University of Groningen
Biomimetic metal-mediated reactivity
Wegeberg, Christina
IMPORTANT NOTE: You are advised to consult the publisher's version (publisher's PDF) if you wish to cite from it. Please check the document version below.
Document Version
Publisher's PDF, also known as Version of record
Publication date: 2019
Link to publication in University of Groningen/UMCG research database
Citation for published version (APA):
Wegeberg, C. (2019). Biomimetic metal-mediated reactivity. University of Groningen.
Copyright
Other than for strictly personal use, it is not permitted to download or to forward/distribute the text or part of it without the consent of the author(s) and/or copyright holder(s), unless the work is under an open content license (like Creative Commons).
Take-down policy
If you believe that this document breaches copyright please contact us providing details, and we will remove access to the work immediately and investigate your claim.
Downloaded from the University of Groningen/UMCG research database (Pure): http://www.rug.nl/research/portal. For technical reasons the number of authors shown on this cover page is limited to 10 maximum.
Chapter 4 – Paper II
Reduction of Hypervalent Iodine by Coordination to
Iron(III) and the Crystal Structures of PhIO and PhIO
2Iodine L3-edge XANES spectra using reference compounds with formal iodine oxidation states spanning -1 to +7 show that iodine in an Fe(III) coordinated iodosylbenene (PhIO) is reduced compared to parent hypervalent PhIO which has structurally characterized.
This chapter has been published as
C. Wegeberg, C. G. Frankær, C. J. McKenzie Dalton Trans. 2016, 45, 17714 – 17722
The supporting information can be found on https://doi.org/10.1039/C6DT02937J
Chapter 4
50
Reduction of Hypervalent Iodine by Coordination to Iron(III) and the Crystal Structures of PhIO and PhIO2
51
Chapter 4
52
Reduction of Hypervalent Iodine by Coordination to Iron(III) and the Crystal Structures of PhIO and PhIO2
53
Chapter 4
54
Reduction of Hypervalent Iodine by Coordination to Iron(III) and the Crystal Structures of PhIO and PhIO2
55
Chapter 4
56
Reduction of Hypervalent Iodine by Coordination to Iron(III) and the Crystal Structures of PhIO and PhIO2
57
Chapter 4
58
