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Synthesis of oxygen and nitrogen heterocycles via stabilized carbocations and
ring closing metathesis.
Doodeman, R.
Publication date
2002
Link to publication
Citation for published version (APA):
Doodeman, R. (2002). Synthesis of oxygen and nitrogen heterocycles via stabilized
carbocations and ring closing metathesis.
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LISTT OF ABBREVIATIONS
Ac c Anal l BF3OEt2 2 Boc c w-Bu u f-Bu u br r CSA Acy y
d d DBU DBU DCE E DIBALH H DMAP P DMSO O DMD D DMF F d p p p p ee e Et t EtOAc c equiv v h h HRMS S IR R ƒ ƒ LDA A LHMDS S Me e Mes s min n m p p NMR R PE E Ph h t-Pr r PPTS S q q RCM M RSM M Rf Rf rt t s s t t TBS S THF F TLC C Ts s acetyl l elementall analysis borontrifluoridee etherate terf-butoxycarbonyl terf-butoxycarbonyl n-butyl l tert-buty\ tert-buty\ broadd (spectral) camphorsulfonicc acid cyclohexyl lday(s);; doublet (in NMR)
l,8-diazabicyclo[5.4.0]undec-7-ene e 1,2-dichloroethane e diisobutylaluminiumm hydride 4-(dimethylamino)pyridine e dimethylsulfoxide e dimethyldioxirane e N,N, N-dimethy Iformamide bis(diphenylphosphino)propane e enantiomericc excess ethyl l ethyll acetate equivalent t hour(s) )
highh resolution mass spectrum infrared d
couplingg constant (in NMR) lithiumm diisopropylamide lithiumm hexamethyldisilazide methyl l
2,4,6-trimethylphenyl l minute(s) )
meltingg point (range) nuclearr magnetic resonance petroleumm ether (60-80) phenyl l isopropyl l pyridiniumm para-toluenesulfonate quartett (in NMR) ring-closingg metathesis ringsluitingsmetathese e
retentionn factor (in chromatography) roomm temperature
singlett (in NMR) triplett (in NMR)
fert-butyldimethylsilyl fert-butyldimethylsilyl tetrahydrofuran n
thinn layer chromatography para-toluenesulfonyl l