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Sustainable production of plastics (BioBTX)

André Heeres, PhD

• BioBTX, Zernikelaan 17, 9747 AA Groningen, The Netherlands

• University of Groningen, Nijenborgh 4 9747 AG Groningen, The Netherlands

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20

th

Century: The great acceleration

• Growth of population by a factor 3.7 • Annual extraction growth

- construction materials a factor of 34

- ores and minerals by a factor of 27

- fossil fuels by a factor of 12 - biomass by a factor of 3.6

• Total material extraction grew by a factor of 8

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21

th

Century: Population

• Population growth (2050 – 9.7 billion)

• Per capita consumption growth (up to 3 billion consumers moving from low to middle class consumption till 2030)

• Increased need materials

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Plastics from biomass

• Sustainable Consumption and Production, utilization of natural resources: an attractive alternative?

• About 40% of plastics contain aromatics.

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(Bio)aromatics: applications

Prices BTX strongly dependent on oil price (benzene $900/ton, toluene $800/ton, p-xylene $1050/ton (oil about $60 barrel))

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6

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Technology: Catalytic pyrolysis towards

aromatics/BTX

In situ catalytic pyrolysis

• Efficient one-step process

• Sustainable, low carbon footprint

• Non food and cheap biomass

• Conventional zeolite catalysts

• Moderate yields of BTX (5-25%, depending on biomass/conditions)

• …….. but the “life time” of the catalyst??

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Ex situ aromatization

• Extended life time of the catalyst

• Ability to use highly contaminated/wet biomass streams

• More “tools” for optimization

1. Thermal cracking 2. Catalytic conversion 3. Liquids collection

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BioBTX History

4-1-2019 11

Event

2009 BioBTX ideation: Bio-based, drop in aromatics 2012 ICCP technology, experimentation started

2012 BioBTX B.V. founded by KNN, Syncom University Groningen RUG 2016 World’s First 100% bio-PET RUG, Sunoil,

Syncom, Cumapol 2016 Winner Bio-based Innovation award Europe

2017 Carduso Capital invests in BioBTX

2017 BioBTX independent company with 4 employees CEO: Pieter Imhof CTO: Niels Schenk 2018 Start pilot plant for liquid biomass

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Aims BioBTX

 BioBTX: innovative technology provider for sustainable production of

BTX

 Waste to chemicals

 Non-food end-of-life materials

 Replacement of fossil feedstocks (decoupling and CO2)  Added value (compare incineration)

 Integration in existing chemical infrastructure (drop-in chemicals)

 Combine biobased with circular!

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Biobased and circular economy

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An example BioPET 100

Recycling BioPET 100

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Recycling plastics (PET as example)

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BioBTX’ flexible technology

 Biomass

 Fluid: glycerol, fat, oils

 Solid: Agro-waste, wood, lignin

 End-of-life materials: plastics, composites, mixtures

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BioBTX technology: economic feasibility

Positive ROI at low oil price

Valorisation of all products

obtained

 Aromats, gas, coke & char

Local plants

 Location and size dependent on

availability feed stock and infrastructure

 Modulair production units

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BioBTX summary

 Innovative start up, SME

 Collaboration with RUG, Hanzehogeschool and

industrial partners

 Via RUG labs, Innolab to Zernike park  VC and private shareholders

 Supported by regional, national and European

subsidy programs

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Acknowledgement

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