Verslag Colloquium spectroscopicum internationale XXIV

Dr H

.

G.

de Ruig

RAPPORT

85.87

Verslag Colloquium Spectroscopieurn

Internationale XXIV

Verzendlijst: direkteur,

sektorhoofden,

direktie

VKA,

bibliotheek

(2x),

afd.

SERH (4x)

,

Projektbeheer, Projektleide

r (De

Ruig),

circulatie.

8587

Het Colloquium Spectroscopieurn

Internationale

XXIV

omvatte

61

voor-drachten op uitnodiging in 3 parallelseries

en

ongeveer 340 posters,

gegroepeerd in

40 onderwerpen. Er waren 891 deelnemers uit

42

landen.

Aan de

instrumentententoonstelling

namen 43 firma

'

s

deel.

In

het navolgende wordt verslag

gedaan

over

een aantal

voordrachten

en

posters

.

De titels van

alle

voordrachten

en

posters zijn in de bijlage

vermeld.

Isotoopeffecten

van door

enzymen gekatalyseerde

reacties veroorzaken

verschuivingen

in de isotopenverdeling

van H,

C,

N

en S

in in

organische

moleculen. Uit deze verschuivingen uitgedrukt

in

"J-waarden", bepaald

met MS of NMR, kunnen

conclusies

getrokken \>lorden omtrent

aard en

her-komst van voedingsmiddelen. Er kan

op

deze wijze

o.a.

onderscheid

ge-detecteerd worden in klimatologische omstandigheden. Andere

toepassin-gen van deze "natuurlijke labelling" zijn:

aantonen

van vervalsingen

van wijn, vruchtesappen, honing,

toevoegingen van

water

aan

dranken,

onderscheid tussen biogene

of synthetische

vanilline, menthol

of

azijnzuur, onderscheid

tussen

riet- en

bietsuiker (Schmidt).

Na

een eenvoudige monstervoorbereiding

(alleen malen

en

tabletteren)

is

röntgenfluorescentie een

handige techniek voor het bepalen

van een

reeks

elementen

in tal

van matrices: bodem,

stof, meststoffen,

zuiveringsslib, afvalwater,

voedingsmiddelen

en

veevoeders, vruchten

(Rethfield).

Demtröder

besprak

high-resalution moleculaire UV

en IR spectroscopie

met behulp van

lasers

van

moleculen

in

de gasfase.

Hiermee kunnen

ondubbelzinnige

UV

spectra

verkregen worden

met

de

fijnstructuur

van

de

electronenovergangen. Ten opzichte

van

"normale

"

UV detectie zou de

gevoeligheidswinst bovendien een factor

106 bedragen;

in

het IR

gebied, met gebruikmaking van een IR laser en een

bolometer,

gekoeld

met vloeibare He,

een

factor

103,

Apparatuur

voor

een en ander

is

voorlopig

nog niet

commercieel verkrijgbaar

.

--

2

-Er

zi

jn

recente ontwikkelingen in de bestudering van polymorfie van

farmaceutische

pr

e

para

ten

met

s

pectroscopische

technieken

(Röntgen-diffractie

en

IR spectroscopie). Dit is

van

grote praktische betekenis

in

verband

met verschillen in

eigenschappen van

de verschillende

modi-ficaties. Een en

a

nder

werd door HegedUs gedemonstreerd

aan

de

hand

van pr

edolsalon (3

modificaties met verschillende oplossnelheden),

mebendazol

(verschillende

bioactiviteit) en cimetidine

(verschillende

technologische parameters bij de bereiding).

Grasselli

besprak

toepassingen

van

FTIR en Raman in

industrt~le

laboratoria, onder

andere

onderzoek van ongerechtigheden op

het

opper-vlak van

plastic flessen, het opnemen

van

alkanen

onder druk

e

n

onderzoek

aan krukas

se

n

met diffuse reflectie

.

Ze

was

erg trots op

een

fraai spectrum

van

500 ng polystyreen en

zag

grote mogelijkheden

voor

Raman, o.a. bij de analyse van micromonsters drugs

(herolne).

Een on-line combinatie GC-FTIR-FTHS geeft informatie over functionele

groepen

(IR),

fragmentatie

(EI-MS

)

en moleculair gewicht (CI-MS

).

Nodig:

~g

hoeveelheden

(Wilkins).

Met time-resolved FTIR na matrix isolatie kunnen spectra

van

onsta-biele moleculen

worden

opgenomen

(Turnec

). Hoewel

de theoretische

detectiegrens van IR in de orde van

1

ng ligt, wordt IR spectroscopie

zelden toegepast voor

hoe

veelheden beneden

10

~g.

Matrix isolatie van

b.v. IWLC fracties biedt de mogelijkheid de praktisch toegankelijke

detectiegrens omlaag te brengen

(Bod

e

).

Interessant vond ik de poster van Mrs

Zijba

over forensisch onderzoek

v

an

smeerolies m.b.v. infraroodspectroscopie, nl.

voor

het

identifi-ceren van verdachten

bij

auto-

ongevallen,

~11aarbij

een betrom11baarheid

van 1%

veelal

voldoende geacht werd.

Het

be

hulp van

informatietheorie

werd

door Fl6r!_án inzicht

verkr

egen

in de

betrou\11baarheid

van

spectrachemische meercomponent-methoden,

terwijl Doerffel met behulp van correlatiefuncties de signaal-ruis

verhouding wist te

verhogen

.

--

3

-Mantsch besprak biologische

toepassingen

van infraroodspectroscopie

.

Met FTIR is het thans mogelijk biologische monsters

in

water te

be-studeren: identificatie en

differentiatie van

pathogene bacteria,

in

situ onderzoek

van bloed,

bacteri~n

behandeld met

alkohol, enz.

Recente

ont1o1ikkelingen

hebben de toepassing van NMR bij onderzoek van

enzymen

mogelijk

gemaakt, zowel in

vitro

als

in vivo. Volledige

struc-tuuropheldering

is thans

mogelijk. Het NNR onderzoek van

intacte

systemen is een

multimiljoen

dollor

bussiness (Campbell).

Wat

de atoomspectroscopie

betreft, werd

er

uiteraard veel

aandacht

be-steed aan

ICP,

maar ook

aan grafietoventechnieken. Sturgeon

wees

er op

dat

deze laatste techniek

nog

moeilijk

theoretisch

te onderbouwen is,

vooral

omdat er geen evenwichtstoestand optreedt, Chakrabarti

daaren-tegen

presenteerde

een thermodynamisch evenwichtsmodel. Bij

de

posters

waren

er talrijke

toepassingen.

Er was

relatief weinig op het

gebied

van massaspectrometrie,

vermoede-lijk vanwege het

vrijwel gelijktijdige gespecialiseerde

massaspectro-metercongres in

Swansea.

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BIJLAGE

Lij

s

t van

voordrachten en

post

e

rs

Colloquium

Spectroscopieurn

Internationale

XXIV

code MO A IL16 MO A IL04 MO A ILlO MO A IL13 MO A IL53 MO B IL44 MO B IL41 MO B IL35 MO B IL36 MO B IL19 INVITED LECTURES SESSION A V.A. rassel

Analytica! ICP Speclroscopies: Past, Present and Future P.W.J.M. soumans

A centu~y of Speetral Intcrfer.ences in Atomie Emission Spectroscopy -Can we Master Them with Modern Apparatus and Approaches?

r..

de Galan

Low Power ICP - Physical Principles and Analytica! Applications

J.L. oe Vries

X-ray Speetrometry - Past and Future R. van Grieken

Energy-Dispersive X-·ray Spectrornetry: Present State and Trends

INVITED LECTURES SESSION B

s

.

sasaki, K. Funatsu, C.A. Del Carpio, H. Abe Automated Structure Elucldation System - Chemica E. Pretsch, J.T. Clerc

Spectroscopie Data Banks A. ~lizuike

Preconcentration Techniques for Inorganic Trace A~alysis H, ~luntau

The Problem of Accuracy in Bnvironmental Analysis K. Fuwa

Analysis of En~ironmental Materials Usi~g Spectroscopie Methods

VII Page 00 2 002 00 3 003 004 00 6 006 007 007 008

,

..

VIII ' :7~ ~NVITtD LECTURES Code Page ~10 c IL52 1•10

c

IL31 ~10 C IL28 HO C IL20 HO C-ILSS HO A 017 ~lO A 065 HO A 117 HO A 194 HO A 343 ~10 A 380 HO A 414 '· ' ' ·-'' SESSION C

J.J. Turner, H. Pol iakot:f . ~-·. IR Spectroscopy for Unstable Holecules

.. '

,

,

_\:·IC

w.

Kiefer -~ .,

-.

-'

New oevelopments in Ra man Speobrosoopy

T. Hirschfeld ') '-J , ,I

Remote and In-situ Sensors·

' I . :r.

J.G. Grasselli, M. Hehicic, J.R. Mooney

Applications of IRandRaman Specttoscopy·in 1ndus~r~ ï·! •. ~ r · _'j .1 r· ~ :· · t. i

C.L. 'Nilkins I'.-

"'

..

..

)'

New oevelopments in GC-IR-MS and Fourier Hass Speetrometry :.·"..,! :: . ',. -.. i c ~ ~· -POSTERS sgssior~·II ''. : ·J:iJ>J ' · '• . · I ,

..

.· t.'l ~ x-ray: quantification P.A. Pella, G.Y. Tao, .G. Lachance, R; Rousseau· ·

NBSGSC - a Fortran Program for Quantitative~x~r~~ Fluorescence Analysis

M. Boybay

correction for Absorption Effect; ih-XRF Analyeis of Fly llsh and Cement Samples r. . .• ,_ ... ::.

A. Rachetti, W, Wegscheider, K. MUller

Methods for the Characterizat1on of the -~~idual Matrix in Energy

Oispersive X-ray Speetrometry

B.A.R. Vrebos, J.A. Helsen

Evaluation of correction Algorithms, Using Theoretica! Influence Coefficients

T. Fadgyas, S. Török, i/. Mèr.ay·· ·'

Optimization of Hultielement Qualitative X-ray Fluorescence Analysis based on Information Theory

.· . . •

N. Saitoh, K. Fujisawa, 1\,·'Iidá,' Y\~ Goh'shi A New lipproach to Oerivative oeconvolut:fon"

~1. Gaber •• :.11 • .., •. \ .·

The ~lean Energy of Backsèattered· ·E'leetrons 'at va'riou·s Angles of Incidence .. ~ , • . : ·' ~ _ 1 r · : :. ,i, _· \ :" , ; :, : ";. 010 010

·

o

11 012 0 13 016 018 020 022 024 026 0 28

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111

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'!I u 11 ~ ·Code ~10 B 001 ·, MO B 005 HO B 072 ~10 B 087 MO B 237 MO B 298 MO B 468 MO B 489 MO C 060 MO C 076 r· .. ;POSTERS SESSION B X-ray: analytica! .:.··

,

.

-P. Hoffmann, T. Hofmann, N, Pilz, H. Hofmann, K.H. Lieser

In-Line and Non-oestructive Analysis of solutions and Sclid Sample&•

Using XRF Induced by Radionuolides J . J , LaBrecque, P.A. Rosales, G. Mejias

The oetermination of Rare-Earth Elements by-Two Non-Conventional

Radiometric Methods Employing Pm-147 and Cd-109 Nuclides

J, Arber, o.s ... urch, N.G. Wc3t.

oetermination of the Valency of Chromium by High Resolution X-ray

Fluorescence Spectrometry: Analytica! Applications in occupational Hyqiene

J, Laursen

Biomolecular Thin Film samples Analysed by EDXRF

G,J, Manenschijn

Research to the Possibility pf the Oetermination of Sulphur and Phosphor in Iron-Alloys at Smal! Area by X-ray Spectroscopy

P.L. 11arren

Automated Qualitativo Elcmental -Analysis of Unknown Materials by

X-·ray Fluoresconce. Speetrometry A,A, Fakhry

X-ray Energy Spectrometry· for Quantttative Estimation of some

Rare Earth Elements in Egyptian Phosphorite samples

IX Page 0 32 034 036 038 0 40 042 ·044

R. Horn, o.s. urch . 0 4 6

Chemica! Effects in the .x-ray Emis:>io_n Spectra of sulphur

'

-POS.TERS· ,.

.

;

SESSION Cr

UV/VIS: met)1odical

( • ... • • 1 •

K, Yamaya, E. Satoh, M, Yoshida

Fluorimetric Oetermination

ot

S~bmicrogram Amounts of Silicic Acid

with Benzoin and Mannitol

T. Hadeishi, H.J, Pollard, R.Q, McLaughlin

A High Sensivity, High Speelftcity Molecular Detector Utiliztng

Differentlal Absor~tion of Atomie Emission Lines in the Near Vakuum

Ultra Violet

050

x Code NO C 091 110

c

104 HO C 11.0 MO C 192 HO C 210 ~10

c

295 HO C 474

T. Koh, T. Endo, Y, Miura 'l

-Spectrophotometr ie Determ·inat ion of. ~licro. J\mount·s~ of Sul f iöe by

Pormation of Thiocyanate

.

.

-G, Gaug1itz, R, Goes, ~1. G.uthcr,

w.

Stoof! .,,.,··

Photochemical and Photophysical Properties of Laser Dyes Examined by

Simu1taneous and Sequentia! Absorption and rluorescehce·Spectroscopy

.>'

K.-P. Koch, H. Schlemmer, M. ~lächler ..

Optica! Multichannel Dispersion Spectroscopy of Liquid Thin rilms:

A New Analytica! Tool

.,

3·· :. t • •

G, Ramis Ramos, M.C, Garcia Alvarez-Coque,:C, M6ngay rerhandez

Spectrophotometric Determination of Binary Mixtures of Compounds with

Very Close Absorption Maxima< . ; ·. · ... .!.>J·.·,_,f

., 'I • , ... '::. •>:

1~. Liekmeier, u. Liesenfold .·· 1_{~ ?.i~ 1r}

Sample Identification by UV/VIS Spectra Library seàtèh.~C

- Optimisation of search Procedures with a Library

of UV/VIS spectra of Pharmaceutically.Active compóunds!~·

R.M, ~liller, C,T, Tye, I,P, Vickery . .. r:" . ~

Impulse Response Photoacoustic Spectroscopy in the Study of Time

Dependant Physico-Chemical Processes·

J. Mocak

computer-based Spectrophotometric Monitoring of Two-step Reaction

Kinetics - Determination of Rate-constants and Intermediate J\bsorption

Spectrum

POSTERS SESSION D

Applicat·Lons: 'bio'lcigical, pharmaceutical

,

-·

.

..

~10 D 009 . ~1. Hoenig, P. van Hoeyweghen .. · <:· ···:' ' '·

~10 D 0 78

MO D 125

MO D 146

Determination of Selenium in Animal Tissues with Platform rurnace

Atomie Absorption Speetrometry and Deuterium Background correction

~ .... . I ' :.1

J. Stupar, R. Ajlec, J, Korosin, p, Lobnik

Comparison of Different Spectroscop.ic· -1-l.e.thods .for Determination of ·

Phosphorus in Plant Materi<rls1 • so·U: E)(.tra·cts' 'and' 'rertilizers

')• B, Hegedüs

Pharmaceutical Aspects of the Rese~rch. of' Pblymorphism by

Spectroscopie Methods· . · ··

'

. ,._·. •, G, Milch, E. Szabo

Derivative Ultraviolet Spectroscopie Assay of the Active Ingredient

Content of Some Pharmaceutical Tablets

Page 054 056 058 060 062 0 64 066 070 072 074 076

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ll code HO D 283 HO D 306 1·10 D 362 HO D 390 HO D 411 ~10 D 476 HO D 477 HO E 124 HO E 128 HO E 176 HO E 211 H. Harinov, G. Oimitrov

Laser Microspectral.Analy~is· in·Diological·'Hatrix

A.L.H. Geyer, J.C. Horeira, A.J. Curtius

Distribution of Elements in the Red Algae Pteröcladia Capillacea

~.M. Kurepa, M.N. Tomasevic, v.v. Urosevic

Investigation of Fluorescence Emission Spectra of Chlorophyll

Holecules "In vivo"

R.J. Obremski, J, Hiller, H. Scott

Application of FT-IR and Vector Based Software to Problems in

Aqueous and Biological-Systems.

v.o. Chebotareva, v.G. Haidannik, A.P;·Pecheny, v;c. Burlay,

I.V. Bagdasarova, E.M. Ischenko

EPR Signals of Renal, Liver and Other Tissues in Hice with Experimen~al

Pyelonephr· i !:.is·

... ,

.

~

Th.J, Spi'l_re_nh.urg, A .. J. Baars, 11. van Bee~, G.J. de Graaf, H,G, Beeftink

J. Nieuwenhuize

Environmental Heavy Hetals in a ·Salt Narsh •and Their Effect on 'sheép

E.J. van der Molen, Th,J, Spierenburg, G.J. de Graaf, A.J. Baars

carbadox-Induced Changes in Aldosteron and Ion-Levels in the Blood

of Heaned Pigs

POSTERS

SESSION E

Applications: environmental

J,G, Edwards, S.J. Haswell, C,J, Jackson

Development and Validatien of a Field sampling and Molecular

Spectrophotometric Analysis Procedure for the Determination and

Specialion of Chromium Plating Mists

~· Pedersen

The Determination of Multiple Inorganic Arsenic Species in workplace Air

V.N. oreshkin, Yu.I.. B!'!lyaev,-.c,r"' Vnukovskaya

Innovation in Atomie Absorption Oetermination of Heavy Hetals in

Environmental Samples by Oireet Flameless Atomization of Powders

A. Klok, J,J, Tiggelman, p, Weij, J.P.J. van Dalen, L. de Galan

Metal Analysis in Plaster of Paris and Ind~strial Phosphoric Acid

Using ICP-AES~ X-RFS and Other Spectroscopie Technics

: •:.

.

_~:· XI Page 0 78 080 082 084 086 088 089 092 0 94 096 098

XII Code ~10 E 269 110 E 325 HO E 395 HO F 016 HO F 018 HO F 0 92 ~10 F 234 HO F 324 HO !' 344 HO F 383 HO F 384 HO !' 408 • 1' I' A. Mazzucote11i, R. Fr~ch~

Behaviour of Rar~r Hetal E1ements in Environmental samples in

Electrotherma1 Atomie Absorption Speetrometry

A. Aziz, A. Sabet, F. Abu-Dagga

-

..

Trace Heta1 Oetermination in Environmenta1 Reference Hateria1s _{\ .}

- An Evaluation of ICP-OES ~lethod for Environmenta1 Application

H.J.M.P. Houra, H.T.s.o. vascon~~1os

1

A.A.s.c. Ma?hado

Determination of Lead in Atmospheric Aeroso1s by Direct Ana1ysis of

Filters by Graphite Furnace AAS

.

, ; • ; 'I POSTERS • ~ I "l SESSION !' ICP: fundamental n ~ . \' E· ._. ;:· • --· N. I. Gulko

usage of the Reference Elements in An~lysis of Monom~~e!;"!ll ~licrosamp1es

by AES with ICP

..

_-...

Page 100

10 2

10 4

10 8

D.C.F. Garbutt, D. Hardman, M,A. Noble, A.A. Verbeek 110

on Single Channel Internal Standarditation and Tree~An~lysis Using ICP-OES _; 'l l

N.W. Barnett, D,E,M. Spillane, A.A.H, Taobi

some Practical Measurements of Noise Spect~a ~n Plasma Emission

Spectroscopy

D.F. sermin

The Role of Internal standards in ICP-OES Spectrome~ry

A. Delijska, M. vouchkov

Possibilities for Correcting the Inf1uence of Mineral Acids and of Drift in ICP Emission Spectra Analy~i~

w.

schrader, B. Grote

The Use of Meyers-Tracy Signa! compensation technique in

ICP-AES for the Analysis of Samples Containing High Dissolved Solids

V.M. Goldfarb

Excitation and Ionization in a Capacitive Current Region above the

Inductively Coupled Plasma

P.B. Farnsworth

studies of Energy Transport .. and A.n.al,yte Excit~tion in the Inductively

Coupled Plasma Using.Pulsed Excitatfon

. '\

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.

.

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G. Gillson, G. Horlick

•• • " .. ~ ~ ' r

11easurement of Ground State Neut,ra1< A~~-~₁ ~nd Ion .. Spatlal Distributions

in the ICP Using Dye Laser Excited Atomie Fluorescence Speetrometry

112 114 115 116 118 120 12 2 ·[

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èode HO G 099 HO G 149 110 G 20 5 ~10 G 213 MO G 248 110 G 261 1·10 G 345 ~10 G 369 HO G 398 HO G 409 HO 11 0 36 ~10 H 187 POSTERS SESSION G ICP: instniment~l L.l1. Faires

Inductively Coupled Plasma - rourier Transferm Spectrometry:

A New Approach to Spéctrochemistry and spectr9physics

R.D. Ediger, P. Barrett,

w.

Schrader

Design of an Integrated ICP/Robótic sample Preparatien system

J. Davies, R.D. Snook

Studies of a Low Noise Inductively Coupled Plasma (ICP) and Torch for

rourier Transferm Speetrometry (FTS)

P.s.c. van d~r Plas, .L. de Galan

Analytica! Applications of an Air-Cooled ICP, Using 1 L/~lin Total Argon

H. Z. 1·/rembel

Hercury-Assay Using RDP-AES

J .A.C. Broekaer~, ·r. Lei~, K. Laqua

Improved signa! Acquisition for the ICP-Injection Method

B. Grote,

w.

Schrader

ICP-AES Analysis of Trace Constituents in

w,

Nb, Ta, Mo and V Using

a !ligh Resolution Spectrometer

H. Pyrlik, K. Dietze. -K.A. slï'ckers

Spektrometrische Flüssigkeitsanalye mit Spectroflame - ICP

x.

l~ang, R.l1. Barnes

Model for Continuous Hydride Generation and Inductively Coupled Plasma Speetrometry

s. 11arra, G. Horlick

Signal-To-Noise Ratio Characteristics of an Ind~ctively coupled Plasma Fourier Transferm Spectrometer

POSTERS

SESSION H

.

'

IR, Raman: theoretica!

s

.

Mohan, s. Durai

Infared Spectroscopie Investigations' ?f Praseodymium Trichloride (Prcl₃)

Lj.J. Bogunovic, M.D. Dragojevic, U.B. Mioc, s.v. Ribnikar

Estimation of the Solvent Eff.ec.t on H.ydrogen Bonds in solutions of Trimethylsilanol' and

Tri

p

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.

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XIII Page 124 126 128 130 132 134 136 138 140 14 2 144 146

XIV code 1·10 B 330 ~10 H 352 ~10 H 377 ~10 I 004 HO I 013 HO I 0 62 ~10 I 17 2 ~10 I 363 ~10 K 008

m

K 148 I . Iweibo, T. Abe _{'. '\, ~ ' . '"J f '; ; ; .} I ,l >

On the Expresslons for the Oscillator, S_t;:r~.ng~h,

9J

,

E1~"c.t~?niç .. Tra.l'\sitions

in Salution

G.A. Yeo, T.A. ford

Ab·Initio Molecular Orbital Calculations of the ~~~rared Spectra of

Hydragen Bonded complexes of water, Ammonia and Hydroxylamine

M.S. Afifi, S.M. Amer

Assignment of the Skeletal Vibrations of _{(CH 3 )3} S~OCH₃, _{(CH 3 ) 2} Si(OCH_{3 ) 2}

and CH₃ Si(OCH_{3 ) 3}

..

POSTERS

·SESSION I

Structural studies

G. Miksche, 1. Trummer, A. wolf, K. zojer

Study of the 23Na EFG Tensor of _{Na 2S}._{9H 20} for Oetermination'of cristallographic Data

M.H. El-Zaidia, A.A. Ammar, R.A. El-Malawany

A Study of the Infra-Red Spectra in Tungsten-Tellurite and

Zinc-Tellurite Glasses

v.v. Dimitrov, Y.B. Oimitriev

IR-Spectral Investigation of Metavanadate Crystal and Vitreous Phases

M.A. Ewaida, M.M. Abou Sekkina, Z.H. El-Gohary

Further Studies on the Effects of Heat Treatments and Titania Doping on

the Spect~o-Electrical Properties of some Silicate Glasses

A.K. Garg

Fourier Transferm Infrared Studies of the series Sn Sx Se₂_x (O~x~2)

POSTERS

SESSION K

IR, Raman: analytica!

A. Masui, M. Noshiro

Identification of Solid and Gaseaus Inclusions in Glass by Laser

Raman Spectroscopy

G. Platbrood, c. Laire, B. Barten, H. van De Velde

Study of the Relation between the Infrared Spectra of Anorganic Samples

and Their Granulometry Determined by features Analysis on a SEM-EDS Equipment

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R. Kellner, G. Götzinger, F. Kashofer

In Situ FTIR-ATR-Spectroscopic Study of the· Protein Adsorption on Hydrophilic and Hydrophobic Surfaces

C,J, Peacock

Analytica! Applications of Fourier-Transform Infrared Spectroscopy

J, Zieba

The Identification of Lubricating oils in stains on Clothing by

Infrared Spectroscopy for Criminalistic Purposes s. Gergely, J. Garaj

Determination of ~lolar Ratio Haneb/Zineb in Their Mixture by IR-Spectroscopy

M.J. Wojcik,

c.

Paluszkiewicz, M~ Bala

Infrared Spectra of flydrogen-Bonded Salicylic Acid and lts Derivatives

XV Page 17 2 17 4 176 178 180 *

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[i

-INVITED LECTURES I SESSION ·A . R,E, Sturgeon _··.

1:--Graphite Furnace Atomie Absorption Spectrome~ryt ;F~ç~~ ~nd ,Fiction

C.L. Chakrabarti, J,P, Byrne, S.B. Chang, C,K, Tan

A Thermodynamic Equilibrium Model for Atomization in çraphite Furn~ce

Atomie Absorption Speetrometry

K. Dittrich

Molecule Formation in Electrothermal Atomizers - Interferences and

Analytica! Possibilities by Absorption, Emission, and Fluorescence

Processes

J, Ruzicka

Flow Injection Analysis - A Survey of lts Potentlal for Spectroscopy

K. Hirokawa

State of the Art of Coherent Forward Scattering Spectroscopy

N. Omenetto !'• ·: ;

Laser Excited Fluorescence and looization Spectroscopy

-Analytica! Applications

INVITED LECTURES

SESSION. B

J, seelig

NMR Tomography and Spectroscopy in Vivo·

.

.

.

'

..

.

P,J, Derrick •,· .r. -·.:

New Techniques in Mass Spectroscopy at High Mass

A. Petraklev 1 ·" . ~ :·~ ·~'I • ' ]

Microspectrochemical Analysis with Laser AtomizatiQn

H. coufal

Photothermal Spectroscopy

and in Chemical Analysis

Applications in Surface Sciences

X VIl Page 182 182 18 3 183 184 184 186 186 187 187

XVIII code TU B ILO 1 TU C IL18 TU C IL15 TU C IL23 TU C IL24 TU C IL33 TU A 0 53 TU A 0 86 TU A 10 3 TU A 221 TU A 233 J.F. Alder

Optical Fibre Chemica! sensors

INVITED LECTURES

SESSION C K. Florian, M. Matherny

Informationstheorie - Ein Hittel fUr die Bewertung der spektrochemischen

Mehrkomponent-Methoden

K. ooerffel

Improving Signal-To-Noise by Evaluation of correlation-Functions

P.R. Griffiths

Infrared S6bctrometry of Surfaces by Diffuse Reflection,

Reflection-Absorption and Emission Techniques

P.L. Hanst

IR-Spectroscopy of the Atmosphere

H.H. Mantsch, H.L. Casal

Biological Applications of Infrared Spectroscopy

POSTERS SESSION A

Detectors, data handling, instruments

w.B. Barnett, w. Bohler, G.R. carnrick, w. slavin

Signal Handling for Graphite Furnace Analysis by Atomie Absorption

H. saaby Johansen

Use of a Microcomputer in Emission Spectroscopical Analysis of the

Stable Isotopes c-13 and N-15

G. Gauglitz, T. Klink, w. Schmid

Automatisation, Data Recording and Handling Demonstrated by HPLC

in Photokinetics

P. Taylor, P. Schutyser '

A Software Package for Operator Independent Quantitative Speetral

Analysis and Subsequent Data Treatment on ICP-AES Spectra D.F. sermin

A Critical Loo~ at Computer Curve Fitting Algorithms for OE, XRF and ICP

Spectrometric Analysis ;. Page 188 190 190 191 19 1 192 194 196 19 8 20 0 20 2

:

u:

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code

TU A 263 lil !IJ _{TU A 266}

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lil TU A 271 TU A 284 1111 TU A 339 11!1

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11 TU B 0 41

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lil TU B 175 ~

K. Janssens, P. van Espen, D. vermeir F ·.-·.

Interpretation of

E1ect~on-Micro~~6b~

0

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wlth

Á~i

ificia1

Inte11igence Techniques

R.F.M. Herber, H.J. Piete~s, R. Jager, F. S~hipaanboor~ Computer Aided Signa1 Analysis of Electrothermal Atomization Atomie Absorption Speetrometry

F, Gaillard, R. Bador, Use of Micro-Computers Electron-Induced X-ray

c. De~uzi~ges, M. Romand

for Data Acquisition and $pectrometry (LEEIXS)

' • .._J.

Ana1ysis in Low-Energy

E.P. de Lima, M.A.F. Alves, M. sa1ete, s.c.P. Leite, R. Ferreira Marques, A.J.P.L. Policarpo

Detector Features and some Mechanisms Associated to Self-Quenching Streamers

'I 1,. ~ I

T.L. Pap, J. Inczedy

Effect of Different

smo~th

.

{ng ~lethods

on.

Sp~c\

J~

~

·

Li~~

,

~

··

in Emission

Spectrographic Analysis

v. Karanassios, G. Horlick

Speetral Characteristics of a New Spectrome~er Design for Atomie

Emission Speetrometry

H. Bubert, R. Klockenkämper

• J

Improvement of Precision in Spectrochemica~ Analysis by Correlation

of Intensity Measurements POSTERS SESSION B ,

.

.

.

..

MIP, DCP K.J. Timmins

sample Introduetion -into a ~i~rowave-I~auc~d ~lasma

R. Ishida, Y, Fujishiro, s. Nishiura, H. Mizuno, E. Onaki, N. Nishiura A DC-Plasma Light souree

N.W. Barnett, L.S, Chen,, c,~. ~~ee?way

sample Introduetion Technlq~es f~~,use.wit~ Mic~owave-Induced Plasmas

G,A, Meyer

conical Three-Electrode Direct curren~ Plasma for Optical Emission

Speetrometry

-E.N. Savinova, T.V. Shumskaya.

The Plasma Jet as a

,

.so

~~~~

of,

~xc

i~~Ü

~

n

Óf Atomie Spectrums of Nonmetals ' ' XIX Page 20 4 20 6 20 8 210 21'2 214 216 220 222 224 226 228

XX 'fU.B 204 TU 13 30 7 TU B 367 )'U. C 011 TU C 0 31 TU C 0 35 TU C 048 TU C 071 TU C 0 74 TU C 0 81 TU C 137 TU C 164

H.M. Abdi1lahi, R.D. snook

H~crowave Induced Plasmas for _. the _I Determination of Non-l·leta1s

N.Z. Pavlovic, H. Harinkovic

The App1ication of New Construction of Stabilized Are Device with Aerosol Supply for Direct Plasma oiagnostics

' I B.A. Belchev

Apparatus and Metbod for Direct Speetral Anal~sis of Liquids

POSTERS SESSION C ,•

Applications:. industrial próducts

w.

Jaxa-Bykowski

. ~pectroch.emi~a.l, D~termination of Contaminations in High Purity calcium

Phosphate

~~. Taddia

Determination of Silicon in Gallium Arsenide by Electrothermal AAS using the L'Vov Platform

v.

Spevackova

Determination of Some Impurities in Ammonium Diuranate by Atomie

Absorption Speetrometry

H. Tanaka, K. Sushida, H. Saisho

Determination of Trace Elements in Zirconia ceramics by Inductively

Coupled Plasma Emission Speetrometry K. Reyniers, R. Carleer, J.-P. Francais

Determination of Minor and Trace Elements in zirconium Dioxide by lleans of ICAP-OES

o.

Buresch,

w

.

Hönle, H.G. von Schnering

!CP-Analyse von P/I-Verbindung,en

J, Stupar

Determination of some Rare Earth Elements in

uo;

by ICP-OES

P. Hisaelides, K, Bethge, J; Krauskopf, G. Wolf

Determination of Oxygen and Carbon in GaAs Using 3_{He- and Deuteron}

Activatien Analysis

J, Amouroux, F, slootman, H. Apostolidou,

o

.

"Horvan

Application of Emission Spectroscopy for Control and Diagnostic of a

Plasma Refining Process of Silicon correlation between Spectroscopie Meas~rement During Purification a~d Pr~perti'es of the silicon

after Treatment Page

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code TU C 190 TU C 267 TU C 351 TU D 0 68 TU D 084 TU D 218 TU D 303 TU D 378 TU D 453-TU D 454 TU E 077

H.~1. Abou Sekkina, E. El..:She~eafy

;·

,

·.

··

;··

·

Speetral

P~opertiei

and

Temperat~re

_.

.

De~endenc~

·

of

....

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.

..

' . _ .. . Sem~conductivity

of Various Doped Bismuth 'Trioxide Polycrystals

R. Braun, F. Geyer, E. Hainka, I!.G. Mü~l_ei-;_·,.7. 'Neuber

A Preliminary study on the Determination of cerium and uranium in

Radioactive Waste

·'

Ch. Berthelot, H.L. Eschbach, V. Verdingh, S, Herrmann

The Analysis of Rare Earths and Cadmium in Reference Haterials:

Li₂so₄ and HnS0₄ ...

..

..

:

POSTE.RS

SESSION .D _,.·

.

' "'..!•'

' : • ••• ~~ : ~-.t ! 1 ..

f'lame, graphite fyrp,afr

9

,?_~s '>:

H. Falk, E. Hoffmann, Ch. Lüdke, H. Cze~wensky __

• • • I . ; · ' •

Hultielement Trace Analysis with ~he f'AN~è-syste? ~~

P. Tittarelli, T. Zerlia, G. Lavorato

Bridging the Gap between Atomie and Holecular Speetrometry

I. Lakatos, J, Lakatos

Direct f'AES and FAAS Analysis of ~ispersed Systems

I. Ogasawara, T. Nishikawa, T. Sakaguchi,_,Y. p~yagi

The Dually-Used Normal or/and Inverted Flame Burner (the so-Called 3RD

Burner) Applied to the Flame Photome~ries

pf

(1) Hicro Amount of Barium

in Calcium and (2) Germanium by Ge-H Band

E. Lundberg, D. Baxter,

w.

Frech

Constant Temperature Graphite Furnace - Computer Controlled Echelle

Spectrometer System for Átomic Emission Speetrometry

E.D. Prudnikov

Some Theoretica! Aspects in Atomie Analytica! Spectroscopy

E.D. Prudnikov, Y.s. Shapkina

Some Advances in Atomie An;;tlytical Speetrometry

POSTERS

SESSION E:

\ - J'

'

..

,

·.4-:.

:-Fuina~e AAS:. }echniques

G. Schlemmer, B. Welz

Palladium, a Powerful New Hatrix Modifier for Graphite Furnace AAS

XXI Page 256 258 261 264 266 268 270 272 274 276 280

XXII Code TU E 085 TU E 121 TU E 197 TU E 20 3 TU E 216 ·. c TU E 288 TU E 331 TU E 341 TU E 388 TU E 419 TU !' 002

M.W. Hinds, R. Karwowska, K.W. Jackson

The Vaporization and Atomization Behaviour of solid Samples Analyzed

Directly 'by El~ctrÓthermal Atomizatio,n-Atomic Absorption Speetrometry

T. Kantor, L. Bezur

Volatilization studies of Cadmium Compounds by thP Combined Quartz

Furnace and Flame Atomie Absorption Method. The Effect of Magnesium

Chloride and Ascorbic Acid Additives

Tsv. Jötov

Hybrid Atomizer for Isothermal Atomization in Graphite Furnace Atomie

Absorption Speetrometry (GFAAS)

J.R. Dean, R.D. Snook

Electrothermal Atomization or vaporization?

A.A. Brown, P.M. Green, T.C. Dymott, S.F.N. Morton

The Graphite Furnace AAS Determination of Refractory Elements Using

• , ~' ' 1..· • '

rurnace cuvettes Made \•/holly from Pyrolytic Graphite

)

..

s. Akman, s. Bektas,

o

.

Gene

A New Approach in Interpretation of Flameless Atomie Absorption Signals

J .~1. Harnly

simultaneous Hultielement Atomie Absorption Speetrometry Using

Electrothermal Atomization

z.

Benzo, N. Carrion, J. Flores, C.R. Castro

Treatment of Graphite Atomizers by ~letallie Deposition for Atomie

Absorption Spe~troscopy

w.

Frech, A. Cedergren, E. L~ndberg

Investigation of some ~lethods used to Reduce Interterenee Effects

in Graphite Furnace Atomie Absorption Spectro~etry (GFAAS)

P.M. Pollard, J.W. McMillan, J.L. Bowen, J.P. Arthur

The Measurement of Technetium in Radioactive Waste Leaehates by Furnace

Atomie Absorption Spectroscopy

POSTERS ·'

.

SESSION F studies of complexes Page 282 284 286 28 8 290 29 2 294 29 6 29 8 300

R.M. Issa, A.K. Abdel-Kader, ~. Gaber, M. Abd-El-Ghafar 304

IR, 1_{!iN~lR, Electronic and ESR Spectroscopie Investigation of some Charge}

Transfer Complexes of Schiff Bases Derived from 4-Aminopyridine with

-['fl

-

Code

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I.M. Al-Daher, B.M. Al-Saadi . I • .>

2-~lercaptobenzoic Acid· Complex~s .. o.f s·H·veli.·

(U..-

·

Palladium . ( 11) and

Bismuth (111) ... ··: ..

S.H. Etaiw, G.B, El-Hefnawey,· .N •. T. Abd~l ,Ghany

Temperature Dependenee of Formation constantn EXtlnction coefficient

and Total Absorption Intensity of Thiophenes _{-1 2} complexes

.

..

)

·

.

B. Tamhina,

v.

Vojko~lc ..

·

.

Spectrophotometric Determination of Titanium(IV),with

3-Hydroxy-2-Methyl-1-(4-Tolyl)-4-Pyridone

R. Vilaplana, M.G. Basallote, E.J.G. conejero, P •. -Gon,alez-Vilchez

Applications of. Infrared Speçtroscopy· to:the Thermal ·Study of Melal

complexes with Chelating Agents

M,S, Masoud, A.M. Heiba

Speetral Properties of Sorne Azo Compounds and Complexes

M.C. Garcia Alvarez-Coque, Gi -Ramis Ramos, c. Martinez Vaya,

c.

Mangay Fernandez

Spectrophotometric Determination·of Copper(II) and Mercury(II) with

Diethyldithiocarbamate and Triton X-100

A. Benedetti, E. Ori, C. Preti, s. Solmi, G, Tosi

Spectroscopie Studies of Transition Metal Complexes with some

1,4-Benzodiazepines ., I . XXIII Page 306 JO 8 310 31 2 314 316 318 l.S. Maslennikova 320

Infrared Spectroscopie Studies of Kaolin and Water Interaction in the

Presence of Aniline Complexes

POSTERS

- '· ~ESSION G

Atomie fluorescence, forward scattering

J. Tilch, H. Falk, H.-J,·Paetzold, P.Ç. ~Ion, .K.P, Schmidt

Application of the Laser-Excited Atomie Fluorescence on the

Determination of Trace Elements in Soli~·Samples

. )

M. GroS, s. Ganz, G. Hermann, A. Scharmann

Hultielement Analysis Using, Optical"Forwarct.· scatter ing. in Combination

with Flarne Atomization

'

'

,.

H. Debus, S. Ganz, G. Hermann, A. Scharmann

Background correction by Polarization Modulation in Hultielement

Analysis Using Speetrometry of Optical Forward scattering

324

326

XXIV Code TU G 143 TU· G 294 TU G 401 TÛ G 472 TU H 0 39 TU H 0 50 TU H 0 51 TU H 0 54 TU H 191 TU H 198 TU 11 296 A. Quentmeier, K. Laqua

Laser Atomie Fluoresoence Spectroscopy in the

uv

Speetral Range by Anti-stokes Raman-Shifting

G.~l. Hieftje, G.!l. Vickers, R.H. ·r-liller

E'xtending the

Time Resolved Fluorescence Measurements Using an Optic~l Fibre Probe

B.V. Arkhangelsky, A.S. Gonchakov, s.s. Grazhulene

Application of the Atomie Fluorcscence Method of Analysis with a

Tungsten Spiral Atomizer and Different Excitation Sourees to a

Trace Analysis

.K. óittrich, H.-J. Stärk

.Laser Excited Atomie Fluorescencc Spectromt!try (l.AFS) Using Graphite

Tubes as Atomizer

.

..

~.

-

.. POSTERS

SCSSION H

Furnace AAS: fundamental

H.H. Ortner,

v

.

Sychra

Scanning Electron Microscopy Studies on Tungsten Atomizers

w.

Wendl, G. MUller-Vogt

Kinetics of the Atomization Process for Various Metals in Graphite

Furnace AAS

G. HUller-Vogt,

w.

wendl

Reactions of oxide Forming Elements in the Graphite Furnace of Atomie

Absorption Spectrometers

H.M. Ortner, G. Schlemmer, B. Welz

Scanning Electron Microscopy Studies on New Graphite Materials for GFAAS

Page 33 2 335 337 340 342 344 346 C.J. Rademeyer, H.G.C. ·~uman 348

Evaluation of Contoured Tubes for Effecting Stabilised Temperature

Atomisation Conditluns in Graphitc rurnacc Atomie Absorption Speetrometry

H.G.C. Human, C.J. Radefueycr 350

Gas Temperature in Graphite Furnace Atomie Absorption Speetrometry

B. Radziuk, I. Martinseo, Y. Thom~stien

Characterization of some Interterences Oue to Non-Specific Absorption

in Electrothermal Atomie Absorption Speetrometry

\. 352

f

r

l

l

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Code TU I 014 TU I 0 25 TU I 098 TU I 115 TU I 287 TU I 3 34 TU I 485 TU K 224 TU K 243 TU K 319 TU K 346 POSTERS SESSION I

Mass Spectrometry: eleméhtal

M.J, Adams, G. Ewen, J, Bacon' · / .

...

Multi-Element Analysis with a·computeri~ed· Microdensitometer for

Spark souree Mass Speetrometry

T.J. Piper, L. Rundeli

A Computer-controlled Micr.odensitometry System for the Interpretation of SSMS Photoplates

N.S. Ham, T. McAllister

Flame Ionization Mass Speetrometry of Si, Ge, Sn and Pb

N. Jakubows~i,

o

.

StUwer

A New Glow Discharge Ion souree for Mass Spectroscopy of Inorganic Solids

w.w

.

Harrison, K.R. Hess

Laser Resonance Ionization in a Pulsed Clow Discharge

K. Takaishi, T. Kikuchi, K. Furuya, I. Hashimoto, H. Yamaguchi,

E. Yagi, M, Iwaki

Thermal Extraction of Krypton in Aluminium Using Mass Spectrometer

H. zeininger, J.D. Fassett, L.J. Moore

Resonance Ionization Mass Speetrometry for Elemental and Isotopic

Analysis

POSTERS

SESSION K

Mass Spectrometry: molecular

A. Benedetti, c. Preti, L. Tassi, G. Tosi, P. zannini

Mass Speetral studies on Phenylsubstituted Dithiocarbamato Derivatives

A. l·lolf, I . Trummer, G. lliksche, K. Thomke

Einsatz eines Massenspektrometers zur Uberwachung eines mehrstufigen

Deuterierungsprozesses

M. Masur, H.F. GrUtzmacher

Separated Mass Spectrometric Study of Pure Keto and Enol Tautomers

of 1,3-Diketones

I•I,D, Koller

Mass-Spectrometric Identification of Volatile Compounds in combination

with Static Head-Space Analysis

kxv

Page 356 358 360 362 364 366 368 370 372 374 37 6

XXVI

Code

TU K 350

TU K 478

C.J. Peacock

~nvestigation of the Odours Emitted from an Animal Wastes Processing Plant Using GC-MS

~1. Linscheid, E.-~1. Rustler, H. Hillig

Design and Performance of a Postacceleration Detector for a SP.ctor

Field Mass Spectrometer Page 377 37 9

*

*

*

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Code TH A IL56 TH A IL54 TH A IL22 TH A IL26 TH A IL32 INVITED LECTURES SESSION A J,B, Willis

Aerosols in Flame Atomie Spectroscopy B, Welz, M, Schubert-Jacobs

Investigations on Atomization Mechanisms in Hydride-Generation Atomie Absorption Speetrometry

A.L. Gray

Ions or ·Photons - An Assessment of the R~lationship between Emission and Mass Speetrometry with the ICP

K.G. Heumann

High Accuracy in the Element Analysis by Màss Spectroscopy L. Kosta

Radiochemical Analysis - A Survey of lts Present State

INVITED LECTURES SESSION B TH B IL03· J, Amouroux, D, Morvan, A. Gicq~ei

Plasma for Special Applications

'.

TH B IL17 J. Fijalkowski

DC-Arc Excitation - Is It Obsolete?

TH

e

·

IL38 B.V. Pavlovic . r

.

~

..

,

The DC Are as Radlation Souree for Op~ic;:al E:mission Spectroscopy .·: j( . :

- A Survey

-TH B IL09 J ,B, Dawson

Analytical Atomie Spectroscopy in Biology & Medicine

. :.. ... .; ;t

TH B IL02 R. Alvarez '. ... ) ' ' .J •• :::" : ,-. : ': ,._ •• •

Certified Reference llaterials for Validating Spectroscopie Methods . . -. r '

and Experimental Data _{, .}

; J ,· ... •• XXVII' Page 382 382 383 383 384 386 386 387 387 388

XXVIJl Code TH C IL11 TH C IL05 TH C IL45 TH C IL47 TH C IL48 TH A 015 TH A 0 21 TH A 043 TH A 0 52 TH A 153 TH A 167 TH A 228 TH A 392 TH A 403 INVITED LECTURES SESSION C 1~. Demtröder

High Reso1ution Molecular Spectroscopy with Lasers r.o. Campbell

NHR Studies of Enzymes

H.-L. Schmidt

Food Quality Control and Tracer Sudies on Human Nutrition by Hass

Spectrometric Isotope Ratio Determination

J.N. Shoolery

Some Structural and Analytica! Applications of Multidimensiona1 NMR

C.E. Snape

Application of NMR to Fossil Fuels: An Assessment of Recent Advances

POSTERS SESSION A

ICP - mass speetrometry

A. Boorn, P. Arrowsmith, D. Douglas, J, Fulford, E. Quan

Recent Developments in ICP-MS at SCIEX

J,\1, 11cLaren, A.P. Mykytiuk,

s.s.

Berman

Applications of Inductively Coupled Plasma Mass Speetrometry in Marine Analytica! Chemistry

F.E. Lichte, A.L, Meier

Analysis of Geological Materials Using Inductively Coupled Plasma

Mass Speetrometry

H.E. Taylor, J .R, Garbarino

Characterization of Stabie Isotope·oilution Trace Analysis Using

rnductively Coupled Plasma-Mass ~pectrometry

.

·, I. Holclajtner-Antunovic, N, Ikonomov, M. Todorovic, N. Kovacic

Analysis of R.F. Discharge Composition in Air

E, Poussel, D. Deruaz, J,M, Mermet

Study of a 100 MHz ICP Generator as an Ion Souree in Mass Speetrometry

F. Kinnart, R.C. Hutton, P,J, Goddard, H. Kutter

Trace Element Determinations in Binary and Ternary Actinide Compounds

by ICP-OES and ICP-MS Techniques

S.E, Long, R.M. ~rown, C.~. Piekford

The Characterisation of Some Interterences in ICP-MS

G. Horlick, S.H. Tan, M.A. váughan, C.A. Rose . .

The Effect of Plasma Operating Parameters on'Änalyt~ Si~nals in

Inductively Coupled Plasma-Mass Speetrometry

Page 390 390 391 391 392 394 395 397 398 400 40 2 40 4 40 6 '107

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TH A 405 TH A 406 TH A 480 TH 0 0 94 Tfl B 100 TH R 102 TH R 291 TH B 465 TH 0 4 66 Til B 4 67 TH R 4 93 ' .

.

~: . S.H. Tan, G. Horlick

Background Spectr~l Feature~ in }nductively Coupled Plasma-Mass

Speetrometry

S.H. Tan, H.A. Vaughan, G. HoçlLck . .

The Quantitative Performance of Induçtiver~y. Coupled ~Pl.asma-~lass

Speetrometry

·

'

.

.

'.

S.H. Tan, G. Horlick

Matrix Effects in Inductively Coupled Plasma-Mass Speetrometry

. ,:

A.R. Date, Y.Y •. Çheung,. ~1.~:-·Stuart _{1 1}

The Determination of Trace Elements in Ca-Rich,,Sa!llples .by ICP-f·IS

POSTERS • .. • •• • (._·- J ... , r "..

, .. ,:.;

SESSIOfl B

; :;

::

)•) : ~

.

:·'

I~,. Raman: method.i,Ci):l.:.~ :··,,

.. ~ . . .

.

...

.

.

.

G. Thirup, J.F. Alder, F. Renmakroha, A. Leontakianakos

F'requency Locked Analytical f-licrowave Rotational Spectrometer

S. Higt,~chi, S. Ogitani, S •. Tanaka_

Laser-Induced Infrared Fluorescence Spectrocopy Sensitized by Addition

of SF_{6 -} Examinatien in View of. the The~~l Effect

-T. Hattori,

s

.

Higuchi, ~·· .Tanaka~ .

Ra~an Optical Activity of ,Sgme Aphi~al Mqlecules in Chiral Environments ' ' .

W. Hellmann, H.H. Belz

Quantitative Analysis of Aqueous Solutions by Using a;Cylindrical ATR .

Cell and FT-IR Speetrometry

A. Otto, E.H. Korte

Novel Design of an Accessory for Diffuse Reflectance Infrared

Fourier Transferm (Orift.) ·Sp~~~r<;>.:>,sopy . .

_'·

U. Bode, H.M. Helse

flatrix-Iso1ation-Techni.que. _f_or IR Hicro and Trace Analysis

H .~1. Hei se :-·:

Cell Pathlength Determination with Grating and FT-Spectrometers

.

.

:

.

.

·.

:.'. XXIX Page 40 8 40 9 410 411 414 416 418 420 422 424 426 T. Hirschfeld 428

l~hat Else Can ~e Done with, NIR~? .). : .,.,

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XXX ., · Code TH C 0 30 TH C 095 TH C 158 TH C 181 TH C 182 TH C 250 TH C 328 TH C 329 TH C 389 TH D 0 55 TH D 061 POSTERS SESSION C Applications: clinical

L.A. Kuyun, V.G. Bordonos, N.M. Bereshnaya

Spectral-Luminescence Properties ·of Alveolar Hacropnages and Lung Tissues· Dut·ing Allergie 'oamage

J.F, Alder, A.J. Guthrie, R. Narayanaswamy

Optical Fibre pH Sensors

L. Yao-han,

s.

Qi-rong, H, Hui-ming

'

Determination of Trace Lithium in Biologïca-1 Samples by Graphite

Furnàce Atomization

.

..

Y. Thomassen, ~. Radziuk

Direct Electrothermal Atomie Absorption Spectrometric Determination of Aluminium in Human Biopsy Samples

H. Ihnat, M. Stoeppler, Y. Thomassen,

c

.

Veillon, H. Wolynetz IUPAC Interlabor'at'ory Trials for the Determination of Elements

in Human Body Fluids

M. Ba~cells, G. Lacor~, M, Roura

Determination of Se in Serum by Graphite Furnace and Automatic Hydride

Generation Using AAS and ICP Techniques. A Comparative Study

R. Rodriguez Roza, R. Gbnzalez Alonso, A. Noval, J. Cannata, A. Sanz-Medel

Critica! Comparison of Atomic-Sp~ct~ometric M~thods (Graphite

Furnacè AAS, Conve n't ion al ICP and ICP w ith Electrothermal Va por i zat ion)

for Determination of Aluminium in Biologica! Fluids · J. R. Andersen

Determination of Aluminium in Human Tissues ·and Body Fluids by Zeeman Corrected AAS

lv.J. Kinsey, R, Fisher

Atomie Emission Spectroscopy arid the ·Clinical Laboratoiy

'

..

_POSTERS

SESSION D

Are, spark

H. Simic, T. Mihailidi, J. Georgij~vic,

v

.

G~orgijevic, D. Simic Some Aspects of the ~!atrix Effect in Different Types of DC Are Light Sourees

L.A. Guirguis, A.E.L. Bialy, M. Rasmy,

·

w.

Moussa

Study of Carrier Effect and Associated Phenomena in Emission Spectrographic Analysis of Granitic Rocks

Page 4 _,. 30 432 434 436 438 440 442 444 446 4 50 452

!

I

•

Code T!i D 136

!

11

TH D 140 i

U

TH D 150 II.D

_{,_}

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-

TH D 152 TH D 163

·

' II'J

-TH D 207

;

ïïi

TH D 255 lUl TH D 290

--:.lil I 1 • TH.D 422 11

._.

TH D 466 .fll

:

n

1

u

TH 8 0 37

.

ll

TH E 0 96 IJl IJ TH E 120 IJ

A. Golloch, H.-M. Ku~, J , Schmitz ~ r •

Erprobung eines neuen, Wech.se:ls.t.rornbog,ens JÜ.s .Anregungsei.nheit in der Emissions-Spektrometrie

P. Serapinas, I. Apostol,· .. R. But.eikis,. I.~·N •.. Hiha.P~.sçu, ·J,: O~erauskas

Spark Discharge Cathode Spot Hicrostructure and Anlytical Parameters

~ . . . :-f, .

A. Strasheim, R._o. B!)hmer. . .•. - ·:.: .· .-.- ~·: ,. :·

A Study of a High Repetition Condensed Are ,Sou~ce f.or. th~ rAnaly.sis of

Low Alloys Steels Using Different Counter Electrode Sample

Con f igura ti ons. Analys is of JtaQgane.se : )~ . i . ·.· .. , . : .. , . '

' .

'

S.B. Radovanov, M.R. Tripkovic, Z.D. Janevski

Spectroscopie Analysis of Pulsed Discharge,l'!~asf11~:,il'\ .I,i,quids,,

.

.

,•('·: -' ...

R. TUrker, M. Dogan.. , ' . ·:

.

-::.

•:

... ;

"-.

The Influence of Selected Buffer

Determination of Ni, Ho and V in

L. Paksy, I. Lakatos

Compounds on Spectrochemical

As ph a 1 ti te A3. lt.,:·; . :' . ·:

Various Applications of an Efficient Impravement of the Conventional

Excitation Sourees by Axial Injec;tion of Argqn , -.-,

o

.

Mollov, A. Petraklev

Emission Speetral Analysis of Gases in Metals and Alloys

H. Dogan, L. Elci ·

Spektrachemische Bestimmung von einigen an·der Aktivko~le

angereicherten Spurenelementen durch Gleichstromlichtbogen

J, Wysocka-Lisek, B. Paszkowska

The RQle of Thermochemical Reaction~'in the Spectrographic

Determination-of ·Rare Earth .Elements~Using Different Metallic Electredes

M.A. Eid, A.A. Fakhry, M,S. El Alfy, F.A. El Anany, A.A. Mahdy

Effect of Buffers and Inhomogeneous Magnetic Field on the Speetral Line

Intensities in the DC Carbon Are

.

...

. ~ :

:. POSTERS

, ·,,1· · SESSION E · ·_

', ·_; " .. :·:' ..

AAS:.--flame

D,Dj. Stojanovic, V.J. Vajgand,

.

s

.

o

.

.

Nikolie

A New Look at the·Releasing E;~feqi;··Qf ·Sol)le: Re{lgents in the Determination

of Magnesium by At;omic ·.MH>O';'Pt~on-,Fli!me Speetrometry

N.S. Ham, J ,B, Willis· :

.

_{. / ; "':}

_:

Impact Beads, Spray.Chambers-and Ioter~~r~nces.

N. Barakat,

z

.

El Gohary, H. Medaht

The Effect of Background Interference on .1\.tomic Absorption Measurements

XXXI Page 4 5.4 4 56 456 4 60 462 464 466 466 470 472 •476 476 460 I

I

' I

~

I

I

·:XXXII ·code fH·E 170 H. Berndt, M.L.B. Tristao TH E 179 ~ : . TH E 215 TH E 227 TH E 247 TH E 327 ! . TH E 347 TH E 385 ~. TH E 450 TH f 0 49 TH f 10 9 TH f 274

··.· .Probenv·erdàmpfung fUr die IHktoanalys~ in ·der' Flammen-AAS

H. Urbain

Use' of Suitable Duffers i·n fl'ame spe'ctral· Anlysis of Catalysts

I . . . ; '

A.A. Brown, M. Lee, A. Taylor

Comparison of Atom Trapping Techniques in ~lame Atomie

"Absorpt:io'n Speetrometry ;··

. ·. ') ' '

.

.

:

D.E. Shrader, P.R. Liddell, D.C. Ho'obin :.r

New System Integration and Customized Analysis for Atomie Absorption

s. Gücer, A.E.· ~aragözler .,

Investigation of Chemica! Interferences in Determination of Some

Metals with Platinum-Loop Atomie Absorption Spectrophotometei

;:~ I • '. J • ..•

G, Özcan, O.Y. Ata~àn

Determination of Zinc in Cerebrospinal fluid by Platinum Loop Atomie Absorption Speetrometry

~ 3 ,., . . .. • • '

J, Risova,

z

.

Hladky, ;\J. Izak

Application of Atom Trapping Atomic-Absorption Speetrometry in Trace Analysis of High Purity Acids

o.

Rohon, L. Dankova, J. Lesny, J. Tölgyessy

.

'

The Relationship Between Chemical form of Organometallic Compounds,

Strictly Optiruized Instrumental Conditions and Achieved Sensitivity in flame AAS

A.G. Brashnarova

Effect of Some Acids and Thcir Salts on Cu, Zn, Mn,·cr and Fe

Determinatiun in ~oils

by

Atomic'Abs6rption Spectroscopy

,•}

•' .. POS'l'EHS

. : l

SESSION F

Laser(s in) spectroscopy

H. Saisho, K. Sushidai H~·Hashimoto, E. Nakamura

Fundamental Studies of Laser Probe Elemental Analyses with a SIT Vldicon as a neteetion S~stam

R. Bador, H, Dechaud, 11. Moi'in;.c. ,!Jesuzinges

Time-Resolved Luminescence· Mèàslirements··of' Eu+++. Excited by a Laser Souree: A H ighly Sëns i ti iie 'lu'I<Hyt i tal ~lè thod

G.C. Turk, f.C. Ruegg, J .C. Travis, J,_R, DeVoe .. : ·

Three-Dimensional Atumlc S~ectrà in:Flames· U~i~g·stepwisé Excitation

Laser-Enhanced Ionization Spectroscopy

:

.·.

·

·

"

.

.

.

' . J 48 2 484 486 488 490 492

[

494 496 498

r

f

502 50 4 .. l 506

n

11 11 .11

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r.K

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Code TH F 315 TH F 361 TH G 006 TH G 022 TH G 127 TH G 230 TH G 232 TH G 311 . TH G 337 TH G 365

.

.

M. Schreiner, P. Dolezel, G. Banik, F. Mairinger

Laser - Emissions'spektra.ian'ál'yse 'bef"·dEir Untersuchung von Kunstwerken

V.T. Yaroslavtzev, v·:A. Lu'n.che\,,''(;,A;·:Aöákumo.v,'1A.P. Simonov

· ·· ·i · · n · · r.

Laser Photodissociatio~ of Polyatomic-Mólecul~r·Ions

POSTERS

·, .'\ ''!i

SESSION G

NMR s~ectroscopy ' • J I ~ ' :

S.M. Abu-El-Wafa, R,M, Issa, A.A, El~~a~f,h}i~: f~~~il

Spectroscopie Studies (Electronic Absorption, IR and lH N~IR) of

• .. .: I: ··I ' 'I:' ' ... ~ ..

l-Hydroxy~2-Carboxy, 4-Pheriyl-AZO-B-Diketones

;

.

...

.

; ..

K, Funatsu, C.A. Del Carpio, S. Sasaki

Role of

Interdepende~t

Analysès of ltr and l

&ê

L

N

~

Ii

·~

S~eè't

:ra

in

Structure Elucidation Syst~m, 'chemics· · :' - ···;,,.,,., ,_.t ...

,'••'1'".:- ' ·,

G. Schütze, 1~.-o. Domke, F. Dickert, K, Kretzschmar

0' -= t •

NMR-Spectroscopic S~udies on Boron T.r.ihalogenid~ Amlne Adducts

: ~ ,

P. Ruostesuo, R, Liias,

u.

Salminen, A.-M. Häkkinen

-~ "

Multinuclear NMR Spectrosco~Î.c Stuil'iês of Sulfur and Selenium· Amides ·

.. '\ - (', ·- · .. , ~ "3 f.,

P, Ruostesuo,

s

.

Kaartinen,

V.

Rukajärvi, L,' Heikkinen,

P, Pirilä-Honkanen

Study on the Interactlens of NH Group Containing Lactams and Sulfur

Amides in Binary Mixtures ·.;'

A. Dölle, Th, Bluhm

;

"

..

'·

Rotational .oynamics in Liquids: Orien_tatio.n of the Rotational Diffusion

Tensor Principal Axis' System by In'teq:iretation of l3ç Spin-Lattice

Relaxation Data

F, Bylicki, H.G, Web~r

~lagnetic Resonance Experiments in N0₂: An Iéregul.ar Lande Factor in

the N0₂ 2B₂ State.

.,·,

R.I. Zalewski

Applicat ion of Characteristic Vee tor Analys is to 13c N~IR Spectra of

Substituted Flexible and .~i,~id···~lic~cli~ Compounds

"I , o o t , I .. ·· . ' . , . ,- 0,; : :0

.

,) ; -' .• = ',' ' :.: . \ , ' 'J -•• • • ..:- , : . ..:.. ., ) • ::... - _•

..

• < XXXIII Page 50 8 510 514 516 .,·, 518 520 522 524 526 52 8