Coordination chemistry of manganese and iron with N,O-donor ligands:
oxidation catalysis and magnetochemistry of clusters
Godbole, M.D.
Citation
Godbole, M. D. (2006, January 12). Coordination chemistry of manganese and iron with
N,O-donor ligands: oxidation catalysis and magnetochemistry of clusters. Retrieved from
https://hdl.handle.net/1887/4333
Version:
Corrected Publisher’s Version
License:
Licence agreement concerning inclusion of doctoral thesis in the
Institutional Repository of the University of Leiden
Downloaded from:
https://hdl.handle.net/1887/4333
Table of Contents
List of Abbreviations
Chapter 1 Manganese and Iron Complexes in Biomimetics, Oxidation Catalysis and Cluster Chemistry
1
1.1 Introduction 1
1.2 Manganese in Biomimetic Chemistry 1 1.3 Iron in Biomimetic Chemistry 8 1.4 Manganese and Iron in Biomimetic Oxidation Catalyis 11 1.5 Magnetochemistry of Manganese and Iron Clusters 20 1.6 Objectives and Outline of the Thesis 23
1.7 References 25
Chapter 2 Highly Efficient Disproportionation of Dihydrogen Peroxide: Synthesis, Structure, and Catalase Activity of Manganese Complexes of the Salicylimidate Ligand
31
2.1 Introduction 32
2.2 Experimental Section 33 2.3 Results and Discussion 36 2.4 Concluding Remarks 50
2.5 References 50
Chapter 3 Stereochemical Influence of the Ligand on the Structure of Manganese Complexes; Implications for Catalytic
Epoxidations
53
3.1 Introduction 54
3.2 Experimental Section 56 3.3 Results and Discussion 61 3.4 Concluding Remarks 82
3.5 References 83
Chapter 4 Structural Studies of ‘Fe(phox-R)’ Complexes and Use in Catalytic Oxidations
85
4.1 Introduction 86
4.2 Experimental Section 87 4.3 Results and Discussion 89 4.4 Concluding Remarks 96
Chapter 5 High-Nuclearity Manganese and Iron Complexes with the Anionic Ligand Methyl Salicylimidate
99
5.1 Introduction 100
5.2 Experimental Section 101 5.3 Results and Discussion 103 5.4 Concluding Remarks 119
5.7 References 120
Chapter 6 Summary, General Discussion and Outlook 123
