Catalytic allylation of phenols : chloride-free route towards epoxy resins
Rijn, J.A. van
Citation
Rijn, J. A. van. (2010, September 14). Catalytic allylation of phenols : chloride-free route towards epoxy resins. Retrieved from https://hdl.handle.net/1887/15943
Version: Corrected Publisher’s Version
License: Licence agreement concerning inclusion of doctoral thesis in the Institutional Repository of the University of Leiden
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Table of contents
List of abbrevations 6
1 General introduction 9
2 Cationic ruthenium-Cp-diphosphine complexes as catalysts 33 for the allylation of phenols with allyl alcohol
3 [RuCp(PP)]+-catalyzed allylation of phenols: a 53 gem-dialkyl-type effect induces high selectivity for O-allylation
4 Remarkable activity of the isomerization catalyst 71 [RuCp(PPh3)2](OTs) in O-allylation of phenol with allyl alcohol
5 Scope of the allylation reaction with [RuCp(PP)]+ catalysts: 87 changing the nucleophile or allylic alcohol
6 Immobilization of ruthenium catalysts for allylations 103 with allyl alcohol as allylating agent
7 Theoretical study on the mechanism of [RuCp(PP)]+- 123 catalyzed allylations of phenols with allyl alcohol
8 Palladium-diphosphine complexes as catalysts for 143 allylations with allyl alcohol
9 Selective O-allylation of bisphenol A: 157
the ultimate goal
10 Summary, conclusions and outlook 165
Samenvatting 175
List of publications 180
Curriculum Vitae 183
Nawoord 185
