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Magnetostratigraphy of upper Miocene-lower Pliocene sediments of the Black Sea Basin (Taman Peninsula, Russia)

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Magnetostratigraphy of upper Miocene-lower Pliocene sediments of the Black Sea Basin (Taman Peninsula, Russia)

Iuliana Vasiliev

1,*

, Alexandr Iosifidi

2

, Alexei Khramov

2

, Wout Krijgsman

1

, Cor Langereis

1

, Vicktor Popov

2

, Marius Stoica

3

, Vika Tomsha

3

, Serghei Yudin

4

1

Paleomagnetic Laboratory ’Fort Hoofddijk’, Department of Earth Sciences, Utrecht University, The Netherlands;

2

All-Russia Petroleum Research Exploration Institute (VNIGRI), St.Petersburg, Russia;

3

Faculty of Geology and Geophysics, Bucharest University, Romania,

4

Faculty of Geology, St. Petersburg State University, St. Petersburg, Russia. *e-mail: (vasiliev@geo.uu.nl)

Introduction

During the late Miocene to early Pliocene (~11 to 3 Ma), the Eastern Paratethys domain extended from the Dacian Basin in Romania to the Aral Sea in Kazakhstan (Fig. 1). The Paratethys became progressively isolated from open ocean system, resulting in environments marked by varying salinities with marine to brackish and fresh water conditions. The Mio-Pliocene chronostratigraphic scale for the Eastern Paratethys encompasses the regional Sarmatian, Maeotian, Pontian and Kimmerian/Dacian stages, which are all defined on the basis of characteristic faunal assemblages endemic to Paratethys Sea. Correlation to the global Geological Time Scale is highly debated because radiometric age determinations are scarce and magnetostratigraphic studies are generally controversive (e.g. Trubikhin, 1977; Pevzner and Chikovani, 1978; Trubikhin, 1989). As a consequence, the ages of the Paratethyan stage boundaries can differ more than a million years in the various geological time scales (see Vasiliev et al., 2004 ).

Methods

In this paper, we aim to establish a magnetostratigraphic framework for the upper Miocene-lower Pliocene successions of the Black Sea Basin (Fig. 2). The Zheleznyi Rog (Iron Cape) section on the Black Sea margin of the Russian Taman Peninsula was selected. One volcanoclasic layers from upper Sarmatian deposits have been radiometrically dated using

40

Ar/

39

Ar method.

Results

Our magnetostratigraphy sustains both, earlier obtained, black and white patterns of Trubikhin (1989) and Pevzner and Semenenko (2003) despite of the different interpretation given by the two papers. Additional

40

Ar/

39

Aage constrains indicate that important non-deposition and/or erosion let to significant hiatuses in the Meotian part of the Zheleznyi Rog section (Fig. 4). The

40

Ar/

39

Ar dating the volcanoclastic layer from Zhelezyi Rog, Taman Peninsula–Russia yielded a homogeneous age population at 8.7 ± 0.09 Ma (Fig. 3). This

40

Ar/

39

Ar dating indicate that the Sarmatian/Meotian boundary in the Eastern Paratethys has to be younger than 8.7 Ma, in agreement with the magnetostratigraphy provided by Vasiliev et al., 2004 based on the Sarmatian-Meotian section in Carpathian foredeep.

Figure 2. Schematic lithological column and polarity zones for Zheleznyi Rog section. Position of dated volcanoclastic layer is indicated. Eastern Paratethys substages are given next to lithology. In polarity columns black (white) denotes normal (reversed) polarity intervals. Different symbols in declination/inclination plots represent reliable direction of demagnetisation and the steps are according to legend (inset in right-hand side). Representative demagnetization diagrams (a-j), after tilt correction. Selected examples are displayed in stratigraphical order from youngest (a) to oldest (j). Solid (open) circles denote projection on the horizontal (vertical) plane and the attached numbers indicate temperatures in ºC.

Figure 1. a) Schematic palaeogeographic map of the late Miocene/early Pliocene, showing the Paratethys area and the present-day land configuration. The big star locates the Zheleznyi Rog (ZR) section on Taman Peninsula, Russia. The small star indicates the position the Rîmnicu Sărat section, studied in Romania. b) Zheleznyi Rog section.

Figure 4. . Review of the paleomagnetic polarity patterns obtained for the Zheleznyi Rog section by Pevzner et al., 2003, Trubickin et al., 1989 and this research (in the let hand side). The multiple correlations of the magnetic polarity sequence to the APTS are presented. In the right hand side our correlation is indicated. The solid line between the section record and APTS connect (interepretative) simultaneous polarity boundaries. The names of the subchrons are in the column attached to the APTS. A to c are images of visible brake in the accumulation of the sedimentary deposits. a) Photograph of the distinct reddish layer marking the beginning of the Kimmerian; b) photograph of an intra upper Meotian unconformity and c) photograph at the lower Meotian- upper Meotian transition. The upper Meotian starts with the layer containing pebbly breccias and olistostroms.

Figure 3. Results of dated volcaniclastic layer.

NovorossianPortaferrian

Declination Inclination

8.70 Ma

40Ar/39Ar 8.70 Ma

40Ar/39Ar

-475 -450 -425 -400 -375 -350 -325 -300 -275 -250 -225 -200 -175 -150 -125 -100 -75 -50 -25 0

Stratigraphic level (m) SarmatianMeotianPontian Kimmerian Me 1Me2Sm3OdessianPortafferian

180 360 -90 0 90

(420-580 oC) (270-420 oC) (100-270 oC)

(50-100 mT) (0-20 mT) (20-45 mT)

LEGEND for components

TR 125.3B

th N

up/W

-133.63

100

180 ºC 200

210 340

TR 181.1A

th

N up/W

-399.05

20 ºC 80

140 100

210 TR 107.3B

th

N up/W

-167.17 20 ºC

100 150 210

240-340

TR 141.3

R-af

N up/W

-460.55

0 mT

10

15 20 TR 027.2

th

N up/W

-268.90

420

50 ºC 170 290

TK 001.3

R-af

up/W N

-89.21

20 mT 80

45 32

TH 030.1A

af

up/W N

-302.97

10 13

7 34

19 25

0 mT TR 032.3A

af

up/W N

-264.05 0

10 mT 31

19

TR 150.1

af

N up/W

-450.52

0 mT 10

20 40

TK 087.1A

th

N up/W

-30.52

100 ºC

200

250 485

i j

g h

e f

c d

a b

Marine transgression

(Krijgsman et al., 2010)

Volcaniclastic layer

Preliminary dated at ~8.7 Ma

5.0

6.0

7.0

8.0

9.0 4.5

5.5

6.5

7.5

8.5 Age(Ma)

APTS 2004

C3An.1n

C3An.2n

C3Bn

C4n.1n

C4n.2n

C4An

C3n.4n

C3Ar

C3Br.2r

C4r.2r C4r.1r

C3n.3n C3n.2n C3n.1n

C3An.1r

C4r.2r-1n

C3r

-275 -250

Me 2

-325

Me 2 -300

Me2

?

?

?

?

Me 1

-475 -450 -425 -400 -375 -350

Sm 3

-225 -200 -175 -150 -125 -100

NovorossianPortaferrian OdPfMe 2

-75 -50 -25 0

Km

MSC interval Pf

Km

-89 m -92.6 m

Me1 Me2

Me2

clay pebbels &

olistostroms

Picture a

Picture b

Picture c

Picture c Picture b Picture a

NovorossianPortaferrian

-475 -450 -425 -400 -375 -350 -325 -300 -275 -250 -225 -200 -175 -150 -125 -100 -75 -50 -25 0

SarmatianMeotianPontian Kimmerian Me 1Me 2Sm 3OdessianPortafferian

MeotianPontianKm upperlowerupper

50

100

150

200

250 0

Chron 6 = C3ArChron 7 = C4nGilbert

Pevzner &

Semenenko 2003

MeotianPontianKm upperlowerupper Chron 5 = C3AnChron 6 = C3ArGilbert

Trubikhin, 1989

This paper

a

b

c

0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15

0 10 20 30 40 50 60 70 80 90 100

Ar-Ages in Ma

W E IG HTE D P L ATE AU 8.70 ± 0.09

TOTAL F US ION 8.71 ± 0.09

NOR MAL IS OC HR ON 8.71 ± 0.09

INVE R S E IS OC HR ON 8.71 ± 0.09

MS W D 1.61

S ample Info

G las s Iuliana AL

IR R = VU78

J = 0.0026607 ± 0.0000266

Cumulative 39Ar Released (%)

Age (Ma)

INCREMENTAL HEATING

8.70 ± 0.09 Ma

Laboratory of Isotope Geology Vrije Universiteit, Amsterdam The Netherlands

0 200 400 km

50ºN

35ºN 40ºN 45ºN

20ºE 30ºE 40ºE 50ºE 60ºE

Black Sea

Casp

ian Se a

Hungary

Ukraine

Russia

Turkey

Kazahstan

RM

RM

ZR ZR

a

Eastern Paratethys (Black Sea)

Zheleznyi Rog section in Taman Peninsula - Russia (Miocene - Pliocene)

Kimmerian

Pontian Meotian

Sarmatian

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