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Atomic-scale friction: thermal effects and capillary condensation Jinesh, Kochupurackal Balakrishna Pillai

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Atomic-scale friction: thermal effects and capillary condensation

Jinesh, Kochupurackal Balakrishna Pillai

Citation

Jinesh, K. B. P. (2006, September 19). Atomic-scale friction: thermal effects and capillary condensation. Retrieved from https://hdl.handle.net/1887/4562

Version: Corrected Publisher’s Version

License: Licence agreement concerning inclusion of doctoral thesis in theInstitutional Repository of the University of Leiden Downloaded from: https://hdl.handle.net/1887/4562

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Stellingen

behorende bij het proefschrift

Atomic-Scale friction: Thermal Effects and Capillary Condensation door

K.B. Jinesh

1. Friction in the limit of zero velocity is reduced to zero at nonzero temperatures. [Phys. Rev. E 71, 65101(R) (2006) and Chapter 4 of this PhD thesis].

2. When granted enough time, a sliding nanocontact will explore higher-energy two-dimensional trajectories to reach the next energy minimum in front, even if there is a direct, low-energy one-dimensional path. This significantly lowers the friction force at low velocities. [Chapter 4 of this PhD thesis].

3. Exciting a contact externally at its lateral resonance frequency can be a very efficient tool to ‘lubricate’ sliding motion, which might be very useful in MEMS and NEMS technology. [Chapter 5 of this PhD thesis].

4. Water condensing inside nanometer sized clefts can freeze at room temperature, which makes water a glue rather than a lubricant at the nanoscale. [Phys. Rev. Lett. 96, 166103 (2006) and Chapters 6 – 8 of this PhD thesis]. 5. Nucleation of multiple capillary bridges between the tip and the surface has

been claimed to introduce a velocity dependence in nano-scale friction in a humid atmosphere [Phys. Rev. Lett. 88, 185505 (2002)]. However, it is very unlikely that multiple capillary bridges would remain separated within the nanometer sized tip-sample gap.

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7. Nature lubricates biological machines with water-based lubricants, whereas manmade lubricants are mostly oil-based [M. Urbakh et al., Nature 430, 525 (2004)]. Nature might be achieving this by addition of special molecules that prevent confinement-induced crystallization of water in biological nanopores. 8. Oxides formed at ambient pressure and elevated temperatures on

various palladium surfaces have a higher reactivity in oxidation catalysis in this pressure regime than the original metallic surfaces. [S.C. Bobaru et al., unpublished].

9. Rice husk ash (RHA) can be used as a partial substitute for cement. This reduces the environmental issues of cement manufacture and usage, by introducing an environment-friendly material. [D.G. Nair et al., unpublished]. 10. It has been estimated that friction and wear alone cost a whopping 1.6 percent

of the annual gross national product of western countries, which amounted to $116 billion for the USA in 1995 [J. Krim, Scientific American, October issue 1996, page 48]. In this light, it is surprising that western society is investing such a small fraction of its R&D budget on tribology.

11. The origin of this Universe is so mysterious that only God knows all about it; perhaps even God himself doesn’t know. [Rigveda, X, 129 Creation Hymn].

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