Sustainable production of plastics (BioBTX)
André Heeres, PhD• BioBTX, Zernikelaan 17, 9747 AA Groningen, The Netherlands
• University of Groningen, Nijenborgh 4 9747 AG Groningen, The Netherlands
20
thCentury: The great acceleration
• Growth of population by a factor 3.7 • Annual extraction growth
- construction materials a factor of 34
- ores and minerals by a factor of 27
- fossil fuels by a factor of 12 - biomass by a factor of 3.6
• Total material extraction grew by a factor of 8
21
thCentury: Population
• Population growth (2050 – 9.7 billion)
• Per capita consumption growth (up to 3 billion consumers moving from low to middle class consumption till 2030)
• Increased need materials
Plastics from biomass
• Sustainable Consumption and Production, utilization of natural resources: an attractive alternative?
• About 40% of plastics contain aromatics.
(Bio)aromatics: applications
Prices BTX strongly dependent on oil price (benzene $900/ton, toluene $800/ton, p-xylene $1050/ton (oil about $60 barrel))
6
Technology: Catalytic pyrolysis towards
aromatics/BTX
In situ catalytic pyrolysis
• Efficient one-step process
• Sustainable, low carbon footprint
• Non food and cheap biomass
• Conventional zeolite catalysts
• Moderate yields of BTX (5-25%, depending on biomass/conditions)
• …….. but the “life time” of the catalyst??
Ex situ aromatization
• Extended life time of the catalyst
• Ability to use highly contaminated/wet biomass streams
• More “tools” for optimization
1. Thermal cracking 2. Catalytic conversion 3. Liquids collection
BioBTX History
4-1-2019 11
Event
2009 BioBTX ideation: Bio-based, drop in aromatics 2012 ICCP technology, experimentation started
2012 BioBTX B.V. founded by KNN, Syncom University Groningen RUG 2016 World’s First 100% bio-PET RUG, Sunoil,
Syncom, Cumapol 2016 Winner Bio-based Innovation award Europe
2017 Carduso Capital invests in BioBTX
2017 BioBTX independent company with 4 employees CEO: Pieter Imhof CTO: Niels Schenk 2018 Start pilot plant for liquid biomass
Aims BioBTX
BioBTX: innovative technology provider for sustainable production of
BTX
Waste to chemicals
Non-food end-of-life materials
Replacement of fossil feedstocks (decoupling and CO2) Added value (compare incineration)
Integration in existing chemical infrastructure (drop-in chemicals)
Combine biobased with circular!
Biobased and circular economy
14
•
An example BioPET 100
•
Recycling BioPET 100
Recycling plastics (PET as example)
15
BioBTX’ flexible technology
Biomass
Fluid: glycerol, fat, oils
Solid: Agro-waste, wood, lignin
End-of-life materials: plastics, composites, mixtures
BioBTX technology: economic feasibility
Positive ROI at low oil price
Valorisation of all products
obtained
Aromats, gas, coke & char
Local plants
Location and size dependent on
availability feed stock and infrastructure
Modulair production units
BioBTX summary
Innovative start up, SME Collaboration with RUG, Hanzehogeschool and
industrial partners
Via RUG labs, Innolab to Zernike park VC and private shareholders
Supported by regional, national and European
subsidy programs