Synthesis, characterization, and reduction chemistry

In this respect, similar to base metal complexes, the incorporation of redox-active ligands in main group complexes may allow to perform chemical transformations catalytically..

We attribute this difference to the fact that in 4a, resonance delocalization from the electron-rich, reduced formazanate backbone occurs into two aromatic groups (N-Ph), whereas

In general, we anticipate that the ability to influence basicity, radical stability and N-H/N-C bond strength of compounds containing the formazanate ligand, either via

The synthesis and characterization data for aluminum complexes with one or two redox-active formazanate ligands reported in this paper provides an entry to studying the reactivity

spectroscopy, X-ray crystallography) and computational studies (Wiberg bond indices, NBO analysis) reveal that the increased ionic character in the Al compounds results in a