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Properties of Materials Home Work 3 (Due: 10/11/2010)

1. Find Bragg angles and indices of diffraction for the three lowest angle lines for an FCC crystal lattice with lattice parameter, a = 6Å with λ = 1.54 Å. (20) (NB: Allowed h2+k2+l2 = 3, 4, 8; for first three reflections from FCC lattice)

2. Calculate Bragg angle at which electrons accelerated from rest through a potential difference of 80 V Will be diffracted from the (111) planes of an FCC crystal of lattice parameter = 3.5 Å. (10)

3. List types of bonds in materials and a brief account of mechanism of their action respectively. (20) 4. Assume that the potential energy of two particles in the field of each other is given by:

U ( R )=−A R+ B

R9

, where A and B are constants.

(10x3)

(a) Show that the particle form stable compound for R=Re=

(

9 BA

)

18

(b) Show that for stable configuration, the energy of attraction os nince time the enrgy of repulsion.

(c) Show that the potential energy of the sustem under stavble configuration os 8A/9Re.

5. Calculate the potential energy of system of Na+Cl- ions when they are at 2 Å. Calculate in units of Joules as well as eV. (20)

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