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Cover Page The handle http://hdl.handle.net/1887/83484 holds various files of this Leiden University dissertation. Author: Jollans, T.G.W. Title: Hot Nanoparticles Issue Date: 2020-01-30

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Cover Page

The handle http://hdl.handle.net/1887/83484 holds various files of this Leiden

University dissertation.

(2)

Propositions accompanying the thesis titled

‘Hot Nanoparticles’

I. The distinction between gas and vapour bubbles is only meaningful for sufficiently slow dynamics.

chapter 2 of this thesis

II. For measuring small polarization-dependent effects at the nanoscale, large polarized beams are preferable to tightly focussed polarized beams.

chapter 3 of this thesis

III. Out of equilibrium, small changes in optical properties of a single gold nanoparticle on a substrate can only be properly understood with reference to the medium and the substrate.

chapter 4 of this thesis

IV. Anti-Stokes photoluminescence from pulsed excitation can provide insight into the dynamics of electron thermalization in metal nanoparticles and/or nanostructures.

chapter 5 of this thesis

V. The sensitivity of the plasmon-enhanced ensemble chirality measurement presented by Maoz et al. is limited by the chirality and quasi-chirality of the randomly grown gold film. This limitation can, with great care, be overcome in a nanoscale measure-ment.

B. M. Maoz et al., Nano Lett. 13, 1203–1209 (2013)

VI. The caveat given by Jones et al., maintaining that different solvents produce different vapour nano- and microbubble dynamics is superfluous given the limited time resol-ution of the measurements justifying it.

S. Jones et al., Nano Lett. 19, 8294–8302 (2019)

VII. Plasmonic nanosprings can be a promising tool for nanoscale force measurement, but only when their force response has been thoroughly and directly characterized.

B. Xiong et al., ACS Nano 11, 541–548 (2017)

VIII. Optical elements created through microscale temperature control may one day lead to a ‘smart’ replacement for bifocal spectacles.

C. Liu et al., ACS Photonics 6, 422–428 (2019)

IX. Algorithms for use in science are either trivial, open source, or not to be trusted.

Thomas G. W. Jollans

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