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Assessing the cross-link density of rubber vulcanizates using three different approaches

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Assessing crosslink density of rubber vulcanizates using three different approaches M.M. Sęk, W. Kaewsakul, L.A.E.M. Reuvekamp, A. Blume

The determination of crosslink density in rubber vulcanizates remains a complex issue in practice. This presentation gives a concise overview of the commonly used laboratory measurement techniques for crosslink density. It draws the attention to the equilibrium swelling and Mooney-Rivlin mechanical approaches in comparison to a recently developed method, called Temperature Scanning Stress Relaxation (TSSR). Advantages and disadvantages of these techniques are discussed for unfilled and filled compounds with various curing systems.

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