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Sigma-Bond-to-Ligand Charge Transfer Transitions and Excited States of d6 Metal-Diimine Complexes. - CONTENTS

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Sigma-Bond-to-Ligand Charge Transfer Transitions and Excited States of d6

Metal-Diimine Complexes.

van Slageren, J.

Publication date

2000

Link to publication

Citation for published version (APA):

van Slageren, J. (2000). Sigma-Bond-to-Ligand Charge Transfer Transitions and Excited

States of d6 Metal-Diimine Complexes.

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Chapterr 1 Introduction: Excited States in Organometallic Chemistry 7

Chapterr 2 Research Methods and Backgrounds 29 Chapterr 3 Tuning the Excited State Properties of [M(SnR3)2(CO)2(a-diimine) (M 49

== Ru, Os; R = Me, Ph)

Chapterr 4 The Excited-State and Redox Properties of [Ru(L0(L2)(CO)2(iPr- 73

DAB)]] Complexes Bearing One or Two Electron Donating RuCp(CO)2 Axiall Ligands

Chapterr 5 FT-EPR Study of Methyl Radicals Photogenerated from 95

[Ru(Me)(SnPh3)(CO)2(iPr-DAB)]] and [Pt(Me)4(iPr-DAB)]: An

Examplee of a Strong Excitation Wavelength Dependent CIDEP Effect

Chapterr 6 The Complexes a's-[Rh(R)2(I)(CO)(dmb)] (R = Me, iPr; dmb = 4,4'- 111

dimethyl-2,2'-bipyridine):: Synthesis, Structure and Photoreactivity

Chapterr 7 An Experimental and Theoretical Study of the Electronic Transitions 123

andd Emission Properties of [Pt(I)(CH3)3(iPr-DAB)], [Pt(CH3)4

(a-diimine)]] and [Pt(SnPh3)2(CH3)2(iPr-DAB)]

Chapterr 8 Influence of the Metal-Ligand Interaction and the Character of the 143

Electronicc Transitions on the Resonance Raman Spectra of d6 Metal-Diiminee Complexes

Summary/Samenvattingg 163

Dankwoordd 173 Listt of Publications 176

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