University of Groningen
Electric field modulation of spin and charge transport in two dimensional materials and
complex oxide hybrids
Ruiter, Roald
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Publication date: 2017
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Ruiter, R. (2017). Electric field modulation of spin and charge transport in two dimensional materials and complex oxide hybrids. Rijksuniversiteit Groningen.
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The work described in this thesis was performed in the research group Physics of Nanodevices of the Zernike Institute for Advanced Materials at the University of Groningen, the Netherlands. This work was realized using NanoLabNL (NanoNed) facilities and is a part of the ’Functional Materials’ programme (project number ..), financed by the Netherlands Organisation for Scientific Research (NWO). Thesis design based on classicthesis from André Miede. Redesigned by Roald Ruiter to fit on B paper. Typeset using LATEX and KP Fonts Serif family of fonts.
Cover art: Electric field marionette controlling an electron with its spin. Cover design: Roald Ruiter.
Electric field modulation of spin and charge transport
in two dimensional materials and complex oxide
hybrids
proefschrift
ter verkrijging van de graad van doctor aan de Rijksuniversiteit Groningen
op gezag van de
rector magnificus prof. dr. E. Sterken, en volgens besluit van het College voor Promoties.
De openbare verdediging zal plaatsvinden op vrijdag juni om : uur
door
Roald Ruiter
geboren op september te Appingedam
Promotores
Prof. dr. T. Banerjee Prof. dr. ir. B.J. van Wees Beoordelingscommissie Prof. dr. B. Noheda Pinuaga Prof. dr. A. Ghosh
CONTENTS
acronyms
introduction
. The ever shrinking calculators . Silicon’s successor
. Alternative technologies . Graphene spintronics . Complex oxide spintronics . Outlook
. Thesis outline
theoretical concepts
. Spintronics . Spin injection and detection in non-magnetic materials . Local spin valves
. Non-local spin valves
.. Non-local spin signals in a two-dimensional channel . Three terminal measurements
.. Three terminal spin signals in a three dimensional channel . Hanle spin precession
.. Non-local geometry .. Three terminal geometry . Conductivity mismatch problem . Spin relaxation
.. Elliot-Yafet mechanism .. D’yakonov-Perel’ mechanism
.. Electric field induced spin-orbit coupling . Schottky barriers
. Graphene
. Molybdenum disulfide . Strontium titanate
.. Semiconducting strontium titanate
experimental concepts
. Exfoliation
.. Exfoliation on PDMS . Pick-up and transfer of flakes
. Titanium dioxide termination of strontium titanate . Contact fabrication
.. Two dimensional material based samples .. Three terminal devices
. Electrical measurements . Measurement circuits
CONTENTS
spin transport in graphene on SrTiO
. Introduction . Device fabrication . Measurement method
. Temperature dependent spin transport . Temperature dependent charge transport . Modelling of the non-local signal
. Conclusions
inherent electric field driven inversion of spin
accumu-lation in Nb:SrTiO
. Introduction . Device fabrication . Measurement methods . Inversion of the spin voltage . Spin relaxation time
. Reproducibility . Discussion
. Modelling of the Schottky profile . Conclusions
electrical characterisation of MoS
tunnel barriers in
a metal/MoS
/graphene configuration
. Introduction . Device fabrication . Measurement methods . Square resistance of graphene
. Scaling of the barrier resistance with barrier thickness . Barrier resistance with temperature
. Non-linear barrier conductance
.. Tunnel barrier thickness dependence of the conductance .. Shifting the minimum conductivity
.. Altering the barrier conductance with gate . Conclusions
summary
samenvatting
acknowledgements
publications
curriculum vitae
ACRONYMS
EF Fermi level D two-dimensional T three terminal
AFM atomic force microscope BHF buffered hydrofluoric acid BR Bychkov-Rashba
DOS density of states DP D’yakonov-Perel’
EBL electron beam lithography EY Elliott-Yaffet
FM ferromagnetic
GMR giant magnetoresistance h-BN hexagonal boron nitride IPA isopropyl alcohol MR magnetoresistance NM non-magnetic PC polycarbonate PDMS polydimethylsiloxane RSS resonant surface states SOC spin-orbit coupling STO SrTiO
TAMR tunnelling anisotropic magnetoresistance TMD transition metal dichalcogenide
PREFACE
You are about to read a thesis which probably looks a bit different than what you are used to. The reason for this is that when I read something it bothered me that text and figures seem to live in different worlds in most books, papers or articles. By this I mean that often when a text refers to a figure, the figure is not located close to the text itself. The physical barrier between the two was a hindrance when trying to grasp an idea or concept, especially since I’m a very visual person and a picture is often worth a thousand words.
Luckily I came across The Visual Display of Quantative Information, from Edward Turfte []. He felt the same and has thought quite a bit on how to change this for years. Reading his books, I came to understand that in the time of Gallileo and Leonardo da Vinci, it was very common to integrate images into your text, or even use small images which were integrated into a sentence.
An example of this can be seen on the right, where Galileo Galilei integrated images of Saturn into his texts []. The top image depicts how he imagined Saturn would look like with perfect
vi-sion and the bottom one is how he perceived it through his telescope [, p. ]. Also more recently, Martinus Veltman in Diagrammatica took a similar approach and abolished figure and equations numbers all together, as he wrote[, p. xii]:
This has forced me to keep all derivation and arguments closed in them-selves, and the reader needs not to have its fingers at eleven places to follow an argument.
I decided to try a similar concept for my thesis and keep images and text to-gether. For small figures I chose to wrap the accompanying text around it and for larger figures the accompanying text is in the paragraph right above the figure. Fur-thermore this concept makes the need for captions unnecessary. Additionally I have sometimes placed drawings or graphs with a height equal to the line height into the text itself. This was relatively easily to realise by using LATEX. For the figures in general I have tried not to use abbreviations, texts at a degree angle and some other ideas which are mostly taken from Tufte’s work [].
I hope this methodology helps the reader more easily understand the concepts of this thesis.
Roald Groningen,
references
. E.R. Tufte, The Visual Display of Quantitative Information (Graphics Press, ). . G. Galilei, Istoria e dimostrazioni intorno alle macchie solari (Rome, Rome, ).
. G. Galilei, Discoveries and Opinions of Galileo, th edition ed. (Anchor, New York, ). . M. Veltman, Diagrammatica: The Path to Feynman Diagrams (Cambridge University Press,