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Physics Procedia 41 ( 2013 ) 650 – 660

1875-3892 © 2013 The Authors. Published by Elsevier B.V.

Selection and/or peer-review under responsibility of the German Scientific Laser Society (WLT e.V.) doi: 10.1016/j.phpro.2013.03.129

Lasers in Manufacturing Conference 2013

Analysis of irradiation processes for laser-induced periodic

surface structures

J. Eichstädt

a

*

a,b

aUniversity of Twente, Chair of Applied Laser Technology, P.O. Box 217, Enschede, 7500 AE, The Netherlands bTNO Technical Sciences; Mechatronics, Mechanics and Materials, De Rondom 1, 5600 HE, Eindhoven, The Netherlands

Abstract

The influence of errors on the irradiation process for laser-induced periodic surface structures (LIPSS) was studied theoretically with energy density simulations. Therefore an irradiation model has been extended by a selection of technical variations. The influence of errors has been found in a deviation from optimal conditions, by a shift or spread of accumulated fluence and a variation of local fluence, related to variations of the peak fluence and relative pulse intersection. The analysis of the irradiation process by energy density simulations, gives the possibility to perform realistic irradiation simulations and derive optimization strategies for the determination of irradiation parameters. This analysis is required for the application of LIPSS for surface functionalization.

© 2013The Authors.Published by Elsevier B.V.

Selection and/or peer-review under responsibility of the German Scientific Laser Society (WLT e.V.)

Keywords: Laser-induced periodic surface structures, irradiation model, energy density simulations, sub-aperture stitchining

1. Introduction

Laser-induced periodic surface structures (LIPSS) have been investigated theoretically [1-4] and experimentally [5-7]since 1965 [8]. Different types of LIPSS have been observed, usually described by their periodicity and orientation with respect to the polarization of the laser light.LIPSS with a spatial period in the order of the laser wavelength are usually referred to as low spatial frequency LIPSS (LSFL) and those with a significantly smaller period as high spatial frequency LIPSS (HSFL) [7, 9]. Recent research is triggered by the

* Corresponding author. Tel.: +31 53 489 2434; fax: +31 53 489 2434.

E-mail address: [email protected].

Available online at www.sciencedirect.com

© 2013 The Authors. Published by Elsevier B.V.

Selection and/or peer-review under responsibility of the German Scientific Laser Society (WLT e.V.)

Open access under CC BY-NC-ND license.

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growing demand for manufacturing technologies transcribing requirements of engineered surfaces for surface functionalization [10-13]. The application of LIPSS, in a flexible and efficient manufacturing process, requires the control of the spatial emergence, of a specific type of LIPSS, on surface areas largerthan thefocused beam diameter. LIPSS regions can be extended by a lateral displacement of the beam position relative to the surface [14]. This displacement has to fulfill certain conditions, when a large area with a

-successive pulses is required [14]. For irradiation conditions where the applied displacement was too small, an

- [15], resulting in the disappearance of LIPSS on the

surface.

Fig. 1. m

Insert (a) shows an example for an area non-homogeneouslyand (b) homogeneouslycovered with LIPSS.

In our experimental practice, irradiation results have been used to optimize a laser setup. During this optimization procedure, irradiation errors, such as a shift between irradiated lines,shown in Fig. 1 (a), have been observed.The applicability and spatial emergence of LIPSS can be affected by technical limitations. This is important for the design of a laser system and for the development of a process. In previous work, an approach has been described for the determination of irradiation parameters of extended surface areas homogeneously covered with LIPSS[16]. During this work, an irradiation model has been developed, to analyse the irradiation under optimal conditions. Afterwards, we extended the irradiation model, in order to study the influence of errors on the irradiation process. In this contribution, we communicate some of the obtained results in order to support the application of LIPSS.

2. Assumptions

The irradiation model analyses the laser radiation transmitted to the sample plane. The input of the model considers parameters of the laser source, optical and kinematical system. The output of the model is the fluence accumulation process in the irradiation plane. A detailed description of the irradiation model, including a set of primary assumptions, can be found in reference[16]. In practice the irradiation process faces technical limitations. To analyze the influenceof these limitations on the irradiation process, the irradiation model has been extended by a set of secondary assumptions.

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to the (x,y) plane and located, together with the symmetry center of a focused Gaussian beam, in the origin of a Cartesian coordinate system. In this paper the irradiation plane is assumed to be tilted by an angle , spanned between the x and z axis, and out of focus by an offset z0. This situation can appear, if shape

deviations of a sample surface, motion errors of a kinematical system or alignment errors of the sample-kinematic system occur. The offset and tilt are considered in the simulation by calculating the projected beam radius for each irradiated location (x,y,z).

Whereas previously, the spatial Gaussian distribution was assumed to be circular, here it is assumed to have an elliptical deformation. This type of laser beam deviation can be caused by optical elements in the laser system. The deformation is described by scaling the beam radius , usually defined as the 1/e2-radius, by

different factors ( x y) in (x,y) direction. Furthermore, the average power P0 is assumed to vary over long and

short time periods. The cause for this deviation can be found in electrical or ambient disturbances. The long term drift P1(t) is simulated by a sinus function and the short term drift P2(t) by a function creating

pseudorandom values, following the laser pulse frequency.

In the irradiation model, irradiated locations were described by a sequence of lateral displacements. Here, the addressed locations are additionally assumed to vary due to position errors. This error can be caused by synchronisation issues or ambient disturbances. Two type of positioning errors are assumed, statistical variations and a phase shift between irradiated lines. Statistical variations (x1,y1) are numerically generated

using a pseudo random value generator. The phase shift x3 is introduced by a sinusoidal expression.

Furthermore, a second kinematical system with larger displacement capacities is assumed. Sub-apertures are displaced in order to mechanically increase the irradiated area. The assumptions and descriptions for these kinematics are similar to the first, but indicated with indices (k,g) instead and a different frequency fs.

The numerical energy density simulations are based on two main functions. The first function isthe accumulated fluence , , , , , , , g k r j i t z y x t z y x (1)

which is the summation over local fluence contributions from a certain distribution function, a sequence of displacements and repeating irradiation steps. The second function, is the local fluence

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for the second kinematical system and p y x x y z x y z f t P t P P t z y x , , , , 2 , , , 0 1 2 0 (3)

is the peak fluence.The simulation results are characterized by a set of analysis parameters, described in reference[16]. In addition to the accumulated fluence peak AP, valley AV and peak-to-valley difference PV,

the accumulated fluence center is determined AC= AV+ PV/2 too. 3. Simulations

At first, the influence of errors on the irradiation has been analysed individually and in combinationof errors on a small space domain for different relative velocities. The accumulated and local fluence has been found to deviatefrom optimal conditions, due to errors. The deviation can be observed in accumulated fluence profiles. Fig. 2 (a-c) shows examples of accumulated fluence profiles, for 0 = 1 J/cm2,Nr= 1 and (a) i= j=35

mm/sand =-0.75, (b) i= j=18 mm/sand = 0.10and (c) i= j=9 mm/sand =0.55. Fig. 2 (d-f) show

simulations with the same irradiation parameters, but with a set of selected irradiation errors. The beam profile was elliptical (x= 1.1 y = 0.9) at an input radius of = 10 a wavelength of = 1030 nm. The

average power was P0= 1.57 mW atfp1= 1 kHz and was varied sinusoidally withP1= ± 8 % at fp1= 0.175 kHz.

Irradiated locations were varied statistically withx1= y1= ± 1

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Fig. 2. Examples of numerical energy density simulations without (a-c) and with (d-f) the influence of errors. The greyscale represents the accumulated fluence in J/cm2.

An offset from the center of the beam waistin z direction, increases the beam diameter, which decreases the peak fluence and thereby the values within the local fluence variation. Furthermore the accumulated fluence is decreased for lower pulse intersections. The increased beam diameter, also influences the relative intersection between subsequent pulses if the velocity is constant. This increases APand decreases PV for a certain

intersections. If the offset is the only error, the effect is constant over the whole irradiated area.

An elliptical beam profile causes the beam diameter to deviate in lateral directions, which varies the peak fluence and therefore the local fluence and accumulated fluence peak. The direction of variation depends on the previously considered beam diameter. Similar to the z-offset, ellipticity also has an influence on the intersection of pulses. For an equal lateral displacement in x and y direction, the intersection is different. This effect causes, for low intersections, the accumulated fluence to spread anisotropicover the area. In Fig. 2 (e) it can be seen that individual pulses are more connected in x direction than in y. If the ellipticity is the only error, the effect is constant for the whole irradiated area.

If the irradiation plane is tilted, the beam profile gets deformed elliptically in the direction of the tilting plane, locations with a certain distance to the tilting point have an offset in z direction and irradiated locations in the direction of the tilting plane increase. In general this effect decreases the local and accumulated fluence. The effect of a tilted irradiation plane varies if this error is combined with an z-offset and beam deformation. If the tilt is the only error, the irradiation varies over the whole area, e.g. the peak fluence.

A shift of the irradiated lines, varies the start and end position of a line and the position of neighbouring pulses from subsequent lines. Whereas the variation of start and end positions increases with the shift,

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neighboring pulses from subsequent lines get back in phase after a certain shift. The shift varies the local and accumulated fluence, due to the non-orthogonal contributions of subsequent pulses from different lines. The shift between lines can be different for each new line, e.g. increase until pulses are back in phase and then start again.

Fig. 3. Examples of energy density simulations for stitched sub-apertures with different displacement boundaries. In (a) the geometrical length, in (b) the geometrical length minus the absolute intersection length and in (c) the real length of sub-apertures minus the absolute intersection length was applied as boundary.

The displacement of sub-apertures requires a displacement boundary, which results in a homogeneous irradiated area. Otherwise a stitching error can be obtained, as a variation of the accumulated fluence at the interface between stitched irradiation planes. The boundary condition for stitching depends on the real length of the sub-apertures and the relative intersection length applied within the sub-apertures. The real length of a sub-aperture can deviate from the geometrical because the required intersection determines an integer value for the number of pulses. Fig. 3 shows examples of energy density simulations for stitched sub-apertures with different displacement boundaries. In Fig. (a) the geometrical length was applied as boundary, in (b) the geometrical length minus the absolute intersection length and in (c) the real length of sub-apertures minus the absolute intersection length.

The variation of the power leads to a variation of the pulse energy and peak fluence linearly following the power error function. The variation in time is transformed into a spatial variation of local and accumulated fluence, where the temporal error frequency determines the spatial localization. Both, the long and short term drift, vary the peak or center point of the accumulated fluence. In Fig. 1 (e) the power variation can be observed as differences in peak brightness for different laser pulses.

Position errors vary the displacement in between pulses. The effect of this variation depends on the required pulse intersection and the given beam diameter. If pulses have a low intersection, the influence on neighbouring pulses is low, see Fig. 2 (a). If pulses intersect significantly, positioning errors vary the magnitude and spread of accumulated fluence. Although they do not modify the peak fluence, they also modify the location where a certain fluence is applied. Initial simulation results show, that they determine the spread of accumulated fluence for high pulse intersections.

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Fig. 4. Recalculated data from numerical energy density simulations, (a-c) with APand AV and (d-f) a percentage of AC as boundaries for the energy density domain. The greyscale represents the normalized accumulated fluence.

The deviation of accumulated fluence from optimal conditions can be analysed quantitatively, by comparing numerically with analytically determined characterization parameters. But, the deviations can also be visualized, if the numerical data are recalculated using the analytical values as boundaries for the energy density domain. Two different boundaries have been applied. First, APand AV are applied as domain

boundaries and for normalization. Fig. 4 (a-c) shows the recalculation with these boundaries for the energy density domain. This type of graph directly shows the spatial distributions of the deviations. Second, the domain boundaries can be defined as percentage relative to AC. Fig. 4 (d-f) shows the recalculation with these

boundaries for the energy density domain. This type of graph shows the principle influence on the spatial emergence. For both methods, areas of black and white color indicate locations where the domain boundaries have been exceeded.

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Fig. 5. (a) Example of an energy density simulation with errors and stitched sub-apertures, (b) recalculation with APand AV and (c) with a percentage of AC as boundaries for the energy density domain.

Fig. 5 (a) shows an example of an energy density simulation for a larger space domain with irradiation errors and (b-c) shows the visualization of irradiation deviationswith the two different domain boundaries. The diagonal in black color in Fig. 5 (b)is produced by the long term drift of the average power.In Fig. 5 (c) it can be seen that the domain boundaries are exceeded at the interface between stitched areas. This error is caused by the position errors of stitching displacements. Another effect which can be observed is a spread of accumulated fluence, visible as noisy accumulated fluence in the sub-apertures. If this effect is, either caused by short term power variations or by position errors, cannot be distinguished from a single graph. But other simulations show, that position errors have a large influence on the accumulated fluence spread especially for high pulse intersections.

Fig. 6. Numerically [ AP N, AV N] and analytically [ AP A, AV A] determined values on areas and cross-sections along x direction [ AP N x, AV N y] and y direction [ AP N y, AV N y] for different values of the relative intersection length . Insert (a) for z0

for y = 0.8 and insert (c) for x3= x0/2.

The determined characterization parameters can be recorded for different values of the relative intersection length. Analysis results of such a sequence of simulations are shown in Fig. 6. In Fig. 6 (a) analysis results are shown for z0= 200 accumulated fluence deviates for low intersection, but gets close to the values

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without offset at high intersections. In Fig. 6 (b) analysis results are shown for y = 0.8. For low intersections,

the ellipticity causes a global anisotropic spread of accumulated fluence. This effect seems to be reduced for high intersections. In Fig. 6 (c) analysis results are shown for a lateral shift x3= x0/2 of subsequent irradiated

lines each second displacement step.The effect of the phase shift on the accumulated fluence seems to be reduced for high pulse intersections.

4. Discussion

In this paper an extension to the irradiation model [16]has been presented, in order to analyse the influence of errors on the irradiation process. Energy density simulations show that the assumed technical variations influence the fluence accumulation process. The influence has been found in a deviation from optimal conditions, by a shift or spread of accumulated and a variation of the local fluence. The influence can be local or global, with respect to the irradiated area. One error can have multiple effects on the irradiation process. The mechanism underlying these effects, are related to variations of the peak fluence and relative pulse intersection. In which one parameter can have different effects.

In order to analyse the influence of errors, certain characterization values have been applied. Values for these parameters have been determined numerically and analytically, to determine deviations from optimal conditions. This approach allows to identify the deviation and classify different errors by the magnitude of the deviation. Additionally, the values have been used to visualize the deviations due to the influence of errors. Two different domain boundaries have been applied. Whereas the first directly indicates the deviation and their spatial distribution, the second definition of domain boundaries gives a more realistic impression of the influence on the spatial emergence. The latter one also allows to distinguish visually the magnitude of deviation for high pulse intersections.

The spatial emergence of LIPSS is related to the local and accumulated fluence[16, 17]. Therefore the deviations can influence the spatial emergence of LIPSS. On the one hand, an area homogeneously covered with LIPSS can be interrupted by the emergence of another morphology in case the accumulated fluence domain boundaries are exceeded. On the other hand, the regularity of LIPSS can be affected, in case the accumulated fluence spreads and addresses a range of values in the accumulated fluence domain of LIPSS. This effect could locally vary the height or splitting of LIPSS. However, detailed information about the spatial emergence of LIPSS under lateral displacement irradiation conditions with respect to their accumulated fluence domain boundaries and spatial properties are lacking in literature. But this informationis important for the application of LIPSS in the field of surface functionalization.

The analysis of deviations can be further improved if the artificial domain boundaries are replaced by experimentally determined domain boundary values for LIPSS. This would allow a comparisonof the absolute error magnitude to real process boundaries and to distinguish whether a certain error is critical or not. But this also requires to consider the effect of incubation. Because, for lower local fluences, the absolute values of the accumulated fluence domain boundaries are smaller than for higher local fluences.

Mostly, LIPSS are required to be uniformly distributed on the surface [15]. Therefore LIPSS areas are usually produced at high values of , see Fig. 2 (c). If the applied irradiationdeviates, see Fig. 2 (f), and as a consequence the spatial emergence also deviates, the irradiation parameters may require furtheroptimization. Without prior knowledge on the influence of errors on the irradiation process, this can increase the time required to empirically determine irradiation parameters. Whereas in practice, all effects contribute at the same time, energy density simulations offer the possibility to analyse the effect of a single error individually. In practice the required data for errors are usually known from the specification of a laser system or are accessible by measurements. If energy density simulations are performed with these data, realistic irradiation simulations can be obtained.

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The simulations indicate that some errors have less effect on the accumulated fluence at high intersections. In case of the z-offset the accumulated fluence deviates for low intersections but not for high. That means, a set of parameter would still address the correct accumulated fluence value in the energy density domain for LIPSS. But a decreasedlocal fluence means that the location of the accumulated fluence domain could be different due to incubation. Whereas the phase shift, does not vary the accumulated fluence peak and the peak fluence for high intersections.For the z-offset it seems important to determine the beam radius in the sample plane. This can be done by a D2-Experiment[18]. Such an experiment would also allow to determine the beam

ellipticity. This information could be used to improve the accuracy of the peak fluence and to apply an unequal lateral displacement, which would reduce the anisotropic spread of accumulate fluence present at low intersections. Also position errors seemto have an influence on the homogeneity of the irradiation with low intersections. The effect of this error could be reduced by increasing the beam diameter in focus by a beam expander. The consideration of incubation effects, may also allow to optimise the irradiation time. If the peak fluence would be increased, the number of repetitions could be reduced. This directly reduces the required amount of laser pulses and therefore the irradiation time.

5. Conclusions

The influence of errors on the irradiation process for laser-induced periodic surface structures (LIPSS) was studied theoretically with energy density simulations. Therefore an irradiation model has been extended by a selection of technical variations. The influence of errors has been found in a deviation from optimal conditions, by a shift or spread of accumulated fluence and a variation of local fluence, related to variations of the peak fluence and relative pulse intersection. The analysis of the irradiation process by energy density simulations, gives the possibility to perform realistic irradiation simulations and derive optimization strategies for the determination of irradiation parameters. This analysis is required for the application of LIPSS for surface functionalization. But the obtained results also identify interesting directions for further research. The relation between spatial properties of LIPSS on extended areas and accumulated fluence values addressed within the energy density domain is so far unclear.

Acknowledgements

The authors would like to thank Paul Verburg for comments on the text of this paper.

References

1. Sipe, J.E., et al., Laser-induced periodic surface structure. I. Theory. Physical Review B, 1983. 27: p. 1141.

2. Wu, Q., et al., Femtosecond laser-induced periodic surface structure on diamond film. Applied Physics Letters, 2003. 82(11): p. 1703-1705.

3. Dufft, D., et al., Femtosecond laser-induced periodic surface structures revisited: A comparative study on {ZnO}. Journal of Applied Physics, 2009. 105(3): p. 034908-9.

4. Bonse, J., A. Rosenfeld, and J. Krüger, On the role of surface plasmon polaritons in the formation of laser-induced periodic surface structures upon irradiation of silicon by femtosecond-laser pulses. Journal of Applied Physics, 2009. 106(10): p. 104910-5.

5. Young, J.F., et al., Laser-induced periodic surface structure. II. Experiments on Ge, Si, Al, and brass. Physical Review B, 1983. 27(2): p. 1155.

6. Costache, F., M. Henyk, and J. Reif, Surface patterning on insulators upon femtosecond laser ablation. Applied Surface Science, 2003. 208-209: p. 486-491.

7. Bonse, J. and J. Krüger, Pulse number dependence of laser-induced periodic surface structures for femtosecond laser irradiation of silicon. Journal of Applied Physics, 2010. 108(3): p. 034903-5.

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8. Birnbaum, M., Semiconductor Surface Damage Produced by Ruby Lasers. Journal of Applied Physics, 1965. 36(11): p. 3688-3689.

9. Borowiec, A. and H.K. Haugen, Subwavelength ripple formation on the surfaces of compound semiconductors irradiated with femtosecond laser pulses. Applied Physics Letters, 2003. 82(25): p. 4462-4464.

10. Vorobyev, A.Y. and C. Guo, Colorizing metals with femtosecond laser pulses. Applied Physics Letters, 2008. 92(4): p. 041914-3.

11. Baldacchini, T., et al., Superhydrophobic Surfaces Prepared by Microstructuring of Silicon Using a Femtosecond Laser. Langmuir, 2006. 22(11): p. 4917-4919.

12. Yasumaru, N., K. Miyazaki, and J. Kiuchi, Control of tribological properties of diamond-like carbon films with femtosecond-laser-induced nanostructuring. Applied Surface Science, 2008. 254(8): p. 2364-2368.

13. Eichstädt, J., G.R.B.E. Römer, and A.J. Huis in 't Veld, Towards Friction Control using laser-induced periodic Surface Structures. Physics Procedia, 2011. 12, Part B(0): p. 7-15.

14. Fauchet, P.M. and A.E. Siegman, Surface ripples on silicon and gallium arsenide under picosecond laser illumination. Applied Physics Letters, 1982. 40(9): p. 824-826.

15. Huang, M., et al., Large area uniform nanostructures fabricated by direct femtosecond laser ablation. Optics Express, 2008. 16(23): p. 19354-19365.

16. -induced periodic

surface structures. Applied Surface Science, 2013. 264(0): p. 79-87.

17. Jee, Y., M.F. Becker, and R.M. Walser, Laser-induced damage on single-crystal metal surfaces. Journal of the Optical Society of America B Optical Physics, 1988. 5(3): p. 648-659.

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