University of Groningen
Dynamic transfer of chirality in photoresponsive systems
Pizzolato, Stefano Fabrizio
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Publication date: 2017
Link to publication in University of Groningen/UMCG research database
Citation for published version (APA):
Pizzolato, S. F. (2017). Dynamic transfer of chirality in photoresponsive systems: Applications of molecular photoswitches in catalysis. University of Groningen.
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Abbreviations and Acronyms
APCI atmospheric pressure chemical ionization BINAM 1,1′-Bi(2-naphthylamine)
BINOL 1,1′-Bi(2-naphthol)
BIPHEP 2,2‘-bis(diarylphosphino)biphenyl
CD Circular Dichroism
CIP Cahn-Ingold-Prelog CLA chiral Lewis acid
cod 1,5-cyclooctadiene
Conv conversion
COSY NMR correlation spectroscopy CSP chiral stationary phase
DABCO 1,4-diazabicyclo[2.2.2]octane
DBS dibenzosuberane
DFT density functional theory
DHPLC Dynamic HPLC
DMA N,N’-dimethylaniline
DMI N,N’-dimethylimidazolinone
DMRG density matrix renormalization group dr diastereoisomeric ratio
(E) entgegen, denotes relative configuration
ee enantiomeric excess
er enantiomeric ratio
EDG electron donating group
EI electron ionization
ESI electrospray ionization EXSY NMR exchange spectroscopy EWG electron withdrawing group
GC gas chromatography
GC-MS gas chromatography-mass spectrometry HOMO highest occupied molecular orbital HPLC high performance liquid chromatography HRMS high resolution mass spectrometry
IR infra-red
LUMO lowest unoccupied molecular orbital (M) denotes left-handed helicity
(Ma) denotes left-handed axial helicity
(M=) denotes left-handed overcrowded alkene helicity
MAP N-methylaminopyridine
MBH Morita–Baylis–Hillman
MS or M metastable
NMR nuclear magnetic resonance
NOESY nuclear Overhauser effect spectroscopy (P) denotes right-handed helicity
(Pa) denotes right-handed axial helicity
(P=) denotes right-handed overcrowded alkene helicity
PET photoinduced electron transfer PSS photostationary state
Abbreviations and Acronyms
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(R) rectus, denotes absolute configuration
(Ra) rectus, denotes absolute axial configuration
(RP) rectus, denotes absolute configuration of phosphorus center
RC rotaxane catalyst
RCL responsive coordination ligand ROC responsive organocatalyst
rt room temperature
(S) sinister, denotes absolute configuration
(Sa) sinister, denotes absolute axial configuration
(SP) sinister, denotes absolute configuration of phosphorus center
St or S stable
TD time-dependent
TEZI thermal E-Z isomerization TLC thin layer chromatography TOF turnover frequency THI thermal helix inversion UV-vis Ultraviolet-visible
