University of Groningen
Catalytic hydrotreatment of pyrolysis liquids and fractions Yin, Wang
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Publication date: 2017
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Yin, W. (2017). Catalytic hydrotreatment of pyrolysis liquids and fractions: Catalyst Development and Process Studies. University of Groningen.
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Catalytic Hydrotreatment of
Pyrolysis Liquids and Fractions
Catalyst Development and Process Studies
This work was financially supported by Agentschap NL (Groene aardolie via pyrolyse, GAP), project number: BIORF01016
ISBN: 978-90-367-9376-6
Catalytic Hydrotreatment of
Pyrolysis Liquids and Fractions
Catalyst Development and Process Studies
PhD thesis
to obtain the degree of PhD at the University of Groningen
on the authority of the Rector Magnificus Prof. E. Sterken
and in accordance with
the decision by the College of Deans. This thesis will be defended in public on
Friday 6 January 2017 at 12.45 hours
by
Wang Yin born on 6 June 1985
Supervisor Prof. H.J. Heeres Co-supervisor Dr. R.H. Venderbosch Assessment Committee Prof. F. Picchioni Prof. S.R.A. Kersten Prof. E.J.M. Hensen
Contents
Chapter 1 An Introduction to Catalytic Hydrotreatment of Pyrolysis
Liquids ... 7
Chapter 2 Catalytic Hydrotreatment of Fast Pyrolysis Liquids in Batch and Continuous Set-ups using A Bimetallic Ni-Cu Catalyst with A High Metal Content ... 55
Chapter 3 Mo Promoted Ni Based Catalysts for the Catalytic Hydrotreatment of Pyrolysis Liquids ... 109
Chapter 4 Hydrotreatment of the Carbohydrate-rich Fraction of Pyrolysis Liquids using Bimetallic Ni Based Catalysts: Catalyst Activity and Product Property Relations ... 137
Chapter 5 Catalytic Upgrading of Sugar Fractions from Pyrolysis Liquids in Supercritical Mono-alcohols over Cu Doped Porous Metal Oxide ... 180
Chapter 6 A One Step Synthesis of C6 Sugar Alcohols from Levoglucosan and Disaccharides using A Ru/CMK-3 Catalyst ... 220
Summary ... 259
Samenvatting... 261
Acknowledgments ...264
