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Study of atmospheric pressure radiofrequency Ar/02 plasma

afterglow used for PTFE surface modification

Citation for published version (APA):

Duluard, C. Y., Dufour, T., Carbone, E. A. D., & Reniers, F. (2010). Study of atmospheric pressure

radiofrequency Ar/02 plasma afterglow used for PTFE surface modification. In W. G. G. M. Hori, & X. Japan Society of Applied Physics (Eds.), Proceedings of the 63rd Gaseous Electronics Conference and 7th International Conference on Reactive Plasmas, Paris, France, 4-8 October 2010 (pp. CTP.00129-). GEC.

Document status and date: Published: 01/01/2010

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Abstract Submitted for the GEC10 Meeting of The American Physical Society

Sorting Category: 2.12 (E)

Study of atmospheric pressure radiofrequency Ar/O2

plasma afterglow used for PTFE surface modification CORINNE DULUARD, THIERRY DUFOUR, EMILE CARBONE, FRANC¸ OIS RENIERS, Universit´e Libre de Bruxelles, Facult´e des Sciences, Chimie Analytique et Chimie des Interfaces — Polytetrafluoroethylene (PTFE) is a hydrophobic polymer, the surface energy of which can be tailored by plasma treatment to increase its adhesion properties or to enhance its hydrophobicity, for example for biocompatible applications. Superhy-drophobic behavior was obtained by low pressure O2 plasma treatment,

and was attributed to surface roughening due to strong etching by O2

plasma. Recently, an increase in hydrophobicity has also been observed after treatment in the afterglow of an atmospheric pressure radiofre-quency Ar/O2 plasma with up to 0.1% O2 in the feed gas. To get a

better understanding of the mechanisms responsible for PTFE surface modification, the Ar/O2 plasma afterglow is characterized by spatially

resolved optical emission spectroscopy and mass spectrometry. The in-fluence of gas flow rate, power and substrate-to-electrode distance on the plasma properties is evaluated, and correlated with the change of PTFE surface energy and surface composition, determined by water contact angle measurements and X-ray photoelectron spectroscopy respectively.

Prefer Oral Session X Prefer Poster Session

Corinne Duluard cduluard@ulb.ac.be Universit´e Libre de Bruxelles, Facult´e des Sciences, Chimie Analytique et Chimie des Interfaces

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